综述了三氟氯乙烯共聚物的主要种类及性能特点,介绍了已商业化的三氟氯乙烯共聚物的应用领域及近年来的研究进展,并对三氟氯乙烯共聚物的发展前景进行了展望。
The main kinds and properties of chlorotrifluoroethylene copolymers were reviewed,the application fields and rencent progress of commercial chlorotrifluoroethylene copolymers were introduced,and the future development trends of chlorotrifluoroethylene copolymers were described.
[1] 陈生,李明武,王燕冬.国内外氟塑料制品的发展及应用[J].化工新型材料,2004,32(5):1-5.
[2] 陈鸿昌.含氟聚合物新产品的开发与应用[J].化工新型材料,2011,39(8):18-24.
[3] 王文贵,杨勇,陈秉倪.乙烯-三氟氯乙烯共聚物(ECTFE)的研究进展[J].有机氟工业,2007(2):28-32.
[4] 付海涛.偏氟乙烯-三氟氯乙烯共聚物的结晶、结构及形态[D].上海:复旦大学,2004.
[5] 龚文化,曾黎明.氟碳涂料研究及发展趋势[J].化工新型材料,2003,31(7):5-7.
[6] Mueller M M,Morristown,Chandrasekaran S.Stress-crack resistent ethylene-perhaloethylene copolymers:US,3847881[P].1974-11-12.
[7] Reimschuessel H K,Rahl F J,Ulmer H E,et al.Copolymers of chlorotrifluoroehtylene,ethylene and perfluoroalktlethylenes:EP,0185242[P].1986-06-25.
[8] Chin H B,Chandrasekaran S.Copolymerrization of ethylene and chlorotrifluoroethylene in an aqueous emulsion:US,4482685[P].1984-11-13.
[9] Hanford W E.Copolymerization of chlorotrifluoroethylene and olifen hydrocarbons:US,2392378[P].1946-01-08.
[10] Reimschuessel H K,Rahl F J.Ethylene-chlorotrifluoroethylene copolymers.I.synthesis and evaluation of compositions resistant to thermal stress cracking[J].Journal of Polymer Science:Part A:Polymer Chemistry,1987,25:1871-1886.
[11] Reimschuessel H K,Marti J,Murthy N S.Ethylene-chlorotrifluoroethylene copolymers.Ⅱ.Effects of structure on resistance to thermal stress cracking[J].Journal of Polymer Science:Part A:Polymer Chemistry,1988,26:43-59.
[12] Randová A,BartovskáL,PilnáČek K,et al.Sorption of organic liquids in poly(ethylene chlorotrifluoroethylene) Halar® ;901:experimental and theoretical analysis[J].Polymer Testing,2017,58:199-207.
[13] Yamabe Masaaki,Kojima Gen,Kaya Seitoku.Curable fluorocopolymers:US,4345057[P].1982-08-17.
[14] 何爱平.国内外FEVE涂料树脂的进展及溶剂型FEVE树脂的合成[J].涂料技术与文摘,2011,32(4):17-29.
[15] 李运德.FEVE氟碳涂料的制备及应用[J].涂料技术与文摘,2011,32(4):30-38.
[16] Shoichi K,Toru O,Nobuyuki M,et al.Composition for an aqueous coating material:US,5548019[P].1996-08-20.
[17] 鹫见直子,守角健,木村功,等.水性涂料用组合物及其制造方法以及二液固化型水性涂料盒:中国,101426866A[P].2009-05-06.
[18] 巩永忠.环保型FEVE氟碳涂料应用与研究进展[J].涂料技术与文摘,2015,36(11):47-56.
[19] 山内优,石田彻.具有固化性官能团的含氟树脂粉体及其涂料组合物的制造方法:中国,1310958C[P].2007-04-18.
[20] 陈红.涂料行业经济趋势对氟碳涂料发展的影响[C].2017氟硅涂料行业年会论文集,常州:2017.
[21] David V,Frédéric B,Bruno A,et al.Synthesis and modification of alternating copolymers based on vinyl ethers,chlorotrifluoroethylene,and hexafluoropropylene[J].Macromolecules,2009,42(20):7689-7700.
[22] Frédéric B,Bruno A.(Co)polymers of chlorotrifluoroethylene:synthesis,properties,and applications[J].Chemical Review,2014,114(2):927-980.
[23] 张亨.聚烯烃类氟橡胶的性能及应用[J].橡塑资源利用,2013(1):32-34.
[24] Zheng L B,Wang J,Yu D W,et al.Preparation of PVDF-CTFE hydrophobic membrane by non-solvent induced phase inversion:relation between polymorphism and phase inversion[J].Journal of Membrane Science,2018,550:480-491.
[25] 车延超,蒋振宁.电活性聚合物P(VDF-TrFE-CTFE)的制备与介电性研究[J].有机氟工业,2010(3):10-12.
[26] Thibaut S,Vincent L,Fabrice Domingues D S,et al.Vinylidene fluoride- and trifluoroethylene-containing fluorinated electroactive copolymers.How does chemistry impact properties?[J].Progress in Polymer Science,2017,72:16-60.
[27] Giulio B,Alessio M,Bernard G,et al.Vinylidene fluoride and trifluoroethylene containing polymers:WO,2009147030A1[P].2009-12-10.
[28] Francois B.Method for the production of terpolymers based on vinylidene fluoride,trifluoroethylene and chlorofluoroethylene or chlorotrifluoroethylene:WO,2010116105A1[P].2010-10-14.
[29] Wang Z,Zhang Z,Chung T,et al.High dielectric VDF/TrFE/CTFE terpolymers prepared by hydrogenation of VDF/CTFE copolymers:synthesis and characterization[J].Macromolecules,2006,39:4268-4271.
[30] Lu Y,Claude J,Zhang Q,et al.Microstructures and dielectric properties of the ferroelectric fluoropolymers synthesized via reductive dechlorination of poly(vinylidene fluoride-co-chlorotrifluoroethylene)s[J].Journal of America Chemistry Society,2006,39(20):6962-6968.
[31] Mikes F,Teng H,Kostov G,et al.Synthesis and characterization of perfluoro-3-methylene-2,4-dioxabicyclo[3,3,0] octane:homo- and copolymerization with fluorovinyl monomers[J].Journal of Polymer Science Part A:Polymer Chemistry,2009,47(23):6571-6578.
[32] Zhang M,Russell T P.Graft copolymers from poly(vinylidene fluoride-co-chlorotrifluoroethylene) via atom transfer radical polymerization[J].Macromolecules,2006,39(10):3531-3539.
[33] Simone S,Figoli A,Santoro S,et al.Preparation and characterization of ECTFE solvent resistant membranes and their application in pervaporation of toluene/water mixtures[J].Separation & Purification Technology,2012,90:147-161.
[34] Zhou B,Li Q,Tang Y,et al.Preparation of ECTFE membranes with bicontinuous structure via TIPS method by a binary diluent desalination and water treatment[J].2016,57(38):17646-17657.
[35] Hamed K,Saeid R,Emanuele D N,et al.Preparation and characterization of ECTFE hollow fiber membranes via thermally induced phase separation (TIPS)[J].Polymer,2016,97:515-524.
[36] Francesco F,Sergio S,Francesco G,et al.Organic/organic mixture separation by using novel ECTFE polymeric pervaporation membranes[J].Polymer,2016,98:110-117.
[37] 中国塑料技术网.美国推出薄膜新产品 提升美太阳能竞争力[J].橡塑技术与装备,2016,42(2):66.
[38] Toniolo P,Carella S.Halar® high clarity ECTFE film-an highly transparent film for new buildings structures[J].Procedia Engineering,2016,155:28-37.
[39] 杜安梅,陈红.2016氟碳涂料行业现状及发展趋势[J].涂料技术与文摘,2017,38(10):51-57.
[40] 付铁柱,王海连,成佳辉.FEVE含氟树脂的结构和性能及含氟涂料的改性和应用[J].有机氟工业,2011(4):24-29.
[41] 王舒钟,高柳敬,斋藤俊,等.水性FEVE氟碳树脂Lumiflon的开发和应用[J].有机氟工业,2017(1):41-45.
[42] 巩永忠,陶冶,任环,等.氟碳粉末涂料在建材表面的应用进展[J].涂料工业,2015,45(5):78-81.
[43] 巩永忠,陶冶.建筑铝型材用氟碳粉末涂料的技术进展及应用展望[J].涂料工业,2017,47(11):63-68.
[44] 刘海涛.FEVE涂料的研究及其在新能源领域应用进展[J].中国建材科技,2017,26(4):58-60.
[45] 胡渊蔚,华建飞,党朋.架空导线的几种防腐措施[J].电线电缆,2017(4):12-14.
[46] 张在利,曾子敏,李嘉.氟橡胶性能、应用及我国氟橡胶工业发展现状[J].化工新型材料,2003,31(2):9-12.
[47] 陈立义,张海波.一种新型偏氟乙烯与三氟氯乙烯氟橡胶的合成研究[J].有机氟工业,2012(1):12-15.
[48] 罗世凯.PBX氟聚合物粘结剂的辐射效应研究[D].北京:中国工程物理研究院,2002.
[49] Wang J,Zheng L,Zhang X,et al.Fabrication of hydrophobic flat sheet and hollow fiber membranes from PVDF and PVDF-CTFE for membrane distillation[J].Journal of Membrane Science,2016,497:183-193.
[50] Zheng L,Wang J,Li J,et al.Preparation,evaluation and modification of PVDF-CTFE hydrophobic membrane for MD desalination application[J].Desalination,2017,402:162-172.