作为一类新型的纳米多孔材料,多孔有机聚合物(Porous organic polymer,POP)由于其具有比表面积大,吸附性能强、相对密度低和环境友好等优点,在离子交换、催化、气体分离和气体储存等领域具有巨大的潜在应用前景,并引起了学术界的广泛关注。多孔有机聚合物高的孔隙率以及其独特的孔道结构,使其具有良好的隔热特性,通过引入含有不同阻燃元素或官能团的有机砌块可提升其阻燃性。因此,多孔有机聚合物可作为隔热和阻燃材料被使用。
As a new class of nanoporous materials,porous organic polymers have enormous advantages of larger specific surface area,strong adsorption performance,low relative density and environmental friendliness.It has aroused widespread concern in academia with potential application prospects in ion exchange,catalytic,gas separation,gas storage and so on.The high porosity of the polymer and its unique pore structure give it excellent thermal insulation properties.The flame retardance of the polymer can be improved by introducing organic blocks contained different flame retardant elements or functional groups.Therefore,the porous organic polymer can be used as thermal insulation and flame retardant materials.
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基金资助
国家自然科学基金项目(51663012,51462021)