二硫化钼与碘氧化铋复合材料的制备与应用

张进, 张钰国, 黄如春, 殷楠

化工新型材料 ›› 2019, Vol. 47 ›› Issue (8) : 127 -130.

PDF (2365KB)
化工新型材料 ›› 2019, Vol. 47 ›› Issue (8) : 127-130.
科学研究

二硫化钼与碘氧化铋复合材料的制备与应用

    张进, 张钰国, 黄如春, 殷楠
作者信息 +

Preparation and application of molybdenum sulfide and bismuth oxide composite

  • Zhang Jin, Zhang Yuguo, Huang Ruchun, Yin Nan
Author information +
文章历史 +
PDF (2421K)

摘要

采用水热法分别制备了二硫化钼(MoS2)和碘氧化铋(BiOI)材料,借助超声辅助方法在140℃条件下制备了MoS2/BiOI复合材料。用X射线衍射仪(XRD)、扫描电镜(SEM)和紫外-可见漫反射(DRS)对制得样品进行了表征。以亚甲基蓝作为被降解物,来探究二硫化钼的复合对碘氧化铋光催化性能的影响;研究加入不同质量比的二硫化钼对材料光催化活性的影响。结果表明:15%(wt,质量分数,下同)MoS2与BiOI的复合材料光催化性能最优。经过330min的可见光照射,15% MoS2/BiOI对10mg/L亚甲基蓝溶液的降解率为97.09%。

Abstract

Bismuth trioxide and molybdenum disulfide were prefabricated by hydrothermal method.And molybdenum disulfide and bismuth oxide composites were prepared under the conditions of ultrasonic-assisted synthesis at 140℃.The samples were characterized by X-ray diffraction (XRD),scanning electron microscopy (SEM) and ultraviolet visible diffuse reflectance (DRS).The effect of the compound of molybdenum disulfide on the photocatalytic properties of bismuth iodide was explored by using methylene blue as the degraded substance.The effects of molybdenum disulfide with different mass ratios on photocatalytic activity of materials were studied.The results showed that the photocatalytic performance of 15% MoS2/BiOI composites was best.The results also showed that15% MoS2/BiOI samples showed a degradation rate of 97.09% for 100mL of methylene blue solution with a concentration of 10mg/L.

关键词

光催化 / 二硫化钼 / 碘氧化铋 / 水热法

Key words

photocatalysis / molybdenum disulfide / bismuth iodide / hydrothermal method

引用本文

引用格式 ▾
二硫化钼与碘氧化铋复合材料的制备与应用[J]. 化工新型材料, 2019, 47(8): 127-130 DOI:

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] Dong Renfeng,Hu Yan,Wu Yefei,et al.Visible-light-driven BiOI-based janus micromotor in pure water[J].J Am Chem Soc,2017,139(5):1722-1725.
[2] Wang Chao,Yao Hongchang,Fan Zeyu,et al.Indirect Z-scheme BiOI/g-C3N4photocatalysts with enhanced photoreduction CO2 activity under visible light irradiation[J].ACS Appl Mater Interfaces,2016,8(6):3765-3775.
[3] Huang Hongwei,He Ying,Du Xin,et al.A general and facile approach to heterostructured core/shell BiVO4/BiOI p-n junction:room-temperature in situ assembly and highly boosted visible-light photocatalysis[J].ACS Sustainable Chem Eng,2015,3(1):3262-3273.
[4] Wen Xiaoju,Niu Chenggang,Zhang Lei,et al,Fabrication of SnO2 nanopaticles/BiOI n-p heterostructure for wider spectrum visible-light photocatalytic degradation of antibiotic oxytetracycline hydrochloride[J].ACS Sustainable Chem Eng,2017,5(6):5134-5147.
[5] Zhou Xuejiao,Shao Changlu,Yang Shu,et al.Heterojunction of g-C3N4/BiOI immobilized on flexible electrospun polyacrylonitrile nanofibers:facile preparation and enhanced visible photocatalytic activity for floating photocatalysis[J].ACS Sustainable Chem Eng,2018,6(7):2316-2323.
[6] 李美娟,沈舒宜,罗国强,等.水热法合成球花状二硫化钼及其电化学性能[J].无机化学学报,2017,33(9):1521-1526.
[7] 王芳,王雪芹,程凯,等.MoS2负载量对MoS2/TiO2光催化降解苯酚效率的影响及其作用机理研究[J].燃料化学学报,2017,45(8):1001-1008.
[8] 侯静静,赵清华,李廷鱼,等.球状MoS2/WO3复合半导体制备及其对RhB的光催化性能[J].无机化学学报,2017,33(9):1527-1536.
[9] 程合锋.铋系层状化合物的结构设计、功能化组装及其光催化性质研究[D].济南:山东大学,2012.
[10] Di J,Xia J,Ge Y,et al.Facile fabrication and enhanced visible light photocatalytic activity of few-layer MoS2 coupled BiOBr[J].Dalton Trans,2014,43(2):15429.
[11] Xia Jiexiang,Ge Yuping,Zhao Dexiang,et al.Microwave-assisted synthesis of few-layered MoS2/BiOBr hollow microspheres with superior visible-light-response photocatalytic activity for ciprofloxacin removal[J].Cryst Eng Comm,2015,17(4):3645-3651.
[12] Di J,Xia J,Ge Y,et al.Facile fabrication and enhanced visible light photocatalytic activity of few-layer MoS2 coupled BiOBr[J].Dalton Trans,2014,43:15429-15428.
[13] 李跃军,曹铁平,梅泽民,等.Ce掺杂Bi2MoO6/TiO2纳米纤维异质结的制备及可见光催化性能[J].无机化学学报,2018,34(4):689-696.
[14] 缐芳,李巧玲,陈贝,等.纳米花球MoS2的制备及其对环氧树脂摩擦性能的影响[J].应用化工,2018,47(3):443-447.
[15] Yang Y P,Li Z M,Yang Y C,et al.Fabrication,microstructure and catalytic degradation performance of MoS2 hollow microspheres[J].Chinese J Inorg Chem,2012,28(7):1513-1519.

基金资助

中国博士后基金(2012M511254);江苏省大学生创新训练计划(201711460054X);南京晓庄学院大学生创新基金(2017XSKY010)

AI Summary AI Mindmap
PDF (2365KB)

655

访问

0

被引

导航
相关文章

AI思维导图

/