导电喷墨墨水研究进展

梁智昊, 王小妹*, 伍雪芬

化工新型材料 ›› 2019, Vol. 47 ›› Issue (7) : 40 -45.

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化工新型材料 ›› 2019, Vol. 47 ›› Issue (7) : 40-45.
综述与专论

导电喷墨墨水研究进展

    梁智昊, 王小妹*, 伍雪芬
作者信息 +

Development of inkjet conductive ink

  • Liang Zhihao, Wang Xiaomei, Wu Xuefen
Author information +
文章历史 +
PDF (1233K)

摘要

喷墨印刷技术是一种新型高效的绿色环保生产技术。其中,导电喷墨墨水由于应用前景广阔,一直受到科研工作者的关注。导电喷墨墨水包括金属喷墨墨水和石墨烯喷墨墨水。综述了导电喷墨墨水中银包裹铜(Cu@Ag)喷墨墨水、低温烧结纳米银喷墨墨水以及新型石墨烯喷墨墨水的研究进展,3种喷墨墨水最低电阻率分别为1.134×10-7Ω·m、3.84×10-8Ω·m、1.9×10-7Ω·m,为块状金属银电阻率的7倍、2.4倍、12倍,具有优异的导电性。同时,还介绍了导电喷墨墨水在探测器、锂离子电池、超级电容器等方面的应用,指出了目前仍存在的问题,并对其发展前景进行了展望。随着柔性线路板应用范围越来越广,导电喷墨墨水的应用将具有广阔的发展空间。

Abstract

Inkjet printing is a novel,environmental friendly and efficient technology and inkjet conductive ink has been focused by science researchers because of its wide application prospects.Inkjet metal ink and inkjet graphene ink are two kinds of inkjet conductive ink.The new research about silver-coated copper (Cu@Ag) nanoparticles ink,nanosilver ink by low temperature sintering and novel graphene ink were expounded.The lowest resistivity of as-prepared three inks were 1.134×10-7Ω·m,3.84×10-8Ω·m and 1.9×10-7Ω·m respectively,just 7 times,2.4 times and 12 times of bulk silver,presenting the excellent conductivity.Besides,their application in the field of detectors,lithium ion batteries and supercapacitors were listed.Moreover,the drawbacks and the development of the present conductive ink were pointed out.Due to the development and popularization of flexible circuit board,conductive ink as a kind of extremely suitable ink for flexible circuit board will be widely used in the future.

关键词

导电墨水 / 纳米金属 / 石墨烯 / 喷墨打印 / 电阻率

Key words

conductive ink / nano metal / graphene / inkjet printing / resistivity

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导电喷墨墨水研究进展[J]. 化工新型材料, 2019, 47(7): 40-45 DOI:

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参考文献

[1] Pan Z D,Wang Y M,Huang H N,et al.Recent development on preparation of ceramic inks in ink-jet printing[J].Ceramics International,2015,10(41):12515.
[2] Roman D,Tomas S H,Graham D M,et al.Inkjet printing for pharmaceutics-a review of research and manufacturing[J].International Journal of Pharmaceutics,2015,2(494):554.
[3] Rahul S H,Balasubramanian K,Sriramvenkatea H.Optimizing inkjet printing process to fabricate thick ceramic coatings[J].Ceramics International,2017,5(43):4513-4519.
[4] Kwon J W,Lee J H,Lee J H,et al.Thermal and chemical stability evaluation of white ceramic pigment for digital inkjet printing[J].Journal of the Korean Crystal Growth and Crystal Technology,2016,5(26):201-208.
[5] Toshita K,Ryota W.A new one-pot method for the synthesis of Cu nanoparticles for low temperature bonding[J].Journal of Materials Chemistry,2012,22(48):25198-25206.
[6] Sung H,Hak S.Flash light sintering of nickel nanoparticles for printed electronics[J].Thin Solid Films,2012,550:575-581.
[7] Wenjer J T,Chen C N.Dispersion and rheology of nickel nanoparticle inks[J].Journal of Material Science,2006,41(4):1213-1219.
[8] Yun H J,Inyu J,Chung S C,et al.Synthesis and characterization of low temperature Sn nanoparticles for the fabrication of highly conductive ink[J].Nanotechnology,2011,22(22):225701.
[9] Kobayashi Y,Ishida S,Ihara K,et al.Synthesis of metallic copper nanoparticles coated with polypyrrole[J].Colloid and Polymer Science,2009,7(287):877-880.
[10] Yan J F,Zou G S,Hu A M,et al.Preparation of PVP coated Cu NPs and the application for low-temperature bonding[J].Journal of Materials Chemistry,2011,21(40):15981-15986.
[11] Kobayashi Y,Sakuraba T.Silica-coating of metallic copper nanoparticles in aqueous solution[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2008,1(317):756-759.
[12] Kanninen P,Johans C,Merta J,et al.Influence of ligand structure on the stability and oxidation of copper nanoparticles[J].Journal of Colloid and Interface Science,2008,1(318):88-95.
[13] Luechinger N A,Athanassiou E K,Stark W J.Graphene-stabilized copper nanoparticles as an air-stable substitute for silver and gold in low-cost ink-jet printable electronics[J].Nanotechnology,2008,19(44):445201.
[14] Anna P S,Yousef F,Alexander K,et al.Air stable copper-silver core-shell submicron particles:synthesis and conductive ink formulation[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2017,521:272-280.
[15] Magdassi S,Bassa A,Vinetsky Y,et al.Silver nanoparticles as pigments for water-based ink-jet inks[J].Chemistry Materials,2003,11(15):2208-2217.
[16] Anna P S,Yousef F,Alexander K,et al.Effect of carboxylic acids on conductivity of metallic films formed by inks based on copper@silver core-shell particles[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2017,522:320-327.
[17] Changsoo L,Na R K,Jahyun K,et al.Cu-Ag core-shell nano-particles with enhanced oxidation stability for printed electronics[J].Nanotechnology,2015,25(45):455601.
[18] Chee S S,Lee J H.Preparation and oxidation behavior of Ag-coated Cu nanoparticles less than 20 nm in size[J].Journal of Materials Chemistry C,2014,2(27):5372-5381.
[19] Angela L D,Patrick J S,Shin D Y,et al.A low curing temperature silver ink for use in ink-jet printing and subsequent production of conductive tracks[J].Macromolecule Rapid Communication,2005,4(26):315-318.
[20] Kim D J,Moon J H.Highly conductive ink jet printed films of nanosilver particles for printable electronics[J].Electrochemical and Solid-State Letters,2005,8(11):30-33.
[21] Daisuke W,Kim K S,Katsuaki S.Room-temperature sintering process of Ag nanoparticle paste[J].IEEE Transactions on Components and Packaging Technologies,2009,3(32):627-632.
[22] Shlomo M,Michael G,Oleg B,et al.Triggering the sintering of silver nanoparticles at room temperature[J].ACS Nano,2010,4(4):1943-1948.
[23] Michael G,Alexander K,Cristina F M,et al.Conductive inks with a “built-in” mechanism that enables sintering at room temperature[J].ACS Nano,2011,5(4):3354-3359.
[24] Yao T,Wei H,Guoyun Z G,et al.A new approach causing the patterns fabricated by silver nanoparticles to be conductive without sintering[J].Nanotechnology,2012,23(35):355304.
[25] Yao T,Wei H,Wang S X,et al.New insight into the size-controlled synthesis of silver nanoparticles and its superiority in room temperature sintering[J].CrystEngComm,2014,16(21):4431-4440.
[26] Kate B,Jetinder S,Danielle M,et al.Silver ink formulations for sinter free printing of conductive films[J].Scientific Reports,2016,6:20814.
[27] Seung H K,Heng P,Costas P G.Air stable high resolution organic transistors by selective laser sintering of ink-jet printed metal nanoparticles[J].Applied Physics Letters,2007,90(14):141103.
[28] Jolke P,Robert A,Sebastian W,et al.Roll-to-roll compatible sintering of inkjet printed features by photonic and microwave exposure:from non-conductive ink to 40% bulk silver conductivity in less than 15 seconds[J].Advance Materials,2012,24(19):2620-2625.
[29] Perelaer J,De Gans B J,Schubert U S.Ink-jet printing and microwave sintering of conductive silver tracks[J].Advance Materials,2006,18(16):2101-2104.
[30] Jolke P,Robin J,Michael G,et al.Plasma and microwave flash sintering of a tailored silver nanoparticle ink,yielding 60% bulk conductivity on cost-effective polymer foils[J].Advance Materials,2012,24(29):3993-3998.
[31] Keun S K,Yue Z,Houk J,et al.Large-scale pattern growth of graphene films for stretchable transparent electrodes[J].Nature,2009,7230(457):706-710.
[32] Li Jiantong,Fei Y,Sam V,et al.Efficient inkjet printing of graphene[J].Advanced Materials,2013,25(29):3985-3992.
[33] Gao Yahui,Wen S,Wucong W,et al.Inkjet printing patterns of highly conductive pristine graphene on flexible substrates[J].Industrial & Engineering Chemistry Research,2014,53(43):16777-16784.
[34] Ethan B S,Pradyumna L P,Kanan P,et al.Inkjet printing of high conductivity,flexible graphene patterns[J].Journal of Physical Chemistry Letter,2013,4(8):1347-1351.
[35] Vineet D,Sumedh P S,Srikanth A,et al.All-organic vapor sensor using inkjet-printed reduced graphene oxide[J].Angewandte Chemie,International Edition,2010,49(12):2154-2157.
[36] Lim Soojin,Boseok K,Donghoon K,et al.Inkjet-printed reduced graphene oxide/poly(vinyl alcohol) composite electrodes for flexible transparent organic field-effect transistors[J].Journal of Physical Chemistry C,2012,116(13):7520-7525.
[37] Porro S,Giardi R,Chiolerio A.Real-time monitoring of graphene oxide reduction in acrylic printable composite inks[J].Applied Physics A,2014,3(117):1289-1293.
[38] Li Lihong,Guo Yuzhen,Zhang Xingye,et al.Inkjet-printed highly conductive transparent patterns with water based Ag-doped grapheme[J].Journal of Materials Chemistry A,2014,2(44):19095-19101.
[39] Wang Gongkai,Wang Zhuo,Liu Zhihong,et al.Annealed graphene sheets decorated with silver nanoparticles for inkjet printing[J].Chemical Engineering Journal,2015,260:582-589.
[40] Xu L Y,Yang G Y,Jing H Y,et al.Ag-graphene hybrid conductive ink for writing electronics[J].Nanotechnology,2014,25(5):055201.
[41] Gyu R H,Sun S L,Hye J P,et al.Unraveling the issue of Ag migration in printable source/drain electrodes compatible with versatile solution-processed oxide semiconductors for printed thin-film transistor application[J].ACS Applied Materials & Interfaces,2017,9(16):14058-14066.
[42] Yung J L,Changsoo L,Hyuck M L.Synthesis of oxide-free aluminum nanoparticles for application to conductive film[J].Nanotechnology,2017,29(5):055602.
[43] Pourahmadazar J,Tayeb A D.60GHz antenna array for millimeter-wave wireless sensor devices using silver nanoparticles ink mounted on a flexible polymer substrate[J].Microwave and Optical Technology Letters,2017,59(11):2830-2835.
[44] Shi Libo,Michael L,Xuan C,et al.An inkjet printed Ag electrode fabricated on plastic substrate with a chemical sintering approach for the electrochemical sensing of hydrogen peroxide[J].Sensors and Actuators B:Chemical,2018,256:938-945.
[45] Nipapan R,Orawon C,Koji S,et al.Fully inkjet-printed paper-based potentiometric ion-sensing devices[J].Analytical Chemistry,2017,89(19):10608-10616.
[46] Cai Wenran,Chen Yanqiu,Liu Yu,et al.Fabrication of copper electrode on flexible substrate through Ag+-based inkjet printing and rapid electroless metallization[J].IEEE Transaction on Components,Packaging and Manufacturing Technology,2017,7(9):1552-1559.
[47] Huang Lu,Huang Yi,Liang Jiajie,et al.Graphene-based conducting inks for direct inkjet printing of flexible conductive patterns and their applications in electric circuits and chemical sensors[J].Nano Research,2011,4(7):675-684.
[48] Pratima L,Yue C.Graphene nano-ink biosensor arrays on a microfluidic paper for multiplexed detection of metabolites[J].Analytica Chimica Acta,2014,813:90-96.
[49] Han X,Chen Y,Zhu H,et al.Scalable,printable,surfactant-free graphene ink directly from graphite[J].Nanotechnology,2013,24(20):205304.
[50] Keunyoung S,Jinyong H,Jyongsik J.Micropatterning of graphene sheets by inkjet printing and its wideband dipole-antenna application[J].Advance Materials,2011,23(18):2113-2118.
[51] Felice T,Tawfique H,Wu Weiping,et al.Inkjet-printed graphene electronics[J].ACS Nano,2012,6(4):2992-3006.
[52] Wei Di,Piers A,Yang Huafeng,et al.Flexible solid-state lithium batteries based on graphene inks[J].Journal of Materials Chemistry,2011,21(26):9762-9767.
[53] Xu Y,Ingolf H,Dieter F G,et al.Inkjet-printed energy storage device using graphene/polyaniline inks[J].Journal of Power Sources,2014,248:483-488.
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