化工新型材料

化工新型材料 ›› 2019, Vol. 47 ›› Issue (7) : 46-49.

综述与专论

多孔材料在去除废水中重金属离子方面的研究进展

作者信息 +

Research progress of porous material applied in removing heavy metal ions from wastewater

Hu Zhilong, Sun Hanxue, Wei Huijuan, Mu Peng, Li An

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文章历史 +

Received		Published
2018-03-06		2019-07-20
Issue Date	Revised Date
2019-08-05	2018-03-06

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摘要

多孔材料是一种具有一定尺寸空隙结构和具有一定比表面积的材料,按其孔径大小可分为微孔材料、介孔材料和大孔材料。多孔材料具有相对密度小、比表面积高、重量轻、渗透性好等特点,并具有很好的吸附性能。本文主要重点介绍了几种不同的多孔材料作为吸附剂应用于去除废水中的重金属离子。

Abstract

Porous material is a kind of material with a certain size of the gap structure and a certain specific surface area,according to the size of its pore size can be divided into microporous materials,mesoporous materials and macroporous materials.Porous materials with a relative density,high specific surface area,light weight,good permeability and good adsorption properties.The use of porous materials as adsorbents for the removal of heavy metal ions in wastewater was focused.

关键词

多孔材料 / 吸附性 / 重金属离子

Key words

porous material / adsorption / heavy metal ion

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多孔材料在去除废水中重金属离子方面的研究进展[J]. 化工新型材料, 2019, 47(7): 46-49 DOI:

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参考文献

原文顺序 | 出版日期 | 本文引用

[1] Vilela D,Parmar J,Zeng Y,et al.Graphene-based microbots for toxic heavy metal removal and recovery from water[J].Nano Lett,2016,16:2860-2866.
[2] Aragay G,Pons J,Merkoçi A.Recent trends in macro-,micro-,and nanomaterial-based tools and strategies for heavy-metal detection[J].Chemical Reviews,2011,111:3433-3458.
[3] Kim Y,Johnson R C,Hupp J T.Gold nanoparticle-based sensing of “spectroscopically silent” heavy metal ions[J].Nano Lett,2001,1:165-167.
[4] 黎青,陈玲燕,沈军,等.多孔材料的应用与发展[J].材料导报,1995(2):10-13.
[5] Park S J,Jang Y S.Pore structure and surface properties of chemically modified activated carbons for adsorption mechanism and rate of Cr(Ⅵ)[J].J Colloid Interface Sci,2002,249:458-463.
[6] Nguyen C,Do D D.A new method for the characterization of porous materials[J].Langmuir,1999,15:3608-3615.
[7] Suriyanon N,Punyapalakul P,Ngamcharussrivichai C.Mechanistic study of diclofenac and carbamazepine adsorption on functionalized silica-based porous materials[J].Chemical Engineering Journal,2013,214:208-218.
[8] Hua M,Hang S,Pan B,et al.Heavy metal removal from water/wastewater by nanosized metal oxides:a review[J].J Hazard Mater,2012,211:317-331.
[9] Yuan Q,Li N,Chi Y,et al.Effect of large pore size of multifunctional mesoporous microsphere on removal of heavy metal ions[J].J Hazard Mater,2013,254:157-165.
[10] Tsai W T,Chang C Y,Wang S Y,et al.Preparation of activated carbons from corn cob catalyzed by potassium salts and subsequent gasification with CO₂[J].Bioresource Technology,2001,78:203-208.
[11] Hayashi J I,Horikawa T,Muroyama K,et al.Activated carbon from chickpea husk by chemical activation with K₂CO₃:preparation and characterization[J].Microporous and Mesoporous Materials,2002,55:63-68.
[12] Jusoh A L,Shiung Su,Ali N a,et al.A simulation study of the removal efficiency of granular activated carbon on cadmium and lead[J].Desalination,2007,7:9-16.
[13] Kang K C,Kim S S,Choi J W,et al.Sorption of Cu²⁺ and Cd²⁺ onto acid- and base-pretreated granular activated carbon and activated carbon fiber samples[J].Journal of Industrial and Engineering Chemistry,2008,14:131-135.
[14] Deliyanni E A,Kyzas G T,Triantafyllidis K,et al.Activated carbons for the removal of heavy metal ions:a systematic review of recent literature focused on lead and arsenic ions[J].Open Chemistry,2015,13:23-29.
[15] Anirudhan T S,Sreekumari S S.Adsorptive removal of heavy metal ions from industrial effluents using activated carbon derived from waste coconut buttons[J].Journal of Environmental Sciences,2011,23:1989-1998.
[16] Iijima S.Helical microtubules of graphitic carbon[J].Nature,1991,354:56-59.
[17] Wang H,Zhou A,Peng F,et al.Mechanism study on adsorption of acidified multiwalled carbon nanotubes to Pb(Ⅱ)[J].Journal of Colloid and Interface Science,2007,316:277-283.
[18] Kabbashi N A,Atieh M A,Al-Mamun A,et al.Kinetic adsorption of application of carbon nanotubes for Pb(Ⅱ) removal from aqueous solution[J].Journal of Environmental Sciences,2009,21:539-544.
[19] Kuo C Y,Lin H Y.Adsorption of aqueous cadmium(Ⅱ) onto modified multi-walled carbon nanotubes following microwave/chemical treatment[J].Desalination,2009,249:792-796.
[20] Kandah M I,Meunier J L.Removal of nickel ions from water by multi-walled carbon nanotubes[J].Journal of Hazardous Materials,2007,146:283-288.
[21] Odom T W,Huang J L,Kim P,et al.Atomic structure and electronic properties of single-walled carbon nanotubes[J].Nature,1998,391:62-69.
[22] Rao G P,Lu C,Su F.Sorption of divalent metal ions from aqueous solution by carbon nanotubes:a review[J].Separation and Purification Technology,2007,58:224-231.
[23] Pillay K,Cukrowska E M,Coville N J.Multi-walled carbon nanotubes as adsorbents for the removal of parts per billion levels of hexavalent chromium from aqueous solution[J].Journal of Hazardous Materials,2009,166:1067-1075.
[24] Novoselov K S,Fal′ko V I,Colombo L,et al.A roadmap for graphene[J].Nature,2012,490:192-198.
[25] Gopalakrishnan A,Krishnan R,Thangavel S,et al.Removal of heavy metal ions from pharma-effluents using graphene-oxide nanosorbents and study of their adsorption kinetics[J].Journal of Industrial and Engineering Chemistry,2015,30:14-19.
[26] Chen Y,Chen L,Bai H,Li L.Graphene oxide-chitosan composite hydrogels as broad-spectrum adsorbents for water purification[J].J Mater Chem A,2013,1:1992-2001.
[27] Dong Z,Wang D,Liu X,et al.Bio-inspired surface-functionalization of graphene oxide for the adsorption of organic dyes and heavy metal ions with a superhigh capacity[J].Journal of Materials Chemistry A,2014,2:5034-5039.
[28] Bhattacharyya K G,Gupta S S.Adsorption of a few heavy metals on natural and modified kaolinite and montmorillonite:a review[J].Advances in Colloid and Interface Science,2008,140:114-131.
[29] Sud D,Mahajan G,Kaur M P.Agricultural waste material as potential adsorbent for sequestering heavy metal ions from aqueous solutions-a review[J].Bioresource Technology,2008,99:6017-6027.
[30] Wan Ngah W S,Hanafiah M A K M.Removal of heavy metal ions from wastewater by chemically modified plant wastes as adsorbents:a review[J].Bioresource Technology,2008,99:3935-3948.
[31] Jiang M Q,Jin X Y,Lu X Q,et al.Adsorption of Pb(Ⅱ),Cd(Ⅱ),Ni(Ⅱ) and Cu(Ⅱ) onto natural kaolinite clay[J].Desalination,2010,252:33-39.
[32] Apiratikul R,Pavasant P.Sorption of Cu²⁺,Cd²⁺,and Pb²⁺ using modified zeolite from coal fly ash[J].Chemical Engineering Journal,2008,144:245-258.
[33] Apiratikul R,Pavasant P.Batch and column studies of biosorption of heavy metals by caulerpa lentillifera[J].Bioresource Technology,2008,99:2766-2777.
[34] Meena A K,Mishra G K,Rai P K,et al.Removal of heavy metal ions from aqueous solutions using carbon aerogel as an adsorbent[J].Journal of Hazardous Materials,2005,122:161-170.
[35] Jiang J X,Su F,Trewin A,et al.Conjugated microporous poly(aryleneethynylene) networks[J].Angewandte Chemie International Edition,2007,46:8574-8578.
[36] Li A,Sun H X,Tan D Z,et al.Superhydrophobic conjugated microporous polymers for separation and adsorption[J].Energy & Environmental Science,2011,4:2062-2069.
[37] Dawson R,Laybourn A,Clowes R,et al.Functionalized conjugated microporous polymers[J].Macromolecules,2009,42:8809-8816.
[38] Yang R X,Wang T T,Deng W Q.Extraordinary capability for water treatment achieved by a perfluorous conjugated microporous polymer[J].Sci Rep,2015,5:10155-10159.