The phase composition and microstructure of ramie fiber fabric legacy structure Al2O3-Cu composite materials with preform infiltration method were investigated by means of XRD,SEM and EDS.Tensile tests were conducted.The results showed that Al2O3 preform retained the complete ramie fiber fabric heritage structure.Oxidation impregnation samples formed a columnar riveted structure which tissue feature was CuO and CuAlO2 coated Al2O3.After reduction and sintering at 1020℃,the Cu phase co-melted with the bulk Al2O3 phase and the precipitated CuAlO2 phase.The outer surface of Al2O3-Cu was covered by Cu protective layer and the inner core was cross-sectioned (Cu+Al2O3+CuAlO2).And its tensile strength was 10.73MPa.
[1] Ren F,Zhi A,Zhang D,et al.Preparation of Cu-Al2O3 bulk nano-composites by combining Cu-Al alloy sheets internal oxidation with hot extrusion[J].Journal of Alloys & Compounds,2015,633:323-328.
[2] Kim J S,Dudina D V,Kim J C,et al.Properties of Cu-based nanocomposites produced by mechanically-activated self-pro-pagating high-temperature synthesis and spark-plasma sintering[J].J Nanosci Nanotechnol,2010,10(1):252-257.
[3] Chen T Y,Lu W,Liu W,et al.Preparation of purity Al2O3 for LED sapphire materials by ammonium aluminum sulfate and its performance[J].Advanced Materials Research,2014,1053:50-55.
[4] Fathy A,Shehata F,Abdelhameed M,et al.Compressive and wear resistance of nanometric alumina reinforced copper matrix composites[J].Materials & Design,2012,36:100-107.
[5] Nachum S,Fleck N A,Ashby M F,et al.The microstructural basis for the mechanical properties and electrical resistivity of nanocrystalline Cu-Al2O3[J].Materials Science & Engineering A,2010,527(20):5065-5071.
[6] 申坤,汪明朴,郭明星,等.Cu-0.23% Al2O3弥散强化铜合金的高温变形特性研究[J].金属学报,2009,45(5):597-604.
[7] 张孟杰,范润华.新型氧化铝陶瓷基复合材料的制备和应用[J].化工新型材料,2002,30(8):27-28;36.
[8] Zu G Q,Shen J,Wang W Q,et al.Synthesis and thermal behavior of high-surface-area monolithic alumina aerogels[J].Rare Metal Materials and Engineering,2016,45(S1):522-529.
[9] Rajkovic V,Bozic D,Jovanovic M T.Effects of copper and Al2O3 particles on characteristics of Cu-Al2O3 composites[J].Materials & Design,2010,31(4):1962-1970.
[10] Zhang X H,Lin C G,Cui S,et al.Microstructure and properties of Al2O3 dispersion-strengthened copper fabricated by reactive synthesis process[J].Rare Metals,2014,33(2):191-195.
[11] Amirthan G,Udayakumar A,Prasad V V B,et al.Synthesis and characterization of Si/SiC ceramics prepared using cotton fabric[J].Ceramics International,2009,35(3):967-973.
[12] 李达,陈沙鸥,朱海玲,等.遗态材料的研究理念和研究进展[J].材料导报,2006,20(10):5-7.
[13] 杨尔慧,王俊勃,王蒙,等.不同诱导剂对氧化铝陶瓷性能的影响与分析[J].应用化工,2015,44(9):1609-1612.
[14] Locs J,B C L,Zhurinsh A,et al.Optimized vacuum/pressure sol impregnation processing of wood for the synthesis of porous,biomorphic SiC ceramics[J].Journal of the European Ceramic Society,2009,29(8):1513-1519.
[15] 刘奋军,姬妍,孟庆森,等.镁合金表面激光熔敷+搅拌摩擦加工Al-Cu涂层的显微组织与性能[J].中国有色金属学报,2017,27(10):1981-1987.
基金资助
国家自然科学基金(21603169);陕西省科技攻关项目(2016-GY014);西安工程大学研究生创新基金项目(CX201704)