介绍了高分子材料的阻燃研究现状,概述了阻燃元素杂化技术、各元素阻燃机理及元素杂化协同阻燃高分子材料的研究进展,同时对阻燃剂的研究方向进行了展望。
The research status of flame-retardant polymer was introduced.The progress of retardant element hybrid technology,the flame retardant mechanism of various elements and synergistic flame retardant polymer materials with hybrid elements were summarized,and the research direction of flame retardant was discussed.
[1] Müller P,Bykov Y,Döring M.New star-shaped phosphorus-containing flame retardants based on acrylates for epoxy resins[J].Polymers for Advanced Technologies,2013,24(9):834-840.
[2] Kashiwagi T,Du F,Douglas J F,et al.Nanoparticle networks reduce the flammability of polymer nanocomposites[J].Nature Materials,2005,4(12):928-933.
[3] Ciesielski M,Schäfer A,Döring M.Novel efficient DOPO-based flame-retardants for PWB relevant epoxy resins with high glass transition temperatures[J].Polymers for Advanced Technologies,2008,19(6):507-515.
[4] Artner J,Ciesielski M,Walter O,et al.A novel DOPO-based diamine as hardener and flame retardant for epoxy resin systems[J].Macromolecular Materials and Engineering,2008,293(6):503-514.
[5] Juang T Y,Liu J K,Chang C C,et al.A reactive modifier that enhances the thermal mechanical properties of epoxy resin through the formation of multiple hydrogen-bonded network[J].Journal of Polymer Research,2011,18(5):1169-1176.
[6] Ding J,Tao Z,Zuo X,et al.Preparation and properties of halogen-free flame retardant epoxy resins with phosphorus-containing siloxanes[J].Polymer Bulletin,2009,62(6):829-841.
[7] Filippi S,Mameli E,Marazzato C,et al.Comparison of solution-blending and melt-intercalation for the preparation of poly (ethylene-co-acrylic acid)/organoclay nanocomposites[J].European Polymer Journal,2007,43(5):1645-1659.
[8] Han Y,Wu Y,Shen M,et al.Preparation and properties of polystyrene nanocomposites with graphite oxide and graphene as flame retardants[J].Journal of Materials Science,2013,48(12):4214-4222.
[9] Ebdon J R,Price D,Hunt B J,et al.Flame retardance in some polystyrenes and poly (methyl methacrylate)s with covalently bound phosphorus-containing groups:initial screening experiments and some laser pyrolysis mechanistic studies[J].Polymer Degradation and Stability,2000,69(3):267-277.
[10] Liu J K,Shau S M,Juang T Y,et al.Tailored thermal and mechanical properties of epoxy resins prepared using multiply hydrogen-bonding reactive modifiers[J].Journal of Applied Polymer Science,2011,120(4):2411-2420.
[11] Wang X,Hu Y,Song L,et al.Preparation,flame retardancy,and thermal degradation of epoxy thermosets modified with phosphorous/nitrogen-containing glycidyl derivative[J].Polymers for Advanced Technologies,2012,23(2):190-197.
[12] Sarwar M I,Zulfiqar S,Ahmad Z.Poly (ether amide) and silica nanocomposites derived from sol-gel process[J].Journal of Sol-Gel Science and Technology,2008,45(1):89-95.
[13] Chiang C L,Chiu S L.Synthesis,characterization and properties of halogen-free flame retardant PMMA nanocomposites containing nitrogen/silicon prepared from the Sol-Gel method[J].Journal of Polymer Research,2009,16(6):637.
[14] Tsai M H,Huang S L,Chiang P C,et al.Morphology,dynamic mechanical properties,and gas separation of crosslinking silica-containing polyimide nanocomposite thin film[J].Journal of Applied Polymer Science,2007,106(5):3185-3192.
[15] Samyn P,Taheri H.Rheology of fibrillated cellulose suspensions after surface modification by organic nanoparticle deposits[J].Journal of Materials Science,2016,51(21):9830-9848.
[16] Brown J R,Chappell P J C,Mathys Z.Plasma surface modification of advanced organic fibres[J].Journal of Materials Science,1992,27(12):3167-3172.
[17] Baskaran D,Mays J W,Bratcher M S.Polymer adsorption in the grafting reactions of hydroxyl terminal polymers with multi-walled carbon nanotubes[J].Polymer,2005,46(14):5050-5057.
[18] Cinausero N,Azema N,Cochez M,et al.Influence of the surface modification of alumina nanoparticles on the thermal stability and fire reaction of PMMA composites[J].Polymers for Advanced Technologies,2008,19(6):701-709.
[19] Ma H Y,Tong L F,Xu Z B,et al.Functionalizing carbon nanotubes by grafting on intumescent flame retardant:nanocomposite synthesis,morphology,rheology,and flammability[J].Advanced Functional Materials,2008,18(3):414-421.
[20] Wu Z P,Hu Y C,Chen M Q.The effect of intumescent flame retardant contained microencapsulated red phosphorus on the flame retardance and thermal degradation behaviour of epoxy resin[J].Advanced Materials Research(Trans Tech Publications),2011,197:1167-1170.
[21] Liu J,Yu Z,Shi Y,et al.A preliminary study on the thermal degradation behavior and flame retardancy of high impact polystyrene/magnesium hydroxide/microencapsulated red phosphorus composite with a gradient structure[J].Polymer Degradation and Stability,2014,105:21-30.
[22] Liu J,Zhang Y,Peng S,et al.Fire property and charring behavior of high impact polystyrene containing expandable graphite and microencapsulated red phosphorus[J].Polymer Degradation and Stability,2015,121:261-270.
[23] Chen X,Yu J,He M,et al.Effects of zinc borate and microcapsulated red phosphorus on mechanical properties and flame retardancy of polypropylene/magnesium hydroxide composites[J].Journal of Polymer Research,2009,16(4):357-362.
[24] Liu S H,Chen W J,Shen M Y,et al.Preparation,characterization and its flame retardance performance of microencapsulated ammonium polyphosphate/bridged polysesquisiloxane polyurethane composites[J].Journal of Polymer Research,2016,23(9):201.
[25] Balabanovich A I,Engelmann J.Fire retardant and charring effect of poly (sulfonyldiphenylene phenylphosphonate) in poly (butylene terephthalate)[J].Polymer Degradation and Stability,2003,79(1):85-92.
[26] Chang Y L,Wang Y Z,Ban D M,et al.A novel phosphorus-containing polymer as a highly effective flame retardant[J].Macromolecular Materials and Engineering,2004,289(8):703-707.
[27] Lin C H,Wu C Y,Wang C S.Synthesis and properties of phosphorus-containing advanced epoxy resins.Ⅱ[J].Journal of Applied Polymer Science,2000,78(1):228-235.
[28] Qian L,Qiu Y,Sun N,et al.Pyrolysis route of a novel flame retardant constructed by phosphaphenanthrene and triazine-trione groups and its flame-retardant effect on epoxy resin[J].Polymer Degradation and Stability,2014,107:98-105.
[29] Zhao X,Gao S,Liu G.A THEIC-based polyphosphate melamine intumescent flame retardant and its flame retardancy properties for polylactide[J].Journal of Analytical and Applied Pyrolysis,2016,122:24-34.
[30] Song M L,Huang Y W,Cao K,et al.Synthesis of a new silicon-phosphorus hybrid flame retardant from waste silicon oil and its application in polypropylene system[J].Advanced Materials Research.Trans Tech Publications,2012,534:304-308.
[31] Wu Q,Zhang Q,Zhao L,et al.A novel and facile strategy for highly flame retardant polymer foam composite materials:transforming silicone resin coating into silica self-extinguishing layer[J].Journal of Hazardous Materials,2017,336:222-231.
[32] Gao M,Sun Y J.Epoxy resins treated with novel silicon-containing flame retardant[J].Advanced Materials Research.Trans Tech Publications,2012,560:563-568.
[33] Deh S,Gähr F,Buchmeiser M R.Synergistic effects in the pyrolysis of phosphorus-based flame-retardants:the role of Si-and N-based compounds[J].Polymer Degradation and Stability,2016,130:155-164.
[34] Martin C,Ronda J C,Cadiz V.Development of novel flame-retardant thermosets based on boron-modified phenol-formaldehyde resins[J].Journal of Polymer Science Part A(Polymer Chemistry),2006,44(11):3503-3512.
[35] Belousova R G,Schwartz E M,Zarina I E,et al.Low-toxicity boron-containing fire-retardant additives for polymeric coatings[J].Russian Journal of Applied Chemistry,2010,83(2):328-331.
[36] Majoni S,Su S,Hossenlopp J M.The effect of boron-containing layered hydroxy salt (LHS) on the thermal stability and degradation kinetics of poly (methyl methacrylate)[J].Polymer Degradation and Stability,2010,95(9):1593-1604.
[37] Çakmakç E,Mülazim Y,Kahraman M V,et al.Preparation and characterization of boron containing thiol-ene photocured hybrid coatings[J].Progress in Organic Coatings,2012,75(1):28-32.
[38] Liang G L,Lin J,Dai P B,et al.Synergistic flame retardant effect of fumed silica and zinc borate with magnesium hydroxide in ABS based flame retardant composites[J].Applied Mechanics and Materials.Trans Tech Publications,2014,599:132-135.
[39] Cabrera-Álvarez E N,Ramos-deValle L F,Sánchez-Valdes S,et al.Study of the silane modification of magnesium hydroxide and their effects on the flame retardant and tensile properties of high density polyethylene nanocomposites[J].Polymer Composites,2014,35(6):1060-1069.
[40] Könnicke D,Kühn A,Mahrholz T,et al.Polymer nanocomposites based on epoxy resin and ATH as a new flame retardant for CFRP:preparation and thermal characterisation[J].Journal of Materials Science,2011,46(21):7046-7055.
[41] Elbasuney S.Novel multi-component flame retardant system based on nanoscopic aluminium-trihydroxide (ATH)[J].Powder Technology,2017,305:538-545.
[42] Wenguang C,Yanlei G,Qing W,et al.Influence of the surface modification of a filler on the properties of high-impact polystyrene composites[J].Journal of Applied Polymer Science,2009,112(1):359-365.
[43] Zhang T,Liu W,Wang M,et al.Synergistic effect of an aromatic boronic acid derivative and magnesium hydroxide on the flame retardancy of epoxy resin[J].Polymer Degradation and Stability,2016,130:257-263.
[44] Chang H C,Lin H T,Lin C H,et al.Facile preparation of a phosphinated bisphenol and its low water-absorption epoxy resins for halogen-free copper clad laminates[J].Polymer Degradation and Stability,2013,98(1):102-108.
[45] Huang Z Z,Zhang X H,Qi G R.Novel halogen-free flame retardant thermoset from a hybrid hexakis (methoxymethyl) melamine/phosphorus-containing epoxy resin cured with phenol formaldehyde novolac[J].Express Polym Lett,2009,3(12):788-796.
[46] Gu J,Dang J,Wu Y,et al.Flame-retardant,thermal,mechanical and dielectric properties of structural non-halogenated epoxy resin composites[J].Polymer-Plastics Technology and Engineering,2012,51(12):1198-1203.
[47] Gu L,Chen G,Yao Y.Two novel phosphorus-nitrogen-containing halogen-free flame retardants of high performance for epoxy resin[J].Polymer Degradation and Stability,2014,108:68-75.
[48] Wang S,Xin F,Chen Y,et al.Phosphorus-nitrogen containing polymer wrapped carbon nanotubes and their flame-retardant effect on epoxy resin[J].Polymer Degradation and Stability,2016,129:133-141.
[49] Ding J,Tao Z,Zuo X,et al.Preparation and properties of halogen-free flame retardant epoxy resins with phosphorus-containing siloxanes[J].Polymer Bulletin,2009,62(6):829-841.
[50] Zhang L,Wang Y,Liu Q,et al.Synergistic effects between silicon-containing flame retardant and DOPO on flame retardancy of epoxy resins[J].Journal of Thermal Analysis and Calorimetry,2016,123(2):1343-1350.
[51] Hamciuc C,Serbezeanu D,Carja I D,et al.Effect of DOPO units and of polydimethylsiloxane segments on the properties of epoxy resins[J].Journal of Materials Science,2013,48(24):8520-8529.
[52] Hsiue G H,Wei H F,Shiao S J,et al.Chemical modification of dicyclopentadiene-based epoxy resins to improve compatibility and thermal properties[J].Polymer Degradation and Stability,2001,73(2):309-318.
基金资助
国家自然科学基金(51465036);甘肃省自然科学基金(1112RJZA019)