棉秸秆制备活性炭及其电化学性能

邱书伟1,马琰1,吴蕾1,程群淑1,曹小利2,任铁真1,2

化工新型材料 ›› 2019, Vol. 47 ›› Issue (4) : 249 -253.

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化工新型材料 ›› 2019, Vol. 47 ›› Issue (4) : 249-253.
开发与应用

棉秸秆制备活性炭及其电化学性能

    邱书伟1,马琰1,吴蕾1,程群淑1,曹小利2,任铁真1,2
作者信息 +

Preparation of ACs from cotton stalk and their electrochemical performance

  • Qiu Shuwei1, Ma Yan1, Wu Lei1, Cheng Qunshu1, Cao Xiaoli2, Ren Tiezhen1,2
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文章历史 +
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摘要

以棉秸秆为原料,KOH和K2CO3混合碱为活化剂采用两步法制备活性炭,通过X射线衍射、拉曼光谱、扫描电镜和N2吸附/脱附等手段对材料结构和形貌进行表征;通过恒电流充放电进行电化学性能测试,热重和质谱进行表面化学分析。结果表明:与单一碱活化相比,用混合碱处理的样品显示了良好的电化学性能。

Abstract

The active carbon materials (ACs) derived from cotton stalks were prepared by two-step synthesis method used the activators of KOH and mixed KOH and K2CO3.XRD,raman spectra,SEM,nitrogen adsorption-desorption isotherm were employed to analyze the structure and morphology of samples.The electrochemical properties were monitored with the cyclic voltametry and charging-discharging test.Surface chemical analysis was performed by thermogravimetry analysis coupled with mass spectrometry (TG-MS).Comparing with AC activated with KOH,the prepared sample with mixed KOH and K2CO3 displayed high electrochemical performance.

关键词

超电性能 / 棉秸秆 / 活化 / 混合KOH和K2CO3

Key words

supercapacitor / cotton stalk / activation / mixed KOH and K2CO3

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棉秸秆制备活性炭及其电化学性能[J]. 化工新型材料, 2019, 47(4): 249-253 DOI:

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基金资助

新疆自然科学基金(2016D01A009)

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