腐植酸钾-丙烯酸-丙烯酰胺保水剂的制备及吸液性能研究

李坤1,张金池2,王炜强1,徐桂明1,朱丽珺1*

化工新型材料 ›› 2019, Vol. 47 ›› Issue (4) : 125 -128.

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化工新型材料 ›› 2019, Vol. 47 ›› Issue (4) : 125-128.
科学研究

腐植酸钾-丙烯酸-丙烯酰胺保水剂的制备及吸液性能研究

    李坤1,张金池2,王炜强1,徐桂明1,朱丽珺1*
作者信息 +

Study on preparation and property of humic acid based water-conservation agent

  • Li Kun1, Zhang Jinchi2, Wang Weiqiang1, Xu Guiming1, Zhu Lijun1
Author information +
文章历史 +
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摘要

以丙烯酸、丙烯酰胺和腐植酸钾为原材料,过硫酸钾为激发剂,N,N′-亚甲基双丙烯酰胺为交联剂,采用溶液聚合法制备腐植酸基的腐植酸钾-丙烯酸-丙烯酰胺保水剂,加入腐植酸钾,既降低成本又提高保水剂的性能及增强土壤肥力,可获得保水增肥的效果。并对保水剂进行表征。研究结果表明:在单体丙烯酸质量为基准,腐植酸钾用量为3%(wt,质量分数),过硫酸钾用量为0.3%(wt,质量分数),N,N′-亚甲基双丙烯酰胺用量为0.03%(wt,质量分数),反应温度为40℃,反应时间为2h条件下,共聚合成的腐植酸基保水剂的吸去离子水倍率为821g/g,吸0.9%盐水的倍率为81g/g,保水性能较好。

Abstract

Using acrylic acid,acrylamide and potassium humic acid as raw materials,potassium persulfate as initiator,N,N′-methylenebisacrylamide as crosslinking agent,the humic acid-based agricultural water-conservation agent was prepared by solution polymerization.Adding potassium humate not only reduced costs,but also improved the performance of water-conservation agent and enhanced soil fertility,the purposes of water and fertilizer were achieved.The water-conservation agent was characterized by fourier transform infrared spectroscopy(FT-IR).The experiment showed that the dosage of potassium humate was 3%(wt,mass fraction),the amount of initiator was 0.3%(wt,mass fraction),the amount of crosslinking agent was 0.03%(wt,mass fraction),the reaction temperature 40℃,the reaction time was 2h,the deionized water absorption rate of super absorbent polymer was 821g/g,0.9% brine suction rate of 81g/g,which had good water retention.

关键词

腐植酸钾 / 保水剂 / 吸液性能

Key words

potassium humate / water-conservation agent / liquid absorption property

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腐植酸钾-丙烯酸-丙烯酰胺保水剂的制备及吸液性能研究[J]. 化工新型材料, 2019, 47(4): 125-128 DOI:

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基金资助

国家林业局林业公益性行业科研专项(201504406);江苏高校优势学科建设工程资助项目(苏政文发[2018]87号)

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