锰铁氧体/生物炭的制备及其对Pb2+吸附性能的研究

王耀1,2, 段正洋1, 石康伟2, 刘树丽1, 徐龙乾1, 何昌华1, 黄启华1, 徐晓军1*

化工新型材料 ›› 2018, Vol. 46 ›› Issue (12) : 209 -213.

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化工新型材料 ›› 2018, Vol. 46 ›› Issue (12) : 209-213.
科学研究

锰铁氧体/生物炭的制备及其对Pb2+吸附性能的研究

    王耀1,2, 段正洋1, 石康伟2, 刘树丽1, 徐龙乾1, 何昌华1, 黄启华1, 徐晓军1*
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Synthesis of biochar loaded with manganese ferrite and their performance for Pb2+ removal

  • Wang Yao1,2, Duan Zhengyang1, Shi Kangwei2, Liu Shuli1, Xu Longqian1, He Changhua1, Huang Qihua1, Xu Xiaojun1
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摘要

利用水热法合成了锰铁氧体/生物炭吸附材料(FBC),用于去除溶液中Pb2+离子。通过傅里叶变换红外光谱仪对吸附前后FBC进行表征分析,研究了溶液初始pH、溶液初始质量浓度、吸附时间等对Pb2+离子吸附的影响,探讨了吸附动力学特性和吸附等温线特性。结果表明:温度为25℃,FBC吸附Pb2+离子在120min内即可达到吸附平衡,最大吸附量为126.1mg/g;吸附过程符合准二级动力学方程和Langmuir等温吸附方程,说明FBC对Pb2+离子的吸附过程主要是单分子层化学吸附。再生吸附实验结果显示,重复利用5次后,FBC对Pb2+离子的吸附量超过70mg/g,表现出良好的再生性能。

Abstract

Biochar loaded with manganese ferrite (FBC) was prepared by hydrothermal synthesis,and applied in Pb2+ removal from synthetic wastewater.The product was characterized by fourier tansform infrared (FT-IR).Effect factors,such as pH,initial concentration of Pb2+,contact time and adsorption kinetics,adsorption isotherms on FBC adsorption for Pb2+ were investigated.The adsorption equilibrium of Pb2+ was achieved after 120min at 25℃,and the maximum adsorption capacity was 126.1mg/g.The adsorption process which followed the pseudo-second-order kinetics and Langmuir isotherm equation showed that monomolecular chemisorption played dominant role in Pb2+ adsorption.The desorption result indicated that the adsorption capacities of FBC could still reach up to 70mg/g by five repetition tests.

关键词

锰铁氧体 / 生物炭 / 吸附动力学 / 吸附等温线 / 含铅废水

Key words

manganese ferrite / biochar / adsorption kinetics / adsorption isotherm / wastewater leaded Pb2+

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锰铁氧体/生物炭的制备及其对Pb2+吸附性能的研究[J]. 化工新型材料, 2018, 46(12): 209-213 DOI:

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