热解温度对离子液体前驱体制备碳基薄膜的影响

钟虹禾, 陈友明, 郭源君

化工新型材料 ›› 2018, Vol. 46 ›› Issue (11) : 165 -168.

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化工新型材料 ›› 2018, Vol. 46 ›› Issue (11) : 165-168.
科学研究

热解温度对离子液体前驱体制备碳基薄膜的影响

    钟虹禾, 陈友明, 郭源君
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Influence of pyrolysis temperature on carbon-based film prepared by ionic liquid precursor

  • Zhong Honghe, Chen Youming, Guo Yuanjun
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摘要

利用离子液体前驱体热解工艺,选取Al2O3作为基体制备碳基薄膜,对比了不同热解温度条件下所制碳基薄膜的表面形貌、结构特征以及摩擦学性能,探究了离子液体热解法制备碳基薄膜的最佳热解温度。利用X射线衍射分析仪、X射线光电子能谱和扫描电子显微镜对碳基薄膜的结构和表面形貌进行分析,并考察薄膜的摩擦学性能。结果表明:热解温度对薄膜成分和内应力具有较大影响,薄膜成分和内应力则影响薄膜表面形貌和摩擦学性能,最佳热解温度为1000℃。

Abstract

Based on the pyrolysis of ionic liquid precursor,the carbon films were prepared on Al2O3 substrate.The surface morphology,structure and tribological properties of carbon films prepared at different pyrolysis temperatures were compared,and the optimum pyrolysis temperature were investigated.The films were analyzed by X-ray diffraction analyzer (XRD),X-ray photoelectron spectroscopy (XPS) and scanning electron microscope (SEM).The results showed that the pyrolysis temperature had great influence on the composition and internal stress of film,and the composition and internal stress affected the surface morphology and tribological properties of films.The optimum pyrolysis temperature was about 1000℃.

关键词

碳基薄膜 / 热处理 / 离子液体 / 摩擦学性能

Key words

carbon-based film / heat treatment / ionic liquid / tribological property

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热解温度对离子液体前驱体制备碳基薄膜的影响[J]. 化工新型材料, 2018, 46(11): 165-168 DOI:

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基金资助

国家自然科学基金(51205125,51275167);湖南省自然科学基金项目(2016JJ6037)

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