锂离子电池(LIBs)是目前存在的能量密度最高的二次储能电池,但是商业化的LIBs远远满足不了未来的电子能源设备需求,原因在于其负极材料石墨的理论容量只有372mAh/g。α-Fe2O3表现出很高的理论容量,能弥补石墨的不足。然而,其体积膨胀造成循环寿命和倍率性能差是当前面临的主要问题。碳纤维与α-Fe2O3复合,能够有效缓解体积膨胀,改善电化学性能。综合了碳纤维的制备方法及其在锂离子电池负极中的应用,讨论了α-Fe2O3在锂离子电池负极中应用面临的问题及解决方法,报道了碳纤维与α-Fe2O3复合材料在锂离子电池负极中应用的研究进展。
Lithium-ion batteries (LIBs) is the highest energy density of secondary energy storage batteries at present,but commercial lithium-ion batteries gradually cannot satisfy the future demand of electronic energy equipment due to low theoretical capacity of graphite cathode material (372mAh/g).α-Fe2O3 possesses high theoretical capacity compared with graphite,which can make up for the shortcoming of graphite.However,its poor cycle life and rate capability,resulting from volume expansion,are the main problems.α-Fe2O3-C fiber composites can buffer volume expansion during charge-discharge process,and improve the electrochemical performance.Carbon fiber,α-Fe2O3 and α-Fe2O3-C fiber composites as cathodes in lithium-ion batteries were reviewed in detail.
[1] Gogotsi Y.What nano can do for energy storage[J].ACS Nano,2014,8(6):5369-5371.
[2] Wang L,Tang W,Jing Y,et al.Do transition metal carbonates have greater lithium storage capability than oxides？a case study of monodisperse CoCO3 and CoO microspindles[J].ACS Applied Materials & Interfaces,2014,6(15):12346-12352.
[3] Chen Q,Lu F,Xia Y,et al.Interlayer expansion few-layered Mo-doped SnS2 nanosheets grown on carbon cloth with excellent lithium storage performance for lithium ion batteries[J].Journal of Materials Chemistry A,2017,5(8):4075-4083.
[4] Qi X,Zhang H B,Xu J,et al.A highly efficient high-pressure homogenization approach for scalable production of high-quality graphene sheets and sandwich-structured α-Fe2O3/graphene hybrids for high-performance lithium-ion batteries[J].ACS Applied Materials & Interfaces,2017,9(12):11025-11034.
[5] Hao S,Zhang B,Feng J,et al.Nanoscale ion intermixing induced activation of Fe2O3/MnO2 composites for application in lithium ion batteries[J].Journal of Materials Chemistry A,2017,5(18):8510-8518.
[6] Yang Y,Liu Y,Pu K,et al.Batteries:highly stable cycling of amorphous Li2CO3-coated α-Fe2O3 nanocrystallines prepared via a new mechanochemical strategy for Li-ion batteries[J].Advanced Functional Materials,2017,27(3):160511.
[7] Mordkovich V Z.Carbon nanofibers:a new ultrahigh-strength material for chemical technology[J].Theoretical Foundations of Chemical Engineering,2003,37(5):429-438.
[8] Deitzel J M,Kleinmeyer J,Harris D E A,et al.The effect of processing variables on the morphology of electrospun nanofibers and textiles[J].Polymer,2001,42(1):261-272.
[9] Lu X,Wang C,Wei Y.One-dimensional composite nanomaterials:synthesis by electrospinning and their applications[J].Small,2009,5(21):2349-2370.
[10] Peng S,Li L,Lee J K Y,et al.Electrospun carbon nanofibers and their hybrid composites as advanced materials for energy conversion and storage[J].Nano Energy,2016,22:361-395.
[11] Wu Y,Reddy M V,Chowdari B V R,et al.Long-term cycling studies on electrospun carbon nanofibers as anode material for lithium ion batteries[J].ACS Applied Materials & Interfaces,2013,5(22):12175-12184.
[12] Dufficy M K,Khan S A,Fedkiw P S.Hierarchical graphene-containing carbon nanofibers for lithium-ion battery anodes[J].ACS Applied Materials & Interfaces,2016,8(2):1327-1336.
[13] Nan D,Huang Z H,Lv R,et al.Nitrogen-enriched electrospun porous carbon nanofiber networks as high-performance free-standing electrode materials[J].Journal of Materials Chemistry A,2014,2(46):19678-19684.
[14] Weitz R T,Harnau L,Rauschenbach S,et al.Polymer nanofibers via nozzle-free centrifugal spinning[J].Nano Letters,2008,8(4):1187.
[15] Badrossamay M R,McIlwee H A,Goss J A,et al.Nanofiber assembly by rotary jet-spinning[J].Nano Letters,2010,10(6):2257.
[16] Yanilmaz M,Zhang X.Polymethylmethacrylate/polyacrylonitrile membranes via centrifugal spinning as separator in Li-ion batteries[J].Polymers,2015,7(4):629-643.
[17] Dirican M,Zhang X.Centrifugally-spun carbon microfibers and porous carbon microfibers as anode materials for sodium-ion batteries[J].Journal of Power Sources,2016,327:333-339.
[18] Jiang H,Ge Y,Fu K,et al.Centrifugally-spun tin-containing carbon nanofibers as anode material for lithium-ion batteries[J].Journal of Materials Science,2015,50(3):1094-1102.
[19] Nava R,Cremar L,Agubra V,et al.Centrifugal spinning:an alternative for large scale production of silicon-carbon composite nanofibers for lithium ion battery anodes[J].ACS Applied Materials & Interfaces,2016,8(43):29365-29372.
[20] Amano H,Sawaki N,Akasaki I,et al.Metalorganic vapor phase epitaxial growth of a high quality GaN film using an AlN buffer layer[J].Applied Physics Letters,1986,48(5):353-355.
[21] Endo M,Kim Y A,Hayashi T,et al.Vapor-grown carbon fibers (VGCFs):basic properties and their battery applications[J].Carbon,2001,39(9):1287-1297.
[22] Zhang C,Wang L,Wang J,et al.Self-assembly and conductive network formation of vapor-grown carbon fiber in a poly (vinylidene fluoride) melt[J].Carbon,2008,46(15):2053-2058.
[23] Wang Y,Geng F,Yue X,et al.Enhanced lithium storage performance of a self-assembled hierarchical porous Co3O4/VGCF hybrid high-capacity anode material for lithium-ion batteries[J].Ionics,2017,23(1):69-76.
[24] Jiang Y,Zhang D,Li Y,et al.Amorphous Fe2O3 as a high-capacity,high-rate and long-life anode material for lithium ion batteries[J].Nano Energy,2014,4(2):23-30.
[25] Cao K,Jiao L,Liu Y,et al.Ultra-high capacity lithium-ion batteries with hierarchical CoO nanowire clusters as binder free electrodes[J].Advanced Functional Materials,2015,25(7):1082-1089.
[26] Balogun M S,Wu Z,Luo Y,et al.High power density nitridated hematite (α-Fe2O3) nanorods as anode for high-performance flexible lithium ion batteries[J].Journal of Power Sources,2016,308:7-17.
[27] Chen M,Xia X,Yin J,et al.Construction of Co3O4 nanotubes as high-performance anode material for lithium ion batteries[J].Electrochimica Acta,2015,160:15-21.
[28] Zhang J,Huang T,Liu Z,et al.Mesoporous Fe2O3 nanoparticles as high performance anode materials for lithium-ion batteries[J].Electrochemistry Communications,2013,29:17-20.
[29] Wang G,Wang H,Cai S,et al.Synthesis and evaluation of carbon-coated Fe2O3 loaded on graphene nanosheets as an anode material for high performance lithium ion batteries[J].Journal of Power Sources,2013,239:37-44.
[30] Hang B T,Doi T,Okada S,et al.Effect of carbonaceous materials on electrochemical properties of nano-sized Fe2O3-loaded carbon as a lithium battery negative electrode[J].Journal of Power Sources,2007,174(2):493-500.
[31] Wu M S,Ou Y H,Lin Y P.Electrodeposition of iron oxide nanorods on carbon nanofiber scaffolds as an anode material for lithium-ion batteries[J].Electrochimica Acta,2010,55(9):3240-3244.
[32] Park Y,Oh M,Park J S,et al.Electrochemically deposited Fe2O3,nanorods on carbon nanofibers for free-standing anodes of lithium-ion batteries[J].Carbon,2015,94:9-17.
[33] Liu Z,Tay S W.Direct growth Fe2O3 nanorods on carbon fibers as anode materials for lithium ion batteries[J].Materials Letters,2012,72:74-77.
[34] Wu C,Li X,Li W,et al.Fe2O3 nanorods/carbon nanofibers composite:preparation and performance as anode of high rate lithium ion battery[J].Journal of Power Sources,2014,251:85-91.
[35] Zhang X,Liu H,Petnikota S,et al.Electrospun Fe2O3-carbon composite nanofibers as durable anode materials for lithium ion batteries[J].Journal of Materials Chemistry A,2014,2(28):10835-10841.
[36] Ji L,Toprakci O,Alcoutlabi M,et al.α-Fe2O3 nanoparticle-loaded carbon nanofibers as stable and high-capacity anodes for rechargeable lithium-ion batteries[J].Acs Applied Materials & Interfaces,2012,4(5):2672.
[37] Cho J S,Hong Y J,Kang Y C.Design and synthesis of bubble-nanorod-structured Fe2O3-carbon nanofibers as advanced anode material for Li-ion batteries[J].Acs Nano,2015,9(4):4026.
[38] Zhu J,Lu Y,Chen C,et al.Porous one-dimensional carbon/iron oxide composite for rechargeable lithium-ion batteries with high and stable capacity[J].Journal of Alloys & Compounds,2016,672:79-85.
PDF
(1201KB)
