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摘要
采用原位乳液聚合法合成了十二烷基苯磺酸掺杂的纳米聚苯胺/环氧丙烯酸树脂(PNAI-DBSA/EA)混合物,加入活性稀释剂、引发剂等搅拌混合均匀后,在紫外光照下固化形成纳米PNAI-DBSA/EA互穿网络导电复合膜。通过凝胶含量和电导率的测定,研究了活性稀释剂、引发剂、光照时间和PANI-DBSA含量等因素对复合膜性能的影响。结果表明:在PANI-DBSA含量为15%(wt,质量分数,下同)、引发剂2,4,6-二苯基氧化膦为4%,固化时间为40s,活性稀释剂乙氧基化三羟甲基丙烷三丙烯酸酯为50%时,导电膜凝胶含量达91.8%,导电率为8×10-6S/m。
Abstract
The nano-polyaniline/epoxy acrylate (PANI-DBSA/EA) mixture was synthesized by in-situ emulsion polymerization.Then it was added that diluted crosslinking monomer and initiating agent with stirring until well-distributed.At last,PANI-DBSA/EA interpenetrating networks conductive film was prepared through UV curing.The influence of crosslinking monomer,initiator,cure time and PANI-DBSA to the film's gel content and conductivity was investigated.The results showed that the gel content of film reached 91.8% and the conductivity was 8×10-6S/m when the content of PANI-DBSA was 15wt%,the initiating agent dosage of TPO was 4wt%,the content of crosslinking monomer EO-TMPTA was 50wt% and the curing time was 40s.
关键词
聚苯胺
/
环氧丙烯酸树脂
/
互穿网络
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光固化
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导电
Key words
polyaniline
/
epoxy acrylate (EA)
/
interpenetrating network
/
UV-curing
/
electric conduction
紫外光固化十二烷基苯磺酸掺杂的 纳米聚苯胺/环氧丙烯酸树脂 互穿网络导电复合膜的制备及性能[J].
化工新型材料, 2018, 46(10): 79-82 DOI:
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