在非离子表面活性剂的反向胶束中,用氨水作为碱式硝酸铜的沉淀剂和四乙基硅烷水解的催化剂,合成了尺寸均匀的碱式硝酸铜@二氧化硅[Cu2(OH)3NO3@SiO2]纳米盘,用扫描电子显微镜、高分辨透射电子显微镜和X射线衍射方法表征了Cu2(OH)3NO3@SiO2纳米盘的结构,讨论了其形成机理,进一步探索了其转化为氧化铜@二氧化硅(CuO@SiO2)的热稳定性。
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基金资助
中国石油化工股份有限公司合同项目(FX1502)