化工新型材料

化工新型材料 ›› 2018, Vol. 46 ›› Issue (5) : 95-98.

新材料与新技术

N-甲基-2-苯基-3,4-富勒烯基吡咯烷微米针的控制合成与表征

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Controllable synthesis and characterization of N-methyl-2-phenyl-3,4-fulleropyrrolidine derivative micro acicular

Huang Fei¹, Ma Xin¹, Hu Xueqian¹, Li Changjiang¹, Wang Xixi¹, Wei Xianwen²

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Received		Published
2016-09-08		2018-05-20
Issue Date	Revised Date
2018-07-03	2016-09-08

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摘要

以富勒烯C₆₀、苯甲醛为原料,通过1,3-偶极环加成反应合成了N-甲基-2-苯基-3,4-富勒烯基吡咯烷。首次采用表面活性剂协助自组装的方法制备出该C₆₀衍生物的微米针结构,经扫描电子显微镜(SEM)、热重分析(TGA)和荧光光谱(PL)表征。结果表明:N-甲基-2-苯基-3,4-富勒烯基吡咯烷结晶态形貌为针状结构,其形貌和晶体结构受溶剂种类、溶液浓度、醇与溶剂体积比及表面活性剂的影响。

Abstract

N-methyl-2-phenyl-3,4-fulleropyrrolidine was synthesized by [60] fullerene and benzaldehyde with 1,3-dipolar cycloaddition reaction,the structure of microacicular was fabricated for the first time using the surfactant assisted self-assembly method.The crystalline structure was characterized by scanning electron microscopy (SEM),thermal gravimetric analysis (TGA) and photoluminescence (PL) spectroscopy.The results was that the crystal morphology of N-methyl-2-phenyl-3,4-fulleropyrrolidine was micro acicular,and controlled by using different solvents,concentration,volume ratio of alcohol and solvent,and surfactant concentration.

关键词

富勒烯C₆₀衍生物 / 表面活性剂 / 微米针

Key words

[60] fullerene derivative / surfactant / micro acicular

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N-甲基-2-苯基-3,4-富勒烯基吡咯烷微米针的控制合成与表征[J]. 化工新型材料, 2018, 46(5): 95-98 DOI:

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