温度响应型TiO2-PVCL复合材料的制备及其性能研究

于在乾1,3, 谷红娟2, 唐冬雁1,3*

化工新型材料 ›› 2018, Vol. 46 ›› Issue (6) : 74 -77.

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化工新型材料 ›› 2018, Vol. 46 ›› Issue (6) : 74-77.
新材料与新技术

温度响应型TiO2-PVCL复合材料的制备及其性能研究

    于在乾1,3, 谷红娟2, 唐冬雁1,3*
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Study on fabrication and property of thermoresponsive TiO2-PVCL composite

  • Yu Zaiqian1,3, Gu Hongjuan2, Tang Dongyan1,3
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摘要

以乙烯基己内酰胺为温度响应型原料,对二氧化钛(TiO2)进行改性,利用X射线衍射、傅里叶变换红外光谱仪和扫描电子显微镜对样品的结构及形貌进行了表征,最后以罗丹明B为模型污染物,探讨了温度对TiO2-聚乙烯基己内酰胺(PVCL)光催化性能的影响。结果表明:改性之后TiO2仍为锐钛矿TiO2的晶相结构;TiO2-PVCL可以由温度控制实现相分离;40℃时TiO2-PVCL光催化降解罗丹明B的速度约为25℃时的1/7。

Abstract

The rmoresponsive poly vinyl caprolactam (PVCL) was utilized to modify TiO2.First TiO2 particles were modified with couple reagent Vinyltriethoxysilane (VETS),then PVCL polymerization was carried out in situ in TiO2 ethanol suspension.The molecular structure and morphology of obtained material were investigated with X-ray diffraction (XRD),Fourier transform infrared spectroscopy (FT-IR) and scanning electron microscope (SEM).The influence of modification on photocatalytic activity was measured using Rhodamine B as organic pollutant.Results indicated that after modification TiO2 remained its anatase crystalline.TiO2-PVCL exhibited temperature dependent phase separation.The photo catalytic degradation rate of Rhodamine B at 40℃ was 1/7 of the rate at 25℃.

关键词

二氧化钛 / 聚乙烯基己内酰胺 / 温度响应 / 热致相分离

Key words

titanium dioxide / poly vinyl caprolactam / temperature response / phase separation

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温度响应型TiO2-PVCL复合材料的制备及其性能研究[J]. 化工新型材料, 2018, 46(6): 74-77 DOI:

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