二维石墨相氮化碳纳米片的制备方法研究进展

曾炜炜, 吴赟炎, 李毅, 杨娟*

化工新型材料 ›› 2018, Vol. 46 ›› Issue (6) : 9 -11.

PDF (1148KB)
化工新型材料 ›› 2018, Vol. 46 ›› Issue (6) : 9-11.
综述与专论

二维石墨相氮化碳纳米片的制备方法研究进展

    曾炜炜, 吴赟炎, 李毅, 杨娟*
作者信息 +

Research process on preparation of two dimensional graphitic carbon nitride nanosheets

  • Zeng Weiwei, Wu Yunyan, Li Yi, Yang Juan
Author information +
文章历史 +
PDF (1174K)

摘要

石墨相氮化碳(g-C3N4)是一种不含金属的聚合物半导体光催化剂,具有独特的电子能带结构、优异的化学稳定性和热稳定性、良好的生物相容性等优点使其广泛应用于催化、生物和能源等领域。研究结果表明,与块体g-C3N4相比,二维g-C3N4纳米片不仅具有增强的本征性质,还能产生很多新的物理化学性质,拓宽了其应用领域。阐述近年来国内外层状材料g-C3N4的主要剥离方法,分析不同方法的优缺点,对其他层状材料的剥离具有借鉴意义。

Abstract

The graphitic carbon nitride (g-C3N4) is a metal-free polymer semiconductor photocatalyst with unique electronic band structure,excellent chemical and thermal stabilities,good biocompatibility and other advantages to enable it to be widely used in catalysis,biotechnology,electrochemical and other fields.The results show that the two-dimensional g-C3N4 nanosheets not only have enhanced intrinsic properties but also have some new properties compared with bulk g-C3N4,which broaden their applications.Focusing on its preparation,the main exfoliation methods of g-C3N4 in recent years,the advantages and disadvantages of different methods which was also meaningful for delamination of other layered materials were described.

关键词

石墨相氮化碳 / 纳米片 / 剥离方法

Key words

graphitic carbon nitride / nanosheet / exfoliation method

引用本文

引用格式 ▾
二维石墨相氮化碳纳米片的制备方法研究进展[J]. 化工新型材料, 2018, 46(6): 9-11 DOI:

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] Ma R,Sasaki T.Nanosheets of oxides and hydroxides:ultimate 2D charge-bearing functional crystallites[J].Adv Mater,2010,22(45):5082-5104.
[2] Mas-Balleste R,Gomez-Navarro C,Gomez-Herrero J,et al.2D materials,to graphene and beyond[J].Nanoscale,2011,3(1):20-30.
[3] Cai M,Thorpe D,Adamson D H,et al.Methods of graphite exfoliation[J].J Mater Chem,2012,22(48):24992-25002.
[4] Coleman J N,Lotya M,O'Neill A,et al.Two-dimensional nanosheets produced by liquid exfoliation of layered materials[J].Science,2011,331(6017):568-571.
[5] Wang X,Blechert S,Antonietti M.Polymeric graphitic carbon nitride for heterogeneous photocatalysis[J].ACS Catal,2012,2(8):1596-1606.
[6] Xu H,Song Y,Liu L,et al.Plasmonic-enhanced visible-light-driven photocatalytic activity of Ag-AgBr synthesized in reactable ionic liquid[J].J Chem Technol Biotechnol,2012,87(12):1626-1633.
[7] Niu P,Zhang L,Liu G,et al.Graphene-like carbon nitride nanosheets for improved photocatalytic activities[J].Adv Funct Mater,2012,22(22):4763-4770.[8] Lotsch B V,Dblinger M,Sehnert J,et al.Unmasking melon by a complementary approach employing electron diffraction,solid-state NMR spectroscopy,and theoretical calculations-structural characterization of a carbon nitride polymer[J].Chem-Eur J,2007,13(17):4969-4980.
[9] 程福星.石墨相氮化碳的剥离及其在光催化中的应用[D].杭州:浙江理工大学,2016.
[10] Wang W,Yu J C,Xia D,et al.Graphene and g-C3N4 nanosheets cowrapped elemental α-sulfur as a novel metal-free heterojunction photocatalyst for bacterial inactivation under visible-light[J].Environ Sci Technol,2013,47(15):8724-8732.
[11] 高山.无机二维超薄材料的可控制备与催化性能研究[D].合肥:中国科学技术大学,2016.
[12] Zhang X,Xie X,Wang H,et al.Enhanced photoresponsive ultrathin graphitic-phase C3N4 nanosheets for bioimaging[J].J Am Chem Soc,2012,135(1):18-21.
[13] She X,Xu H,Xu Y,et al.Exfoliated graphene-like carbon nitride in organic solvents:enhanced photocatalytic activity and highly selective and sensitive sensor for the detection of trace amounts of Cu2+[J].J Mater Chem A,2014(8):2563-2570.
[14] Yang S,Gong Y,Zhang J,et al.Exfoliated graphitic carbon nitride nanosheets as efficient catalysts for hydrogen evolution under visible light[J].Adv Mater,2013,25(17):2452-2456.
[15] Lin Q,Li L,Liang S,et al.Efficient synthesis of monolayer carbon nitride 2D nanosheet with tunable concentration and enhanced visible-light photocatalytic activities[J].Appl Catal(B),2015,163:135-142.
[16] Xu J,Zhang L,Shi R,et al.Chemical exfoliation of graphitic carbon nitride for efficient heterogeneous photocatalysis[J].J Mater Chem A,2013(46):14766-14772.
[17] Tong J,Zhang L,Li F,et al.Rapid and high-yield production of g-C3N4 nanosheets via chemical exfoliation for photocatalytic H2 evolution[J].RSC Advances,2015(107):88149-88153.
[18] Cheng F,Wang H,Dong X.The amphoteric properties of g-C3N4 nanosheets and fabrication of their relevant heterostructure photocatalysts by an electrostatic re-assembly route[J].Chem Commun,2015,51(33):7176-7179.
[19] Zhang Y,Thomas A,Antonietti M,et al.Activation of carbon nitride solids by protonation:morphology changes,enhanced ionic conductivity,and photoconduction experiments[J].J Am Chem Soc,2008,131(1):50-51.
[20] Chen Y,Huang W,He D,et al.Construction of heterostructured g-C3N4/Ag/TiO2 microspheres with enhanced photocatalysis performance under visible-light irradiation[J].ACS Appl Mater Interfaces,2014,6(16):14405-14414.
[21] Lu X,Xu K,Chen P,et al.Facile one step method realizing scalable production of g-C3N4 nanosheets and study of their photocatalytic H2 evolution activity[J].J Mater Chem A,2014(44):18924-18928.

基金资助

国家自然科学基金(51572114)

AI Summary AI Mindmap
PDF (1148KB)

912

访问

0

被引

导航
相关文章

AI思维导图

/