三聚氰胺改性脲醛树脂的研究进展

王博, 张彦华, 谭海彦, 顾继友*

化工新型材料 ›› 2018, Vol. 46 ›› Issue (2) : 234 -237.

PDF (1105KB)
化工新型材料 ›› 2018, Vol. 46 ›› Issue (2) : 234-237.
开发与应用

三聚氰胺改性脲醛树脂的研究进展

    王博, 张彦华, 谭海彦, 顾继友*
作者信息 +

Study on advance of melamine modified urea formaldehyde resin

  • Wang Bo, Zhang Yanhua, Tan Haiyan, Gu Jiyou
Author information +
文章历史 +
PDF (1131K)

摘要

综述了三聚氰胺对脲醛树脂性能的改进,包括游离甲醛、胶接强度、耐水性和稳定性方面的研究,以及反应工艺、三聚氰胺添加方式和预聚体改性脲醛树脂等因素对三聚氰胺脲醛树脂性能的影响;此外,还对三聚氰胺脲醛树脂胶粘剂的未来进行了展望。

Abstract

The improvement of the properties of urea formaldehyde resin was reviewed,including the study of free formaldehyde,bonding strength,water resistance and stability.Effects of reaction process,adding melamine,prepolymer modified urea formaldehyde resin for MUF resin.In addition,MUF resin adhesive in the future was prospected.

关键词

三聚氰胺 / 改性 / 游离甲醛 / 固化

Key words

melamine / modification / free formaldehyde / solidification

引用本文

引用格式 ▾
三聚氰胺改性脲醛树脂的研究进展[J]. 化工新型材料, 2018, 46(2): 234-237 DOI:

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] 李东光.脲醛树脂胶粘剂[M].北京:化学工业出版社,2002,54-243.
[2] Tohmura S,Inoue A,Sahari S H.Influence of the melamine content in melamine-urea-formaldehyde resins on formaldehyde emission and cured resin structure[J].Journal of Wood Science,2001,47(6):451-457.
[3] 官仕龙,李代华,刘攀攀,等.脲醛-三聚氰胺甲醛复合树脂胶粘剂的研制[J].武汉工程大学学报,2008,30(4):12-14.
[4] Tomita B,Ohyama M,Hse C Y.Synthesis of phenol-urea-formaldehyde cocondehsed resins from UF-concentrate and phenol[J].Holzforschung,1994,48:522-536.
[5] Boran S,Usta M,Ondaral S,et al.The efficiency of tannin as a formaldehyde scavenger chemical in medium density fiberboard[J].Composites Part B:Engineering,2012,43(5):2487-2491.
[6] Ye J,Qiu T,Wang H,et al.Study of glycidyl ether as a new kind of modifier for urea-formaldehyde wood adhesives[J].Journal of Applied Polymer Science,2013,128(6):4086-4094.
[7] Paiva N T,Henriques A,Cruz P,et al.Production of melamine fortified urea-formaldehyde resins with low formaldehyde emission[J].Journal of Applied Polymer Science,2012,124(3):2311-2317.
[8] Park B D,Causin V.Crystallinity and domain size of cured urea-formaldehyde resin adhesives with different formaldehyde/urea mole ratios[J].European Polymer Journal,2013,49(2):532-537.
[9] Siimer K,Kaljuvee T,Pehk T,et al.Thermal behaviour of melamine-modified urea-formaldehyde resins[J].Journal of Thermal Analysis and Calorimetry,2010,199(3):755-762.
[10] 李陆民.三聚氰胺-氧化淀粉复合改性脲醛树脂性能研究[D].哈尔滨:东北林业大学,2013.
[11] 陈代祥,邱俊,沈介发,等.E0级人造板用微游离醛脲醛树脂的制备工艺研究[J].化工新型材料,2015,43(7):239-241.
[12] 朱海龙,吴玉章,孙伟圣.三聚氰胺脲醛树脂胶粘剂的合成[J].南京林业大学学报:自然科学版,2013,37(1):173-176.
[13] 陈刚,顾继友,赵佳宁.三聚氰胺-尿素-甲醛共缩聚树脂胶粘剂的研制[J].中国胶粘剂,2010,19(7):1-4.
[14] Hse C Y,Higuchi M.Melamine-bridged alkyl resorcinol modified urea-formaldehyde resin for bonding hardwood plywood[J].Journal of Applied Polymer Science,2010,116(5):2840-2845.
[15] 李雯霞,王长荣.脲醛树脂的改性研究[J].中国建材科技,2011(3):22-24.
[16] Silva D A L,Lahr F A R,Varanda L D,et al.Environmental performance assessment of the melamine-urea-formaldehyde (MUF) resin manufacture:a case study in Brazil[J].Journal of Cleaner Production,2015,96:299-307.
[17] No B Y,Kim M G.Syntheses and properties of low-level melamine-modified urea-melamine-formaldehyde resins[J].Journal of Applied Polymer Science,2004,93(6):2559-2569.
[18] Grigsby W J,Thumm A,Carpenter J E P,et al.Investigating the extent of urea formaldehyde resin cure in medium density fiberboard:characterization of extractable resin components[J].International Journal of Adhesion and Adhesives,2014,50:50-56.
[19] 文美玲,朱丽滨,张彦华,等.三聚氰胺共聚改性脲醛树脂固化性能研究[J].中国胶粘剂,2015,24(2):20-24.
[20] 郑云武,朱丽滨,顾继友,等.三聚氰胺-尿素-甲醛共聚树脂的胶接性能[J].东北林业大学学报,2010,38(2):83-84.
[21] Paiva N T,Henriques A,Cruz P,et al.Production of melamine fortified urea-formaldehyde resins with low formaldehyde emission[J].Journal of Applied Polymer Science,2012,124(3):2311-2317.
[22] Pizzi A,Mittal K L.Handbook of adhesive technology[M].New York:Marcel Dekker,2003,67-233.
[23] 时均友,张中佳.E0级低成本三聚氰胺改性脲醛树脂的研究[J].林产工业,2011,38(2):25-27.
[24] 顾继友,赵佳宁,倪荣超.弱酸性条件起始合成MUF树脂工艺研究[J].哈尔滨工业大学学报,2009,41(5):161-164.
[25] Luo J,Zhang J,Luo J,et al.Effect of melamine allocation proportion on chemical structures and properties of melamine-urea-formaldehyde resins[J].Bio Resources,2015,10(2):3265-3276.
[26] 殷亚庆,张运明,刘幽燕,等.强酸工艺制备低甲醛释放量的MUF胶粘剂[J].中国胶粘剂,2015,24(2):15-19.
[27] 王充.三聚氰胺-尿素-甲醛树脂稳定性的研究[D].哈尔滨:东北林业大学,2010.
[28] 王磊,张斌,孙明明,等.MUF MF共缩合改性树脂胶黏剂的研究[J].化学与粘合,2013,35(5):31-33.
[29] 朱丽滨,顾继友,曹军.木材胶接用三聚氰胺改性脲醛树脂胶黏剂性能研究[J].化学与粘合,2009,31(4):1-4.
[30] 郭如振,高振华,谭海彦,等.低nF/nM三聚氰胺一甲醛低聚物对脲醛树脂性能的影响[J].粘接,2011,32(1):52-57.
[31] Grigsby W J,Thumm A,Carpenter J E P,et al.Investigating the extent of urea formaldehyde resin cure in medium density fibreboard:characterisation of extractable resin components[J].International Journal of Adhesion and Adhesives,2014,50:50-56.
[32] 闫文涛,张永娟,张雄.改性三聚氰胺-尿素-甲醛共缩聚树脂胶粘剂的合成[J].中国胶粘剂,2008,17(9):31-33.
[33] 王辉,杜官本,梁坚坤.三聚氰胺-尿素-甲醛共缩聚树脂固化过程分析[J].西北林学院学报,2013,28(4):166-169.
[34] 韩书广,吴羽飞,卢晓宁.三聚氰胺改性脲醛树脂化学结构及反应过程的13C-NMR研究[J].南京林业大学学报(自然科学版),2007,31(6):82-86.
[35] Siimer K,Kaljuvee T,Pehk T,et al.Thermal behaviour of melamine-modified urea-formaldehyde resins[J].Journal of Thermal Analysis and Calorimetry,2010,99(3):755-762.
[36] Zhang J,Wang X,Zhang S,et al.Effects of melamine addition stage on the performance and curing behavior of melamine-urea-formaldehyde (MUF) resin[J].BioResources,2013,8(4):5500-5514.
[37] Likozar B,Korošec R C,Poljanšek I,et al.Curing kinetics study of melamine-urea-formaldehyde resin[J].Journal of Thermal Analysis and Calorimetry,2012,109(3):1413-1422.
[38] Poljanšek I,Likozar B,Cuk N,et al.Curing kinetics study of melamine-urea-formaldehyde resin/liquefied wood[J].Wood Science and Technology,2013,47(2):395-409.
[39] 陈秀兰,王俊伟,朱光华,等.改性脲醛树脂中三聚氰胺添加量对中纤板防潮性能的影响[J].木材工业,2015,29(4):40-42.
[40] 刘晓颖.脲醛树脂胶接人造板耐老化性研究[D].北京:北京林业大学,2012.
[41] Mamiński M L,Pawlicki J,Zado A,et al.Glutaraldehyde-modified MUF adhesive system-improved hot water resistance[J].Holzals Roh-und Werkstoff,2007,65(3):251-253.
[42] 李改云,吴玉章,李伯涛,等.三聚氰胺改性脲醛树脂的合成及其在阻燃胶合板中的应用[J].南京林业大学学报(自然科学版),2012,36(4):103-106.
[43] Kandelbauer A,Petek P,Medved S,et al.On the performance of a melamine-urea-formaldehyde resin for decorative paper coatings[J].European Journal of Wood and Wood Products,2010,68(1):63-75.
[44] Likozar B,Korošec R C,Poljanšek I,et al.Curing kinetics study of melamine-urea-formaldehyde resin[J].Journal of Thermal Analysis and Calorimetry,2012,109(3):1413-1422.

基金资助

黑龙江省自然科学基金(C201404);黑龙江省教育厅科学技术研究项目(12533030)

AI Summary AI Mindmap
PDF (1105KB)

1070

访问

0

被引

导航
相关文章

AI思维导图

/