综述了目前硅烷封端树脂的特点、分类及合成方法,重点介绍了硅烷封端密封胶国内当前的研究进展、应用前景以及对其阻燃功能化改性的必要性。
The feature,classification and synthetic methods of silane-terminated resin were reviewed.The domestic research progress of moisture curing sealant was mainly introduced.The application prospect and necessity of flame retardance was also discussed.
[1] 晁兵,沈亚郯,耿岩,等.钢筋混凝土湿固化涂料的研究与应用[J].中国涂料,2013,28(7):21-25.
[2] 张同标,倪雅,田明明,等.硅烷改性聚合物密封剂的研究进展[J].化工时刊,2010,24(12):51-55.
[3] Yilgör E,Yilgör I.Silicone containing copolymers:synthesis,properties and applications[J].Progress in Polymer Science,2014,39(6):1165-1195
[4] Indumathi R,Edward J N.Architectural unit possessing rapid deep-section cure silicone rubber component:US,7993754[P].2011-08-09.
[5] Jukka P M,Lippo V L,Pekka K V.The effect of five silane coupling agents on the bond strength of a luting cement to a silica-coated titanium[J].Dental Materials,2007(23):1173-1180.
[6] Hashimoto K,Imaya K.Silyl-terminated polyethers for sealant use:perfor-mance updates[J].Adhesives Age,1998,41(8):18-23.
[7] 王俊.建筑用改性硅酮密封胶发展简介[J].中国建筑防水,2013(22):41.
[8] Ashby B A.Moisture curable siloxy terminated polyethers:US,3408321[P].1968-10-29.
[9] 黄活阳,何晓军,冯炬佳.环保型有机硅改性聚醚密封胶的研制[J].化学与粘合,2015(2):114-116.
[10] 杨静,毛旭华,陈世龙,等.单组分透明型有机硅改性聚醚密封胶的制备[J].中国建筑防水,2011(10):30-33.
[11] 曾军,龚建玲,胡新嵩,等.新型单组分透明硅烷封端聚醚密封胶的研制[J].中国建筑防水,2016(13):18-21.
[12] 黄活阳,刘同科,方铭中.透明硅烷改性聚氨酯密封胶的研制[J].中国建筑防水,2014(3):68-70.
[13] 许雨晴,胡孝勇,柯勇,等.单组分有机硅改性聚醚密封材料的制备及性能[J].工程塑料应用,2015,43(11):27-30.
[14] 方铭中,黄活阳,刘同科.高性能SPU建筑用密封胶的研制[J].粘接,2014,35(8):52-55.
[15] 黄活阳,张剑,刘同科,等.一种高强度有机硅改性聚氨酯密封胶的研制[J].粘接,2015,36(10):64-67.
[16] 王翠花,刘鹏,赵瑞,等.双组分硅烷改性聚醚密封胶的制备及研究[J].粘接,2014,35(9):50-52.
[17] 杜秀才,石耀东,王虎,等.硅烷改性聚氨酯的制备及异氰酸酯结构对粘合性能影响的研究[J].化工新型材料,2016,44(3):50-52.
[18] 王文荣,刘伟区,苏倩倩.纳米蒙脱土插层硅烷化聚氨酯密封胶的研制[J].新型建筑材料,2007,34(8):29-32.
[19] 史小萌,戴海林,马启元.硅烷化聚氨酯及其密封胶的制备和性能研究[J].热固性树脂,2003,18(1):10-14.
[20] 张剑,黄活阳,王奉平.有机硅改性聚醚密封胶的耐水性能研究[J].有机硅材料,2016,30(3)217-221.
[21] Isayama K,Hatano I.Vulcanizable silylether terminated polymer:US,3971751[P].1976-07-27.
[22] Zander L,Loth H,Burmeister M P,et al.Low-modulus silyated polyurethanes:US,20150284610[P].2015-10-08.
[23] Huang M,Kumar V,Thomas L I M,et al.Process for the preparation of silylated polyurethane polymers using titanium-containing and zirconium-containing catalysts:US,9321878[P].2016-04-26.
[24] Boghossian R.Solvent-based primer solution based on silylated polyurethane (SPUR) chemistry for polycarbonate substrates:US,9040622[P].2015-05-26.
[25] Huang M,Cruse R W,Falk B,et al.Moisture curable silylated polymer compositions containing reactive modifiers:US,8809479[P].2014-08-19.
[26] Ramakrishnan I,Landon S J,Williams D A,et al.Silylated polyurethane/ polyorganosiloxane blend and sealant composition and fumed silica composition containing same:US,9200160[P].2015-12-01.
[27] Huang M W,Lacroix C.Moisture-curable silylated polymer possessing improved storage stability:US,8138297[P].2012-03-20.
[28] Huang M W,Nesheiwat J I.Moisture-curable silylated polymer resin composition:US,8207252[P].2012-06-26.
[29] Vyakaranam K R,Zhang L,Minnikanti V S,et al.Compression set property in silylated polymers:US,9181428[P].2015-11-10.
[30] 王澜,姚双华,陈文洁.《建筑用阻燃密封胶》标准解读[J].中国建筑防水,2011(10):22-24.
[31] 欧育湘.实用阻燃技术[M].北京:化学工业出版社,2002,3.
[32] 李向梅,杨荣杰.本质阻燃高分子研究进展[J].中国塑料,2006,19(10):9-16.