锂离子电池MLi2Ti6O14(M=2Na,Sr,Ba)负极材料的研究进展

朱彦荣, 刘思远, 诸荣孙, 伊廷锋*

化工新型材料 ›› 2018, Vol. 46 ›› Issue (2) : 35 -39.

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化工新型材料 ›› 2018, Vol. 46 ›› Issue (2) : 35-39.
综述与专论

锂离子电池MLi2Ti6O14(M=2Na,Sr,Ba)负极材料的研究进展

    朱彦荣, 刘思远, 诸荣孙, 伊廷锋*
作者信息 +

Recent development of MLi2Ti6O14(M=2Na,Sr,Ba) cathode material for lithium-ionic battery

  • Zhu Yanrong, Liu Siyuan, Zhu Rongsun, Yi Tingfeng
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文章历史 +
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摘要

钛酸盐材料由于具有循环寿命长、廉价、安全性好等特点,成为锂离子电池负极材料研究开发的重点。与Li4Ti5O12材料相比,MLi2Ti6O14(M=2Na,Sr,Ba)负极材料具有更低的电位平台。因此,作为全电池的负极材料具有更高的工作电压和能量密度,有望成为动力锂离子电池的热门负极材料,具有更好的应用前景。介绍了MLi2Ti6O14负极材料的结构,综述了近年来MLi2Ti6O14负极材料的合成及掺杂改性方面的研究进展,重点对MLi2Ti6O14负极材料的制备方法和掺杂进行了总结和探讨,并对MLi2Ti6O14负极材料的发展前景进行了展望。

Abstract

Lithium titanate materials become the focus of research and development for cathode material of lithium-ionic battery because of its characteristics such as long cycle life,cheap and good safety.MLi2Ti6O14(M=2Na,Sr,Ba) cathode material have lower potential platform than Li4Ti5O12.Hence,as the cathode material of full battery,MLi2Ti6O14 has higher working voltage and energy density than those of Li4Ti5O12.Thereby MLi2Ti6O14 hopefully becomes popular cathode material of power lithium-ionic battery,and it has better application prospect than that of Li4Ti5O12.The structure of MLi2Ti6O14 was introduced,and the recent progress of synthesis and doping modification were reviewed.Emphasis was placed on the summary and discussion of preparation and doping method for MLi2Ti6O14,and the development prospect was also viewed.

关键词

锂离子电池 / 负极材料 / MLi2Ti6O14(M=2Na,Sr,Ba)

Key words

lithium-ionic battery / cathode material / MLi2Ti6O14(M=2Na,Sr,Ba)

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锂离子电池MLi2Ti6O14(M=2Na,Sr,Ba)负极材料的研究进展[J]. 化工新型材料, 2018, 46(2): 35-39 DOI:

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参考文献

[1] 杨建文,颜波,叶璟,等.锂钛氧嵌锂负极材料的研究进展[J].稀有金属材料与工程,2015,44(1):255-260.
[2] Zhou X,Ma L,Yang J,et al.Properties of graphitized boron-doped coal-based coke powders as anode for lithium-ion batteries[J].J Electroanal Chem,2013,698:39-44.
[3] 潘志国,高标,甘乾,等.多孔VN纳米带锂离子电池负极材料研究[J].稀有金属材料与工程,2015,44(9):2318-2321.
[4] Shyamal K D,Bhattacharyya A J.High lithium sorage in mixed crystallographic phase nanotubes od titania and carbon-titania[J].J Phys Chem C,2009,113(40):17367-17371.
[5] Yi T F,Yang S Y,Xie Y.Recent advances of Li4Ti5O12 as a promising next generation anode material for high power lithium-ion batteries[J].J Mater Chem A,2015,3(11):5750-5777.
[6] Pasquier A D,Laforgue A,Simon P.Li4Ti5O12/poly(methyl)thiophene asymmetric hybrid electrochemical device[J].J Power Sources,2004,125(1):95-102.
[7] Dambournet D,Belharouak I,Amine K.MLi2Ti6O14(M=Sr,Ba,2Na) lithium insertion titante materials:a comparative study[J].Inorg Chem,2010,49(6):2822-2826.
[8] Koseva I,Chaminade J P,Gravereau P,et al.A new family of isostructural titanates,MLi2Ti6O14(M=Sr,Ba,Pb)[J].J Alloy Compd,2005,389(1/2):47-54.
[9] Wang P,Li P,Yi T F,et al.Enhanced lithium storage capability of sodium lithium titanate via lithium-site doping[J].J Power Sources,2015,297:283-294.
[10] Shu J,Wu K,Wang P,et al.Lithiation and delithiation behavior of sodium lithium titanate anode[J].Electrochim Acta,2015,173:595-606.
[11] Li P,Wu K,Wang P,et al.Preparation,electrochemical characterization and in-situ kinetic observation of Na2Li2Ti6O14 as anode material for lithium ion batteries[J].Ceram Int,2015,41(10):14508-14516.
[12] Liu J,Li Y,Wang X,et al.Synthesis process investigation and electrochemical performance characterization of SrLi2Ti6O14 by ex situ XRD[J].J Alloy Compd,2013,581:236-240.
[13] Lin X,Li P,Wang P,et al.SrLi2Ti6O14:a probable host material for high performance lithium storage[J].Electrochim Acta,2015,180:831-844.
[14] Liu J,Wu B,Wang X,et al.Study of the Li+ intercalation/de-intercalation behavior of SrLi2Ti6O14 by in-situ techniques[J].J Power Sources,2016,301:362-368.
[15] 伊廷锋,岳彩波,朱彦荣,等.动力锂离子电池正极材料的研究评述[J].稀有金属材料与工程,2009,38(9):1687-1692.
[16] 沙鸥,赵敏寿,翟静,等.锂离子电池新型正极材料LiFePO4的研究进展[J].稀有金属材与工程,2009,38(11):2060-2064.
[17] Wu K,Wang D,Lin X,et al.Comparative study of Na2Li2Ti6O14 prepared by different methods as advanced anode material for lithium-ion batteries[J].J Electroanal Chem,2014,717-718:10-16.
[18] 常龙娇,罗绍华,王志远,等.高电压正极材料LiMnPO4的研究进展[J].稀有金属材料与工程,2014,43(9):2297-2304.
[19] 苗翠,周佳,孙淑清,等.LiFePO4液相合成法的最新研究进展[J].稀有金属材料与工程,2013,42(S2):379-382.
[20] 王国庆,吕菲,白莹,等.复合熔盐法合成Li4Ti5O12及其电化学性能研究[J].功能材料,2008,39(7):1158-1165.
[21] 裴先茹,王晓东,张顺利,等.熔融法制备纳米管Li-Ti-O化合物及其表征[J].无机化学学报,2006,22(12):2135-2140.
[22] Yin S Y,Feng C Q,Wu S J,et al.Molten salt synthesis of sodium lithium titanium oxide anode material for lithium ion batteries[J].J Alloy Compd,2015,642:1-6.
[23] 龚雪,杨金龙,姜玉林,等.静电纺丝技术在锂离子动力电池中的应用[J].化学进展,2014,26(1):41-47.
[24] 张永龙,胡学步,徐云兰,等.不同形貌结构Li4Ti5O12负极材料的最新进展[J].化学学报,2013,71(10):1341-1353.
[25] Li H,Shen L,Ding B,et al.Ultralong SrLi2Ti6O14 nanowires composed of single-crystalline nanoparticles:Promising candidates for high-power lithium ions batteries[J].Nano Energy,2015,13:18-27.
[26] Dambournet D,Belharouak I,Ma J,et al.Template-assisted synthesis of high packing density SrLi2Ti6O14 for use as anode in 2.7-V lithium-ion battery[J].J Power Sources,2011,196(5):2871-2874.
[27] Liu J,Sun X,Li Y,et al.Electrochemical performance of LiCoO2/SrLi2Ti6O14 batteries for high-power applications[J].J Power Sources,2014,245:371-376.
[28] 邓海福,聂平,聂平,等.锂离子电池用高电位正极材料LiNi0.5Mn1.5O4[J].化学进展,2014,26(6):939-949.
[29] 万洋,郑荞佶,赁敦敏,等.锂离子电池正极材料磷酸锰锂研究进展[J].化学学报,2014,72(5):537-551.
[30] Zhao B,Ran R,Liu M.A comprehensive review of Li4Ti5O12-based electrodes for lithium-ion batteries:The latest advancements and future perspectives[J].Mater Sci Eng R,2015,98:1-5.
[31] Wang P,Li P,Yi T F,et al.Improved lithium storage performance of lithium sodium titanate anode by titanium site substitution with aluminum[J].J Power Sources,2015,293:33-41.
[32] Lao M,Li P,Wang P,et al.Advanced electrochemical performance of Li1.95Al0.05Na2Ti6O14 anode material for lithium ion batteries[J].Electrochim Acta,2015,176:694-704.
[33] Wu K,Shu J,Lin X,et al.Phase composition and electrochemical performance of sodium lithium titanates as anode materials for lithium rechargeable batteries[J].J Power Sources,2015,275:419-428.
[34] Wang W,Gu L,Qian H,et al.Carbon-coated silicon nanotube arrays on carbon cloth as a hybrid anode for lithium-ion batteries[J].J Power Sources,2016,307:410-415.
[35] 韩飞,陆安慧,李文翠.结构可控的炭基材料在锂离子电池中的应用[J].化学进展,2012,24(12):2443-2456.
[36] Li H,Zhou H.Enhancing the performance of Li-ion batteries by carbon-coating:present and future[J].Chem Commun,2012,48(9):1201-1217.
[37] Wu K,Shu J,Lin X,et al.Enhanced electrochemical performance of sodium lithium titanate by coating various carbons[J].J Power Sources,2014,272:283-290.
[38] Krajewski M,Michalska M,Hamankiewicz B,et al.Li4Ti5O12 modified with Ag nanoparticles as an advanced anode material in lithium-ion batteries[J].J Power Sources,2014,245:764-771.
[39] Cai Y,Wang H E,Jin J,et al.Hierarchically structured porous TiO2 spheres constructed by interconnected nanorods as high performance anodes for lithium ion batteries[J].Chem Eng J,2015,281,844-851.
[40] 吴平,杜宁,张辉,等.锂离子电池用α-Fe2O3-Ag复合纳米棒负极材料的制备及储锂性能[J].高等学校化学学报,2013,34(4):668-673.
[41] Lin X,Wang P,Li P,et al.Improved the lithium storage capability of BaLi2Ti6O14 by electroless silver coating[J].Electrochim Acta,2015,186:24-33.

基金资助

国家自然科学基金(51404002、51774002);高校优秀青年人才支持计划重点项目(gxyqZD2016066);安徽省自然科学基金项目(1508085MB25);安徽省安徽工业大学优秀创新团队项目(TD201202);大学生创新创业训练计划资助项目(201610360157)

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