高分子渗透汽化脱水膜一般采用具有刚性链且能与水形成离子-偶极作用或氢键的强亲水性高分子材料,存在渗透性和选择性互为制约的关系,即“Trade-off”效应。将无机纳米材料引入到聚合物中制备有机-无机渗透汽化复合膜是解决这一效应的有效途径之一。综述了碳纳米材料、纳米氧化物颗粒、纳米分子筛等在复合渗透汽化脱水膜领域的应用研究进展。这些纳米材料的填充,有助于提高复合膜的机械稳定性、亲水性、渗透选择性及渗透通量等。此外,对于高分子基体,要制得反“Trade-off”效应的渗透汽化有机-无机复合脱水膜,提出了填充剂需尽量满足对水分子具有选择性透过等4个条件。
Polymeric pervaporation membranes for dehydration were generally fabricated by strong hydrophilic polymer materials,which has a rigid chain and can form ion-dipole interaction or hydrogen bond.However,they are the mutual restraint relationship of permeability and selectivity between each other,which is named “Trade-off” effect.Inorganic nanomaterials were introduced into polymers to prepare organic-inorganic pervaporation nanocomposite membranes,which is one of the effective ways to solve this problem.The researches of nanocomposite pervaporation membranes for dehydration involving nanoparticles such as carbon nanoparticles,nano-oxide particles,nano-molecular sieve particles,etc.were summarized.The filling of these nanomaterials helped to improve the mechanical stability,hydrophilicity,selectivity and permeation flux of composite membranes significantly.In addition,four required conditions were proposed for the fillers to prepare the organic-inorganic nanocomposite pervaporation membranes with anti-“Trade-off” effect.
[1] 徐南平,高从堦,金万勤.中国膜科学技术的创新进展[J].中国工程科学,2014,16(12):4-9.
[2] Jurgen G,Jurgen L,Antje J,et al.A modified UNIFAC(Dortmund) model.3.Revision and extension[J].Industrial & Engineering Chemistry Research,1998,37(12):4876-4882.
[3] Freeman B D.Basis of permeability/selectivity trade-off relations in polymeric gas separation membrane[J].Macromolecules,1999,32(2):375-380.
[4] 彭福兵.反Trade-off效应的有机-无机杂化渗透蒸发膜的研究[D].天津:天津大学,2005.
[5] 王熙大,王志宁,高从锴.纳米复合膜在膜分离领域的研究进展[J].应用化学,2014,31(2):123-132.
[6] Penkova A V,Acquah S F A,Dmitrenko M E,et al.Transport properties of crosslinked fullerenol-PVA membranes[J].Carbon,2014,76(76):446-450.
[7] Penkova A V,Polotskaya G A,Toikka A M,et al.Structure and pervaporation properties of poly(phenylene-iso-phtalamide) membranes modified by fullerene C60[J].Macromolecular Materials and Engineering,2009,294(6/7):432-440.
[8] 施国忠,吴礼光,邱实,等.壳聚糖/碳纳米管杂化膜的制备及其乙醇/水体系的渗透汽化分离[J].膜科学与技术,2011,31(4):54-59.
[9] Shirazi Y,Tofighy M A,Mohammadi T.Synthesis and characterization of carbon nanotubes/poly vinyl alcohol nanocomposite membranes for dehydration of isopropanol[J].Journal of Membrane Science,2011,378(1/2):551-561.
[10] Yeang Q W,Zein S H S,Sulong A B,et al.Comparison of the pervaporation performance of various types of carbon nanotube-based nanocomposites in the dehydration of acetone[J].Separation and Purification Technology,2013,107(4):252-263.
[11] Panahian S,Raisi A,Aroujalian A.Multilayer mixed matrix membranes containing modified-MWCNTs for dehydration of alcohol by pervaporation process[J].Desalination,2015,355:45-55.
[12] Falath W,Sabir A,Jacob K I.Highly improved reverse osmosis performance of novel PVA/DGEBA cross-linked membranes by incorporation of Pluronic F-127 and MWCNTs for water desalination[J].Desalination,2016,397:53-66.
[13] Geim A K,Novoselov K S.The rise of graphene[J].Nature Materials,2007,6(3):183-191.
[14] Katsnelson M I,Novoselov K S,Geim A K.Chiral tunnelling and the klein paradox in graphene[J].Nature Physics,2006,2(9):620-625.
[15] Tang Y P,Paulc D P,Chung T S.Free-standing graphene oxide thin films assembled by a pressurized ultrafiltration method for dehydration of ethanol[J].Journal of Membrane Science,2014,458(9):199-208.
[16] Tsou C H,An Q F,Lo S C,et al.Effect of microstructure of graphene oxide fabricated through different self-assembly techniques on 1-butanol dehydration[J].Journal of Membrane Science,2015,477(1):93-100.
[17] Zhao J,Zhu Y W,Pan F S,et al.Fabricating graphene oxide-based ultrathin hybrid membrane for pervaporation dehydration via layer-by-layer self-assembly driven by multiple interactions[J].Journal of Membrane Science,2015,487(1):162-172.
[18] Chen X F,Liu G P,Zhang H Y,et al.Fabrication of graphene oxide composite membranes and their application for pervaporation dehydration of butanol[J].Chinese Journal of Chemical Engineering,2015,23(7):1102-1109.
[19] Dai S Q,Jiang Y Y,Wang T,et al.Enhanced performance of polyimide hybrid membranes for benzene separation by incorporating three-dimensional silver-graphene oxide[J].Journal of Colloid and Interface Science,2016,478:145-154.
[20] Liu X H,Sun Y,Deng X H.Studies on the pervaporation membrane of permeation water from methanol/water mixture[J].Journal of Membrane Science,2008,325(1):192-198.
[21] 张玲,孙元,邓新华,等.分离甲醇水溶液复合渗透汽化膜的制备与研究[J].天津工业大学学报,2010,29(2):1-4.
[22] Wang J H,Tsuru T.Cobalt-doped silica membranes for pervaporation dehydration of ethanol/water solutions[J].Journal of Membrane Science,2011,369(1):13-19.
[23] Wang X R,Yang Z Z,Yu C L,et al.Preparation of T-type zeolite membranes using a dip-coating seeding suspension containing colloidal SiO2[J].Microporous and Mesoporous Materials,2014,197(10):17-25.
[24] Sairam M,Patil M B,Veerapur R S,et al.Novel dense poly(vinyl alcohol)-TiO2 mixed matrix membranes for pervaporation separation of water-isopropanol mixtures at 30℃[J].Journal of Membrane Science,2006,281(1/2):95-102.
[25] Gestel T V,Sebold D,Kruidhof H,et al.ZrO2 and TiO2 membranes for nanofiltration and pervaporation:Part 2.Development of ZrO2 and TiO2 toplayers for pervaporation[J].Journal of Membrane Science,2008,318(1/2):413-421.
[26] Yang D,Li J,Jiang Z Y.Chitosan/ TiO2 nanocomposite pervaporation membranes for ethanol dehydration[J].Chemical Engineering Science,2009,64(13):3130-3137.
[27] 温馨,马晓华,许振良,等.具有催化与渗透汽化双功能的纳米TiO2和Al2O3填充复合膜性能[J].膜科学与技术,2012,32(3):1-5.
[28] Zhao C H,Jiang Z Y,Zhao J,et al.High pervaporation dehydration performance of the composite membrane with an ultrathin alginate/poly(acrylic acid)-Fe3O4 active layer[J].Industrial and Engineering Chemistry Research,2014,53(4):1606-1616.
[29] Olukman M,Sanli O,Solak E K.Synthesis of magnetite in poly(vinyl alcohol) matrix and its use in separation of acetone/water mixtures via pervaporation,vapor permeation with and without temperature difference methods[J].Vacuum,2015,120:107-115.
[30] Olukman M,Şanli O.A novel in situ synthesized magnetite containing acrylonitrile and 2-hydroxyethyl methacrylate grafted poly(vinyl alcohol) nanocomposite membranes for pervaporation separation of acetone/water mixtures[J].Chemical Engineering and Processing:Process Intensification,2015,98:60-70.
[31] Gao B X,Jiang Z Y,Zhao C H,et al.Enhanced pervaporative performance of hybrid membranes containing Fe3O4@CNT nanofillers[J].Journal of Membrane Science,2015,492(2):230-241.
[32] Lind M L,Jeong B H,Subramani A,et al.Effect of mobile cation on zeolite-polyamide thin film nanocomposite membranes[J].Journal of Materials Research,2009,24(5):1624-1631.
[33] Jeong B H,Hoek E M V,Yan Y S,et al.Interfacial polymerization of thin film nanocomposites:a new concept for reverse osmosis membranes[J].Journal of Membrane Science,2007,294(1/2):1-7.
[34] Sato K,Sugimoto K,Kyotani T,et al.Laminated mordenite/ZSM-5 hybrid membranes by one-step synthesis:Preparation,membrane microstructure and pervaporation performance[J].Microporous and Mesoporous Materials,2012,160:85-96.
[35] Zhou R F,Hu L L,Zhang Y J,et al.Synthesis of oriented zeolite T membranes from clear solutions and their pervaporation properties[J].Microporous and Mesoporous Materials,2013,174:81-89.
[36] Shao J,Zhan Z Y,Li J G,et al.Zeolite NaA membranes supported on alumina hollow fibers:Effect of support resistances on pervaporation performance[J].Journal of Membrane Science,2014,451(1):10-17.
[37] Wang N X,Shi G X,Jing Gao,et al.MCM-41@ZIF-8/PDMS hybrid membranes with micro- and nanoscaled hierarchical structure for alcohol permselective pervaporation[J].Separation and Purification Technology,2015,153:146-155.
[38] Premakshi H G,Ramesh K,Kariduraganavar M Y.Modification of crosslinked chitosan membrane using NaY zeolite for pervaporation separation of water-isopropanol mixtures[J].Chemical Engineering Research and Design,2015,94(3):32-43.
[39] Veerapur R S,Patil M B,Gucasi K B,et al.Poly(vinyl alcohol)-zeolite T mixed matrix composite membranes for pervaporation separation of water+1,4-dioxane mixtures[J].Separation Purification and Technology,2008,58(3):377-385.
[40] Salehian P,Chua M L,Askari M,et al.In situ regulation of micro-pore to design high performance polyimide membranes for pervaporation dehydration of isopropanol[J].Journal of Membrane Science,2015,493(1):299-310.
基金资助
国家自然科学基金(21406082、21476094);江苏省自然科学基金(BK20171268);淮安市科技支撑项目(HAG201609);江苏省高校“青蓝工程”资助项目
PDF
(1169KB)
