化工新型材料

化工新型材料 ›› 2018, Vol. 46 ›› Issue (1) : 38-41.

综述与专论

量子点太阳电池中半导体氧化膜与敏化剂结构调控研究进展

作者信息 +

Recent development in semiconductor oxide film and sensitizer of quantum dot-sensitized solar cells

Zhang Chenguang, Fan Runzhou, Yin Ximing, Xiong Yan

Author information +

文章历史 +

Received
2016-10-09
Issue Date	Revised Date
2018-03-01	2016-10-09

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摘要

新一代太阳电池——量子点敏化太阳电池(QDSSC)由于具有吸收广、多激子和高稳定等独特优势近年来已得到初步发展。从量子点敏化太阳电池的原理入手综述了QDSSC中光阳极半导体氧化膜、量子点敏化剂的种类及两者间的结构调控、量子点制备方法这三大模块的研究进展,从原理上对光阳极半导体氧化膜、敏化剂的性能进行了简要合理的解释,并结合现存的问题提出了今后的发展方向。

Abstract

Recently,a new generation of solar cells—quantum dot-sensitized solar cells (QDSSC)—have got preliminary development due to the unique advantages of absorb wide,multi-exciton and high stability.The research of semiconductor oxide film,species of quantum dots and preparation of quantum dot sensitizer of QDSSCs was reviewed.The performance and operational principle of semiconductor oxide and the sensitizer were stated.The existing problems raised in the future development were discussed.

关键词

量子点敏化太阳电池 / 光阳极 / 半导体氧化膜 / 敏化剂

Key words

quantum dot-sensitized solar cells (QDSSC) / photo anode / semiconductor oxide / sensitizer

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量子点太阳电池中半导体氧化膜与敏化剂结构调控研究进展[J]. 化工新型材料, 2018, 46(1): 38-41 DOI:

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参考文献

原文顺序 | 出版日期 | 本文引用

[1] 李怀辉,王小平,王丽军,等.硅半导体太阳能电池进展[J].材料导报,2011(19):49-53.
[2] 宋鑫.量子点敏化太阳能电池制备及光电转换性能的改进[D].天津:天津大学,2010.
[3] Tian J,Cao G.Semiconductor quantum dot-sensitized solar cells[J].Nano Reviews,2013,4:22578-22583.
[4] Kamat P V.Quantum dot solar cells.Semiconductor nanocrystals as light harvesters[J].The Journal of Physical Chemistry C,2008,112(48):18737-18742.
[5] Villanueva J,Jang S R,Halverson A F,et al.Trap-free transport in ordered and disordered TiO₂ nanostructures[J].Nano Letters,2014,14(5):2305-2309.
[6] Kopidakis N,Neale N R,Zhu K,et al.Spatial location of transport-limiting traps in TiO₂ nanoparticle films in dye-sensitized solar cells[J].Applied Physics Letters,2005,87(20):202106-202110.
[7] Deng J,Wang M,Yang C,et al.TiO₂ nanoparticle/ZnO nanowire hybrid photoanode for enhanced quantum dot-sensitized solar cell performance[J].RSC Advances,2014,4(77):41141-41147.
[8] Lee W,Lee J,Lee S,et al.Enhanced charge collection and reduced recombination of CdS/TiO₂ quantum-dots sensitized solar cells in the presence of single-walled carbon nanotubes[J].Applied Physics Letters,2008,92(15):153510-153515.
[9] Zhao J,Wu J,Yu F,et al.Improving the photovoltaic performance of cadmium sulfide quantum dots-sensitized solar cell by graphene/titaniaphotoanode[J].Electrochimica Acta,2013,96(5):110-116.
[10] Zhang Q X,Chen G P,Yang Y Y,et al.Toward highly efficient CdS/CdSequantum dots-sensitized solar cells incorporating with ordered photoanodes on transparent conductive substrates[J].Physical Chemistry Chemical Physics,2012,14(18):6479-6486.
[11] Han H,Sudhagar P,Song T,et al.Three dimensional-TiO₂ nanotube array photoanode architectures assembled on a thin hollow nanofibrous backbone and their performance in quantum dot-sensitized solar cells[J].Chemical Communications,2013,49(27):2810-2812.
[12] Zhu F,Dong H,Wang Y,et al.Dual-functional hetero-structured TiO₂nanotrees composed of rutile trunks and anatase branches for improved performance of quantum dot-sensitized solar cells[J].Physical Chemistry Chemical Physics,2013,15(41):17798-17803.
[13] Nozik A J.Excition multiplication and relaxatin dynamics in quantum dots:application to ultrahigh-efficiency solar photon conversion[J].Inorganic Chemistry,2005,44(20):6893-6899.
[14] Shockley W,Queisser H.Detailed balance limit of efficiency of p-n junction solar cells[J].Applied Physics Letters,1961,32(3):510-520.
[15] Shen X,Jia J,Lin Y,et al.Enhanced performance of CdTe quantum dot sensitized solar cell via anion exchanges[J].Journal of Power Sources,2015,277:215-221.
[16] Jumabekov A N,Siegler T D,Cordes N,et al.Comparison of solid-state quantum-dot-sensitized solar cells with exsitu and in situ grown PbS quantum dots[J].The Journal of Physical Chemistry C,2014,118(45):25853-25862.
[17] Shen H,Jiao X,Oron D,et al.Efficient electron injection in non-toxic silver sulfide (Ag₂S) sensitized solar cells[J].Journal of Power Sources,2013,240(240):8-13.
[18] Tubtimtae A,Lee M W,Wang G J.Ag₂Se quantum-dot sensitized solar cells for full solar spectrum light harvesting[J].Journal of Power Sources,2011,196(15):6603-6608.
[19] Jara D H,Yoon S J,Stamplecoskie K G,et al.Size-dependent photovoltaic performance of CuInS₂ quantum dot-sensitized solar cells[J].Chemistry of Materials,2014,26(24):7221-7228.
[20] Peng Z,Liu Y,Zhao Y,et al.Efficiency enhancement of TiO₂ nanodendrite array electrodes in CuInS₂ quantum dot sensitized solar cells[J].Electrochimica Acta,2013,111(6):755-761.
[21] Chang C C,Chen J K,Chen C P,et al.Synthesis of eco-friendly CuInS₂ quantum dot-sensitized solar cells by a combined exsitu/in situ growth approach[J].ACS Applied Materials & Interfaces,2013,5(21):11296-11306.
[22] Li W,Pan Z,Zhong X.CuInSe₂ and CuInSe₂-ZnS based high efficiency “green”quantum dot sensitized solar cells[J].Journal of Materials Chemistry A,2015,3(4):1649-1655.
[23] Huang P C,Yang W C,Lee M W.AgBiS₂ semiconductor-sensitized solar cells[J].The Journal of Physical Chemistry C,2013,117(36):18308-18314.
[24] LeeY L,LoY S.Highly efficient quatum-dot-sensitized solar cell based on co-sensitized of CdS/CdSe[J].Advanced Functional Materials,2009,19(4):340-345.
[25] Santra P K,Kamat P V.Mn-doped quantum dot sensitized solar cells:a strategy to boost efficiency over 5%[J].Journal of the American Chemical Society,2012,134(5):2508-2511.
[26] Li T L,Lee Y L,Teng H.High performance quantum dot-sensitized solar cells based on sensitization with CuInS₂quantum dots/CdS heterostructure[J].Energy & Environmental Science,2012,5(1):5315-5324.
[27] Pan Z,Zhao K,Wang J,et al.Near infrared absorption of CdSe_xTe_1-x alloyed quantum dot sensitized solar cells with more than 6% efficiency and high stability[J].ACS Nano,2013,7(6):5215-5222.
[28] Yu X Y,Lei B X,Kuang D B,et al.Highly efficient CdTe/CdS quantum dot sensitized solar cells fabricated by a one-step linker assisted chemical bath deposition[J].Chemical Science,2011,2(7):1396-1400.
[29] Song X,Wang M,Shi Y,et al.In situ hydrothermal growth of CdSe(S) nanocrystals on mesoporous TiO₂ films for quantum dot-sensitized solar cells[J].Electrochimica Acta,2012,81(11):260-267.
[30] Guijarro N,Lana-Villarreal T,Shen Q,et al.Sensitization of titanium dioxide photoanodes with cadmium selenide quantum dots prepared by SILAR:photoelectro chemical and carrier dynamics studies[J].The Journal of Physical Chemistry C,2010,114(50):21928-21937.
[31] Zhu G,Lv T,Pan L K,et al.All spray pyrolysis deposited CdS sensitized ZnO films for quantum dot-sensitized solar cells[J].Alloys Compd,2011,509(2):362-365.
[32] Shin K,Seok S I,Im S H,et al.CdS or CdSe decorated TiO₂ nanotube arrays from spray pyrolysis deposition:Se in photoelectron chemical cells[J].Chemical Communications,2010,46(14):2385-2387.
[33] Salant A,Shalom M,Hod I,et al.Quantum dot sensitized solar cells with improved efficiency prepared using electrophoretic deposition[J].ACS Nano,2010,4(10):5962-5968.
[34] Yu P R,Zhu K,Norman A G,et al.ocrystalline TiO₂ solar cells sensitized with InAs quantum dots[J].Physical Chemistry Chemical Physics,2006,110(50):25451-25454.