合成了具有聚合性能的紫外吸收剂单体2-羟基-4-丙烯酯基二苯甲酮(HAB),采用辐射工艺制备了抗老化涤纶织物。探究了不同辐射量和单体浓度对增重率的影响。优化的整理工艺为:辐射量为260kGy,单体质量浓度为10%,增重率可以达到(7.5±0.2)%。接枝后的织物用红外光谱和扫描电镜进行表征,并测试了抗老化性能。结果表明,UPF值达235±15,经过300h的紫外照射后强力保留率可以达到(68.3±2.5)%。UPF值较传统工艺接枝改性织物提高了38,是未整理的织物的4.5倍;光照后织物的强力保留率较未整理织物提高了30%,比传统方法接枝改性织物提高了8%。经电子辐射工艺改性的涤纶织物具有更好的抗老化性能。
Irradiation process was employed in aging modification of PET with synthesized UV absorber HAB as momomer.The effects of irradiation dose and monomer concentration on weight gain of PET were studied.The optimum finish condition:260kGy of irradiation dose,10wt% of monomer concentration,and weight gain can reached at (7.5±0.2)%.The grafted fabrics were characterized by FT-IR spectra and SEM,and the aging-resistent property was also measured.UPF value of grafted fabrics was 235±15.The retention rate of breaking strength was (68.3±2.5)%.UPF value of grafted fabrics with EB process increased by 38 as aganist traditional method,and increased 4.5 times than untreated sample.After UV-light irradiation,the tensile strength of grafted fabrics with EB process increased 30% and 8%,respectively,compared with untreated sample and treated fabrics with traditional method.The midified PET fabrics showed better anti-aging property.
[1] 李海青.汽车座椅织物耐日晒色牢度低成本,高性能的研究[D].上海:东华大学,2009.
[2] Ichihashi M,Ueda M,Budiyanto A,et al.UV-induced skin damage[J].Toxicology,2003,189(1):21-39.
[3] Entezaria M,Shamelib A,Hekmatic M,et al.Synthesis and application of novel phenols as UV absorber in dyes and polymers[J].Trends Mod Chem,2012(5):14-19.
[4] 陈维国.染色涤纶织物耐光色牢度增进剂的研制,应用及机理[D].上海:东华大学,2010.
[5] 郝会雷.新型二苯甲酮类光稳定剂的合成及性能研究[D].延吉:延边大学,2009.
[6] 王云明,唐炳涛,马威,等.紫外吸收染料研究进展[J].有机化学,2010,30(3):330-337.
[7] 易志文.聚酯纤维的抗紫外老化特性研究[D].上海:东华大学,2015.
[8] 宁培森,王玉民,汪铮,等.二苯甲酮类紫外线吸收剂的发展趋势[J].聚合物与助剂,2012,(4):1-9.
[9] 韩栋,李娜娜,封严,等.纺织材料抗紫外改性的研究进展[J].纺织学报,2014,35(4):160-164.
[10] Lulli G,Albertazzi E,Bianconi M,et al.Nuclear instruments and methods in physics research section[J].B:Beam Interactions with Materials and Atoms,2001,148:573.
[11] Ping X,Wang M,Xuewu G.Surface modification of poly (ethylene terephthalate)(PET) film by gamma-ray induced grafting of poly (acrylic acid) and its application in antibacterial hybrid film[J].Radiation Physics and Chemistry,2011,80(4):567-572.
[12] Ibrahim M S,El Salmawi K M,Ibrahim S M.Electron-beam modification of textile fabrics for hydrophilic finishing[J].Applied Surface Science,2005,241(3):309-320.
[13] 刘今强,王栋,邵建中.HEMA在羊毛纤维上的电子束辐照接枝[J].纺织学报,2002,23(6):5-7.
[14] 秦吉喜,胡志勇,朱海林,等.含二苯甲酮类高分子水溶性紫外线吸收剂的合成与表征[J].应用化工,2009,38(3):418-420.
[15] 秦吉喜.水溶性高分子紫外线吸收剂的合成与性能[D].太原:中北大学,2009.
[16] Sano Y,Konda M,Lee C W,et al.A facile antistatic modification of polyester fiber based on ion-exchange reaction of sulfonate-modified polyester and various cationic surfactants[J].Die Angewandte Makromolekulare Chemie,1997,251(1):181-191.
基金资助
江苏省高校优势学科建设工程资助项目
PDF
