纳米硫氰酸亚铜制备与应用

叶明富1,王标1,孔祥荣2,王成1,许立信1,金玲1

化工新型材料 ›› 2017, Vol. 45 ›› Issue (9) : 229 -231.

PDF
化工新型材料 ›› 2017, Vol. 45 ›› Issue (9) : 229-231.
开发与应用

纳米硫氰酸亚铜制备与应用

    叶明富1,王标1,孔祥荣2,王成1,许立信1,金玲1
作者信息 +

Research progress on preparation and application of nano CuSCN

  • Ye Mingfu1, Wang Biao1, Kong Xiangrong2, Wang Cheng1, Xu Lixin1, Jin Ling1
Author information +
文章历史 +
PDF

摘要

综述了纳米硫氰酸亚铜的制备方法,包括液相沉淀法、电沉积法、连续离子层吸附与反应法、前驱体法等,及其在太阳能电池、防污涂料和电存储材料等方面的应用,并对其应用前景进行了展望。

Abstract

The preparation methods of copper thiocyanate(CuSCN),including liquid-phase preciptation,electrodeposition,successive ionic layer adsorption and reaction method,template-assisted method and so on were presented.The application prospect of nano CuSCN in solar cell,antifouling paint and inorganic semiconductor material were reviewed.

关键词

CuSCN / 液相沉淀法 / 电沉积法 / 连续离子层吸附与反应法 / 应用

Key words

CuSCN / liquid-phase preciptation / electrodeposition / successive ionic layer adsorption and reaction method / application

引用本文

引用格式 ▾
纳米硫氰酸亚铜制备与应用[J]. 化工新型材料, 2017, 45(9): 229-231 DOI:

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] Lu Y F,Ye M F,Liu F,et al.Overview on the synthesis and applications of cadmium hydroxide nanomaterials[J].J Iran Chem Soc,2015,12(10):1829-1840.
[2] 逯亚飞,王成,叶明富,等.CuO纳米材料的制备及其应用研究进展[J].应用化工,2014,43(10):1884-1890.
[3] 许立信,王成,叶明富,等.Cu2S纳米材料的制备及应用研究进展[J].材料导报,2016,30(5):40-44.
[4] 王成,刘峰,叶明富,等.纳米氢氧化铜制备研究进展[J].安徽工业大学学报(自然科学版),2015,32(2):127-132.
[5] 杨慧芳.纳米CuSCN的制备及其在复合涂料中的应用研究[D].天津:天津大学,2007.
[6] 武卫兵,靳正国,华缜,等.高透光p型CuSCN薄膜的电沉积制备及机理研究[J].无机化学学报,2005,21(3):383-388.
[7] Vetere V F,Pérez M C,Romagnoli R,et al.Solubility and toxic effect of the cuprous thiocyanate antifouling pigment on barnacle larvae[J].J Coating Technolol,1997,69(866):39-45.
[8] Dmitry A,Cyril C G,Raul S,et al.Properties of electrodeposited CuSCN 2D layers and nanowires influenced by their mixed domain structure[J].J Phys Chem C,2014,118(29):16095-16103.
[9] Chavhan S,Miguel O,Grande H J,et al.Organo-metal halide perovskite-based solar cells with CuSCN as the inorganic hole selective contact[J].J Mater Chem A,2014,2(32):12754-12760.
[10] 巩翠翠,胡志强,苏岩,等.CuSCN纳米粉体的制备及表征[J].大连工业大学学报,2009,28(3):188-191.
[11] 杨慧芳,肖凤娟,顾业强,等.液相沉淀法制备硫氰酸亚铜纳米颗粒[J].人工晶体学报,2004,33(6):965-968.
[12] 王魁,李晶,杨林.新型涂料防腐剂硫氰酸亚铜纳米颗粒的制备和表征[J].河南师范大学学报(自然科学版),2010,38(3):90-92.
[13] Yang M,Li J J.Synthesis and characterizations of monodispersed nanospheres of β-CuSCN using CuO as the precursor[J].J Disper Sci Technol,2009,30(3):361-364.
[14] Liu S L,Shi Q Q,Tong J B,et al.A facile approach for the synthesis of uniform hollow β-CuSCN microspheres[J].J Exp Nanosci,2013,8(6):625-632.
[15] 靳正国,刘晓新,步绍静,等.SILAR法制备无机化合物薄膜[J].材料导报,2003,17(3):66-68.
[16] 石亚平,高燕,孙承月,等.连续离子层吸附与反应法制备超薄功能膜及应用[J].宇航材料工艺,2010,30(4):5-9.
[17] 高相东,李效民,于伟东,等.CuSCN薄膜的室温液相沉积及其光学性能[J].无机材料学报,2008,23(3):535-539.
[18] 诸葛福伟,高相东,李效民,等.连续式离子层吸附与反应法沉积CuSCN薄膜及其微观结构、光学特性研究[J].无机材料学报,2009,24(1):8-12.
[19] 武卫兵,靳正国,华缜,等.电化学沉积法制备CuSCN固体电解质薄膜的研究[J].太阳能学报,2006,27(7):141-145.[20] 华缜,靳正国,武卫兵,等.Cu(SCN)2-水系电沉积制备CuSCN薄膜[J].应用化学,2005,22(2):138-141.
[21] 武卫兵,靳正国,华缜,等.高透光p型CuSCN薄膜的电沉积制备及机理研究[J].无机化学学报,2005,21(3):383-388.
[22] Cyril C G,Rual S,Solenn B,et al.Room temperature template-free electrodeposition of CuSCN nanowires[J].Electrochem Commun,2012,24:1-4.
[23] Huang M C,Wang T H,Tseng Y T,et al.Influence of annealing on microstructural and photoelectrochemical characteristics of CuSCN thin films via electrochemical process[J].J Alloy Compd,2015,622:669-675.
[24] 王文清.α-CuSCN纳米球和纳米管的合成与表征[J].化学世界,2009,50(12):705-707.
[25] 杨惠芳,申星梅,肖凤娟,等.利用无机分散剂制备纳米硫氰酸亚铜粉体[J].天津大学学报,2006,39(12):1475-1478.
[26] Chai B,Wang M,Wang Z,et al.Synthesis and characterization of ball-in-ball CuSCN hollow architecture[J].Mater Lett,2013,93:56-59.
[27] Xu J S,Xue D F.Fabrication of upended taper-shaped cuprous thiocyanate arrays on a copper surface at room temperature[J].J Phys Chem B,2006,110(23):11232-11236.
[28] Li J J,Li K F,Qiao R,et al.Template-free synthesis of CuSCN and Cu2S crystallites with a facile hydrothermal method at different temperatures[J].Mat Sci Semicon Proc,2011,14(3/4):306-310.
[29] 严翔翔.有机-金属复合光存储介质及形状可控CuSCN颗粒的研究[D].上海:复旦大学,2012.
[30] Chaudhary N,Chaudhary R,Kesari J P,et al.Copper thiocyanate (CuSCN):an efficient solution-processable hole transporting layer in organic solar cells[J].J Mater Chem C,2015,3(45):11886-11892.

基金资助

国家自然科学基金项目(21376005);安徽省自然科学基金项目(1608085QF156);高校优秀中青年骨干人才国内外访学研修重点项目(gxfxZD2016053);安徽工业大学研究生创新研究基金(2015022)

AI Summary AI Mindmap
PDF

345

访问

0

被引

导航
相关文章

AI思维导图

/