一种新型聚磷腈离子交换膜制备与污水处理应用研究

贺敏岚1,2,3,4,李伟1,2,张瑞红1,4,刘旭明1,2,李聪敏1

化工新型材料 ›› 2017, Vol. 45 ›› Issue (9) : 221 -222.

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化工新型材料 ›› 2017, Vol. 45 ›› Issue (9) : 221-222.
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一种新型聚磷腈离子交换膜制备与污水处理应用研究

    贺敏岚1,2,3,4,李伟1,2,张瑞红1,4,刘旭明1,2,李聪敏1
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Study on preparation of a new type of ion exchange membrane and its application in wastewater treatment

  • He Minlan1,2,3,4, Li Wei1,2, Zhang Ruihong1,4, Liu Xuming1,2, Li Congmin1
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摘要

成功合成了一种新型全氟磺酸型聚磷腈离子交换膜。将该膜作阳离子交换膜对污水进行电渗析处理,废水的氨氮浓度从3955mg/L降低到105mg/L,下降了约97.3%,具有较好的去除效率。

Abstract

A novel type of polyphosphazene with perfluoroalky sulfonic acid group was synthesized and prepared to ion exchange membrane.The membrane was used as anion membrane in electrodialysis device for sewage treatment.After the process by the membrane,the concentration of ammonia nitrogen in wastewater decreased by about 97.3%,from 3955mg/L to 105mg/L.This result showed a good removal efficiency.

关键词

电渗析 / 聚磷腈 / 污水处理 / 全氟磺酸

Key words

electrodialysis / polyphosphazene / sewage treatment / perfluoroalky sulfonic acid

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一种新型聚磷腈离子交换膜制备与污水处理应用研究[J]. 化工新型材料, 2017, 45(9): 221-222 DOI:

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参考文献

[1] Allcock H R,Fitzpatrick R J,Salvati L.Sulfonation of (aryloxy)phosphazenes and (arylamino)phosphazenes-small-molecular compounds,polymers and surfaces[J].Chemistry of Materials,1991,3(6):1120-1132.
[2] Allcock H R,Wood R M.Design and synthesis of ion-conductive polyphosphazenes for fuel cell applications:review[J].Journal of Polymer Science Part B-Polymer Physics,2006,44(16):2358-2368.
[3] Sohn Y S C,Yang H,Baek H,et al.Synthesis and properties of low molecular weight polyphosphazenes[J].Macromolecules,1995,28(22):3-5.
[4] Yoshimura K,Iwasaki K.Aromatic polymer with pendant perfluoroalkyl sulfonic acid for fuel cell applications[J].Macromolecules,2009,42(23):9302-9306.
[5] He M L,Xu H L,Dong Y,et al.Synthesis and characterization of perfluoroalky sulfonic acid functionalized polyphosphazene for proton-conducting membranes[J].Journal of Macromolecular Science,Part A Pure and Applied Chemistry,2014,51(1):55-62.
[6] Ismail A F,Zubir N,Nasef M M,et al.Physico-chemical study of sulfonated polystyrene pore-filled electrolyte membranes by electrons induced grafting[J].Journal of Membrane Science,2005,254(1/2):189-196.
[7] 徐昌松,程少民,张荣环,等.电渗析法处理联碱废水的研究[J].纯碱工业,2000(1):10-13.

基金资助

国家科技支撑计划课题(2012BAC25B06);北京市科技计划课题(D131104002013006)

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