聚硫醚橡胶仅含有单硫键,比传统聚硫橡胶的双硫键键能更高,因此耐热性更佳,其在航空油箱密封剂领域的应用逐渐扩大。综述了近年来国内外关于聚硫醚橡胶的研究现状,主要关于聚硫醚的合成路线及多种官能团封端,以及聚硫醚制备成密封剂的性能的研究。
Comparing with traditional polysulfide with double-sulfur bond,polythioether with single-sulfur bond has better thermal resistance,so it has gradually been applied in air craft fuel tank field.Recent developments of synthesis of polythioether and derivatives were summarized.The application of polythioether rubber in sealant materials was also introduced.
[1] Matsui T,Miwa Y.Detection of a new crosslinking and properties of liquid polysulfide polymer[J].Journal of Applied Polymer Science,1999,71(1):59-66.
[2] Lowe G B.The cure chemistry of polysulfides[J].International Journal of Adhesion & Adhesives,1997(17):345-348.
[3] Giannis S,Adamsa R D,Clark L J,et al.The use of a modified peel specimen to assess the peel resistance of aircraft fuel tank sealants[J].International Journal of Adhesion & Adhesives,2008(28):158-175.
[4] Clark L J,Cosman M A.Use of Permapols P3.1 polymers and epoxy resins in the formulation of aerospace sealants[J].International Journal of Adhesion & Adhesives,2003(23):343-348.
[5] Barber J W,Hanhela P J,Huang R H,et al.Effect of temperature on the storage life of polysulfide aircraft sealants[J].Polymer Testing,1990(9):291-313.
[6] 刘嘉,苏正涛.航空橡胶与密封材料[M].北京:国防工业出版社,2014,8-12.
[7] 李锦.聚硫代醚聚合物的研究进展[J].弹性体,2015,25(5):85-87.
[8] 刘星北,王慧珊,章谏正,等.国内外航空聚硫密封剂产品概况[J].粘接,2014(3):84-87.
[9] 宋英红,杨晓东,吴松华.液体聚硫橡胶的改性技术研究进展[J].合成橡胶工业,2013,36(2):158-160.
[10] Hakam S,Jack H W,Morris W E.Liquid polythioethers:US,4366307A[P].1982-12-28.
[11] Jasinski F,Lobry E,Tarablsi B,et al.Light-mediated thiol-ene polymerization in miniemulsion:a fast route to semicrystalline polysulfide nanoparticles[J].Macro Letters,2014(3):958-962.
[12] 曹守德,蔺艳琴,潘广萍,等.氨基树脂在改性聚硫密封剂中的应用研究[J].航空材料学报,2013(23):159-161.
[13] 张宪武,赫萍,石阳秋.改性聚硫橡胶合成研究[J].弹性体,1999,9(1):19-23.
[14] Doherty Z J,Suzanna D,Weldon J D,et al.Composition and method for producing fuel resistant liquid polythioether polymers with good low temperature flexibility:US,6172179B2[P].2001-01-09.
[15] SAE AMS 3277,Sealing compound,polythioether rubber fast curing for integral fuel tanks and general purpose,intermittent use to 360℉(182℃)[S].2010.
[16] Kalaee M,Mahdavi H.Preparation of synthesized sulfide polymer through phase-transfer catalyzed polycondensation of ethylene dibromide and sodium tetrasulfide:characterization,thermal and rheological properties[J].Journal of Sulfur Chemistry,2014,35(4):373-381.
[17] Ameduri B,Berrada K,Boutevin B,et al.Synthesis of telechelic monodispersed dithiols[J].Polymer Bulletin,1991,26(4):377-382.
[18] Hobbs S J,Mccollum G J,Anderson L G,et al.Terminal-modified difunctional sulfur-containing polymers,compositions thereof and methods of use:US,8889800B2[P].2014-11-18.
[19] Hobbs S J,Mccollum G J,Cai Juexiao,et al.Multifunctional sulfur-containing polymers,compositions thereof and methods of use:US,9382447B2[P].2016-07-05.
[20] Hobbs S J,Marfi Ito,Cai Juexiao,et al.Flexible polyamines,flexible amine-terminated adducts,compositions thereof and methods of use:US,9422467B2[P].2016-08-23.
[21] Anderson L G,Cai Juexiao,Marfi Ito,et al.Michael addition curing chemistries for sulfur-containing polymer compositions:US,9365378B2[P].2016-06-14.
[22] Cai Juexiao,Anderson L G,Marfi Ito,et al.Michael addition curing chemistries for sulfur-containing polymer compositions employing bis(sulfonyl)alkanols:US,9394405B2[P].2016-07-19.
[23] Rao C,Cai Juexiao,Lin Renhe.Sulfone-containing polythioethers,compositions thereof,and methods of synthesis:US,9540540B2[P].2017-01-10.
[24] Cai Juexiao,Anderson L G,Lin Renhe.Controlled release amine-catelyzed,Michael addition-curable sulfur-containing polymer compositions:US,9499668B2[P].2016-11-22.
[25] Anderson L G,Cai Juexiao,Bowman M P,et al.Phosphine-catalyzed,Michael addition-curable sulfur-containing polymer compositions:US,9328275B2[P].2016-05-03.
[26] Rao C,Deng Jun,Lin Renhe.Metal ligand-containing prepolymers,methods of synthesis,and compositions thereof:US,9382462B2[P].2016-07-05.
[27] 赫平,张全成,马忠.耐高温聚硫代醚橡胶的合成研究[J].弹性体,2012,22(3):65-67.
[28] 刘刚,秦蓬波,吴松华.新型耐高温耐油聚硫代醚密封剂的研究[J].中国胶粘剂,2009,18(8):36-38.
[29] 章谏正,秦蓬波,刘刚,等.环氧树脂硫化聚硫醚密封剂的性能研究[J].中国胶粘剂,2011,20(4):36-39.