二硫化碳改性松针对Cu2+的吸附性能研究

石晓丹,张庆乐*,吕务娟,魏永腾,林翠玉

化工新型材料 ›› 2017, Vol. 45 ›› Issue (9) : 159 -161.

PDF
化工新型材料 ›› 2017, Vol. 45 ›› Issue (9) : 159-161.
科学研究

二硫化碳改性松针对Cu2+的吸附性能研究

    石晓丹,张庆乐*,吕务娟,魏永腾,林翠玉
作者信息 +

Adsorption characteristics of Cu2+ in aqueous solution on carbon disulfide-modified pine needle

  • Shi Xiaodan, Zhang Qingle, Lv Wujuan, Wei Yongteng, Lin Cuiyu
Author information +
文章历史 +
PDF

摘要

利用二硫化碳(CS2)改性松针作为新型生物材料,对溶液中Cu2+进行吸附去除。结果表明:当pH=7、吸附剂剂量为0.4g、反应时间为60min时,该材料对100mL 50mg/L含铜废水的去除率达94.7%;伪二级动力学方程能较好地拟合该材料对Cu2+的吸附动力学过程,揭示了其吸附主要是离子交换吸附;Langmuir方程能较好地拟合该材料对Cu2+的等温吸附过程,表明其吸附主要是单分子层吸附。

Abstract

Carbon disulfide-modified pine needle as a novel biosorbent was investigated to remove Cu2+ from aqueous solution in batch experiment.The results indicated that when the solution pH was 7.0,adsorbate dosage was 0.4g,contact time was 60min,100mL wastewater containing 50mg/L Cu2+,the removal rate of material was 94.7%.The kinetic adsorption process of Cu2+ on pine needle modified by carbon disulfide was mainly ion exchange adsorption.Langmuir equation could simulate the material process of isothermal adsorption of Cu2+,indicating its adsorption was monolayer adsorption.

关键词

二硫化碳改性松针 / Cu2+ / 吸附动力学

Key words

pine needle modified by carbon disulfide / cupric ion / adsorption kinetics

引用本文

引用格式 ▾
二硫化碳改性松针对Cu2+的吸附性能研究[J]. 化工新型材料, 2017, 45(9): 159-161 DOI:

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] Zhu C S,Wang L P,Chen W B.Removal of Cu(Ⅱ)from aqueous solution by agricultural by-product:peanut hull[J].Journal of Hazardous Materials,2009,85(17):1-8.
[2] 易秀.铜对生物有机体的毒性及抗性机理[J].农业环境保护,1997,16(4):187-189.
[3] 张永兰,王友保.农田杂草对铜污染土壤修复的研究[J].河北农业科学,2009,13(1):44-45.
[4] Suksabye P,Nakajima A,Thirave tyan P,et al.Mechanism of Cr[Ⅵ] adsorption by coir pith studied by ESR and adsorption kinetic[J].Journal of Hazardous Materials,2009,161(2-3):1103-1108.
[5] Garg U K,Kaur M P,Garg V K,et al.Removal of hexavalent chromium from aqueous solution by agricultural waste biomass[J].Journal of Hazardous Materials,2007,140(10):60-68.
[6] Ofomaja A E,Naidoo E B,Modise S J.Removal of copper(Ⅱ) from aqueous solution by pineand base modified pine cone power as biosorbent[J].Journal of Hazardous Materials,2009,21(6):1-9.
[7] Rocha C G,Zaia D A M,Alfaya R V D S,et al.Use of rice straw as biosorbent for removal of Cu(Ⅱ) ion in industrial effluents[J].Journal of Hazardous Materials,2009,166(1):383-388.
[8] 李红萍.改性松针粉对废水中染料及重金属离子的脱除研究[D].郑州:郑州大学,2011.[9] 秦建桥,夏北成,赵鹏,等.镉在五节芒(Miscanthus floridulus)不同种群细胞中的分布及化学形态[J].生态环境学报,2009,18(3):817-823.
[10] 白雪,陈亚慧,耿凯,等.镉在三色堇中的积累及亚细胞与化学形态分布[J].环境科学学报,2014,34(6):1600-1605.
[11] 毕跃峰,郑晓珂,刘宏民,等.马尾松松针化学成分的研究[J].药学学报,2001,36(11):832-835.
[12] 李璐,杨朝晖,孙珮石,等.基于响应面优化条件下柚皮对Pb2+的吸附[J].环境科学报,2009,29(7):1426-1433.
[13] 国家环境保护总局.GB 8978—1996污水综合排放标准[M].北京:中国标准出版社,1996,3.
[14] Ho Y S,Mckay G.Pseudo-second order model for sorption process[J].Process Biochemistry,1999,34(5):451-465.
[15] Kumar Y P,King P,Prasad V S R K.Equilibrim and kinetic studies for the biosorpt in system of copper(Ⅱ) ion from aqueous solution using tectonagrandisl leaves powder[J].Journal of the American Chemical Socity,2006,137(2):1211-1217.
[16] Baccar R,bouzid J,Feki M.A montiel preraration of activated carbon from Tunisian live-waste cakes and its application for adsorption of heavy metal ions[J].J Hazard Mater,2009,162(2-3):1522-1529.
[17] Crini G,Badot P.Application of chitosan,a natural aminopoly saccharide,for dye removal from adequeous solution by adsorption process using batch studies:a review of recent literature[J].Prog Polym Sci,2008,33(4):399-477.
[18] Wang K S,Huang L C,Lee H S,et al.Phytoextraction of cadmium by ipomoea aquatic (water spinach) in hydroponic solution:effects of cadmium speciation[J].Chemosphere,2008,72(4):666-672.

基金资助

国家级大学生科技创新计划(201510439050)

AI Summary AI Mindmap
PDF

357

访问

0

被引

导航
相关文章

AI思维导图

/