全固态Li-O2(air)电池研究进展

卢佳垚,厉英*,孔亚州

化工新型材料 ›› 2017, Vol. 45 ›› Issue (9) : 43 -45.

PDF
化工新型材料 ›› 2017, Vol. 45 ›› Issue (9) : 43-45.
综述与专论

全固态Li-O2(air)电池研究进展

    卢佳垚,厉英*,孔亚州
作者信息 +

Research progress of all solid Li-O2 (air) battery

  • Lu Jiayao, Li Ying, Kong Yazhou
Author information +
文章历史 +
PDF

摘要

锂空气电池[Li-O2(air)]具有极高的能量密度,引起了越来越多的关注。全固态Li-O2(air)电池使用不易燃的无机固体锂离子导体材料作为电池电解质,大大提高了电池的安全性能。研发具有高离子电导率、高稳定性的固体电解质对全固态Li-O2(air)电池的发展起到极大的推动作用。此外,研发高性能正极催化剂、采取合理的技术手段提高电极/固体电解质界面性能也是全固态Li-O2(air)电池面临的挑战。分别从正极、负极、固体电解质以及电极/电解质界面等方面对全固态Li-O2(air)电池进行综述。

Abstract

Li-O2 (air) battery has large theoretical specific energy density and received more and more attention.The battery use non-flammable inorganic solid-state electrolytes,it can improve the safety of batteries.The research and development of solid electrolytes with high ionic conductivity and high stability play a great role in improve the performence of battery.In addition,the research and development of high performance anode catalyst is important,which can improve the interfacial property of electrode/solid electrolyte.Herein,all-solid-state Li-O2(air) battery was reviewed from the anode,cathode,solid-electrolyte and interfacial property between them.

关键词

Li-O2(air)电池 / 固体电解质 / 正极 / 界面性能

Key words

Li-O2(air) battery / solid-state electrolyte / anode / interfacial property

引用本文

引用格式 ▾
全固态Li-O2(air)电池研究进展[J]. 化工新型材料, 2017, 45(9): 43-45 DOI:

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] Wang Y,He P,Zhou H.A lithium-air capacitor-battery based on a hybrid electrolyte[J].Energy & Environmental Science,2011,4(12):4994-4999.
[2] Bruce P G,Freunberger S A,Hardwick L J,et al.Li-O2 and Li-S batteries with high energy storage[J].Nature Materials,2012,11(1):19-29.
[3] Sun Y.Lithium ion conducting membranes for lithium-air batteries[J].Nano Energy,2013,2(5):801-816.
[4] Read J.Characterization of the lithium/oxygen organic electrolyte battery[J].Journal of the Electrochemical Society,2002,149(9):A1190-A1195.
[5] McCloskey B D,Scheffler R,Speidel A,et al.On the efficacy of electrocatalysis in nonaqueous Li-O2 batteries[J].Journal of the American Chemical Society,2011,133(45):18038-18041.
[6] Freunberger S A,Chen Y,Peng Z,et al.Reactions in the rechargeable lithium-O2 battery with alkyl carbonate electrolytes[J].Journal of the American Chemical Society,2011,133(20):8040-8047.
[7] Freunberger S A,Chen Y,Drewett N E,et al.The lithium-oxygen battery with ether-based electrolytes[J].Angewandte Chemie International Edition,2011,50(37):8609-8613.
[8] Zhu D,Zhang L,Song M,et al.An in situ formed Pd nanolayer as a bifunctional catalyst for Li-air batteries in ambient or simulated air[J].Chem,Commun,2013,49(83):9573-9575.
[9] Knauth P.Inorganic solid Li ion conductors:an overview[J].Solid State Ionics,2009,180(14):911-916.
[10] Kumar J,Kumar B.Development of membranes and a study of their interfaces for rechargeable lithium-air battery[J].Journal of Power Sources,2009,194(2):1113-1119.
[11] Kumar B,Kumar J,Leese R,et al.A solid-state,rechargeable,long cycle life lithium-air battery[J].Journal of The Electrochemical Society,2010,157(1):A50-A54.
[12] Kotobuki M,Kanamura K,Sato Y,et al.Fabrication of all-solid-state lithium battery with lithium metal anode using Al2O3-added Li7La3Zr2O12 solid electrolyte[J].Journal of Power Sources,2011,196(18):7750-7754.
[13] Hassoun J,Jung H G,Lee D J,et al.A metal-free,lithium-ion oxygen battery:a step forward to safety in lithium-air batteries[J].Nano Letters,2012,12(11):5775-5779.
[14] Li F,Kitaura H,Zhou H.The pursuit of rechargeable solid-state Li-air batteries[J].Energy & Environmental Science,2013,6(8):2302-2311.
[15] Liu T,Leskes M,Yu W,et al.Cycling Li-O2 batteries via LiOH formation and decomposition[J].Science,2015,350(6260):530-533.
[16] Thotiyl M M O,Freunberger S A,Peng Z,et al.A stable cathode for the aprotic Li-O2 battery[J].Nature Materials,2013,12(11):1050-1056.
[17] Wang X,Zhu D,Song M,et al.A Li-O2/air battery using an inorganic solid-state air cathode[J].Acs Appl Mater Interfaces,2014,6(14):11204-11210.
[18] Kamaya N,Homma K,Yamakawa Y,et al.A lithium superionic conductor[J].Nature Materials,2011,10(9):682-686.
[19] Takada K.Progress and prospective of solid-state lithium batteries[J].Acta Materialia,2013,61(3):759-770.
[20] Liu Y,Li B,Kitaura H,et al.Fabrication and performance of all-solid-state li-air battery with SWCNTs/LAGP cathode[J].ACS Applied Materials & Interfaces,2015,7(31):17307-17310.
[21] Kitaura H,Zhou H.Electrochemical performance of solid-state lithium-air batteries using carbon nanotube catalyst in the air electrode[J].Advanced Energy Materials,2012,2(7):889-894.
[22] Mariappan C R,Gellert M,Yada C,et al.Grain boundary resistance of fast lithium ion conductors:comparison between a lithium-ion conductive Li-Al-Ti-P-O-type glass ceramic and a Li1.5Al0.5Ge1.5P3O12 ceramic[J].Electrochemistry Communications,2012,14(1):25-28.
[23] Liu S,Imanishi N,Zhang T,et al.Lithium dendrite formation in Li/poly (ethylene oxide)-lithium bis (trifluoromethanesulfonyl) imide and N-methyl-N-propylpiperidinium bis (trifluoromethanesulfonyl) imide/Li cells[J].Journal of The Electrochemical Society,2010,157(10):A1092-A1098.
[24] Kitaura H,Zhou H.Electrochemical performance and reaction mechanism of all-solid-state lithium-air batteries composed of lithium,Li1+xAlyGe2-y(PO4)3 solid electrolyte and carbon nanotube air electrode[J].Energy & Environmental Science,2012,5(10):9077-9084.
[25] Zhu X B,Zhao T S,Wei Z H,et al.A novel solid-state Li-O2 battery with an integrated electrolyte and cathode structure[J].Energy & Environmental Science,2015,8(9):2782-2790.

基金资助

国家自然科学基金项目(51474057)

AI Summary AI Mindmap
PDF

414

访问

0

被引

导航
相关文章

AI思维导图

/