化工新型材料

化工新型材料 ›› 2017, Vol. 45 ›› Issue (9) : 37-39.

综述与专论

表面活性剂辅助合成不同形貌纳米CeO₂研究进展

作者信息 +

Advance on surfactant assisted synthesis of nano CeO₂ with different morphology

Dou Zhengjie, Zheng Yuying, Fang Yanxiong

Author information +

文章历史 +

Received		Published
2016-06-06		2017-10-19
Issue Date	Revised Date
2017-10-19	2016-06-06

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摘要

氧化铈(CeO₂)是一种重要的稀土金属氧化物,由于其独特的结构和优良的性能广泛应用于各个领域。CeO₂的形貌对其性能和应用有显著的影响,因此不同形貌CeO₂的合成引起了科研人员的关注。表面活性剂是一种用途非常广泛的双亲分子,可以有效调控纳米CeO₂的形貌和结构,因而在纳米CeO₂的合成中发挥着重要的作用。主要介绍了表面活性剂辅助合成不同形貌的二氧化铈,并对表面活性剂在CeO₂合成中的前景进行了展望。

Abstract

CeO₂ is an important rare earth metal oxide has been widely used in various fields owing to its unique structure and excellent performance.The morphology of CeO₂ has a remarkable influence on its property and application.Therefore,the synthesis of CeO₂ with different morphology has attracted the attention of researchers.Surfactants are versatile amphiphilic molecules.Surfactant plays an important role in the preparation of nano CeO₂,owing to it could effectively control the morphology and structure of nano CeO₂.Surfactant assisted synthesis of ceria with different morphology were summarized,and the prospect of surfactants in the synthesis of ceria was discussed.

关键词

表面活性剂 / 二氧化铈 / 形貌

Key words

surfactant / cerium oxide / morphology

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表面活性剂辅助合成不同形貌纳米CeO₂研究进展[J]. 化工新型材料, 2017, 45(9): 37-39 DOI:

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参考文献

原文顺序 | 出版日期 | 本文引用

[1] Liu H W,Liu H F.Preparing micro/nanocore-shell sphere CeO₂ via a low temperature route for improved lithium storage performance[J].Materials Letters,2016,168:80-82.
[2] Dai Q G,Bai S X,Li H,et al.Template-free and non-hydrothermal synthesis of CeO₂ nanosheets via a facile aqueous-phase precipitation route with catalytic oxidation roperties[J].CrystEngComm,2014,16:9817-9827.
[3] Liu Y J,Li Z F,Xu H B,et al.Reverse water-gas shift reaction over ceria nanocube synthesized by hydrothermal method[J].Catalysis Communications,2016,76:1-6.
[4] Zhang W W,Chen D H.Preparation and performance of CeO₂ hollow spheres and nanoparticles[J].Journal of Rare Earths,2016,34(3):295-298.
[5] Liu Z J,Guo S Y,Hong C G,et al.Synthesis and photocatalytic properties of CeO₂ nanocubes[J].Mater Electron,2016,27(2):2146-2150.
[6] Zhang G Q,Ao J,Guo Y L,et al.Green synthesis and catalytic performance of nanoscale CeO₂ sheets[J].RSC Adv,2014,4(39):20131-20135.
[7] Sun J J,Wang C R,Zeng L.Controllable assembly of CeO₂ micro/nanospheres with adjustable size and their application in Cr(Ⅵ) adsorption[J].Materials Research Bulletin,2016,75:110-114.
[8] Zhou G L,Gui B G,Xie H M,et al.Influence of CeO₂ morphology on the catalytic oxidation of ethanol in air[J].Journal of Industrial and Engineering Chemistry,2014,20:160-165.
[9] Umar A,Kumar R,Akhtar M S,et al.Growth and properties of well-crystalline cerium oxide (CeO₂) nanoflakes for environmental and sensor applications[J].Journal of Colloid and Interface Science,2015,454:61-68.
[10] Zou J,Gong W Y,Zhang S,et al.One-pot synthesis of hollow microspheres of cerium oxide and their application in electrochemical sensors[J].Chem Lett,2014,43(12):1918-1920.
[11] Lyu G M,Wang Y J,Huang X,et al.Hydrophilic CeO₂ nanocubes protect pancreatic β-cell line INS-1 from H₂O₂-induced oxidative stress[J].The Royal Society of Chemistry,2016,8(15):7923-7932.
[12] Wu M Z,Liu Y M,Dai P,et al.Hydrothermal synthesis and photoluminescence behavior of CeO₂ nanowires with the aid of surfactant PVP[J].International Journal of Minerals,Metallurgy,and Materials,2010,17(4):470-474.
[13] Vantomme A,Yuan Z Y,Du G,et al.Surfactant-assisted large-scale preparation of crystalline CeO₂ nanorods[J].Langmuir,2005,21(3):1132-1135.
[14] Zhang D S,Fu H X,Shi L Y,et al.Synthesis of CeO₂ nanorods via ultrasonication assisted by polyethylene glycol[J].Inorg Chem,2007,46(7):2446-2451.
[15] Sun C,Li H,Zhang H,et al.Controlled synthesis of CeO₂ nanorods by a solvothermal method[J].Nanotechnology,2005,16(9):1454-1463.
[16] 徐淑芝,董相廷,盖广清,等.同轴静电纺丝技术制备CeO₂纳米管及光催化性能研究[J].中国稀土学报,2012,30(5):556-562.
[17] 孙庆堂.二氧化铈基微纳米材料的制备与表征[D].杭州:浙江理工大学,2012.
[18] Yang Z J,Han D Q,Ma D L,et al.Fabrication of monodisperse CeO₂ hollow spheres assembled by nano-octahedra[J].Cryst Growth Des,2010,10(1):291-295.
[19] Liu X,Yang H,Han L,et al.Mesoporous-shelled CeO₂ hollow nanospheres synthesized by a one-pot hydrothermal route and their catalytic performance[J].Cryst Eng Comm,2013,15(38):7769-7775.
[20] Han L J,Liu R J,Li C S,et al.Controlled synthesis of double-shelled CeO₂ hollow spheres and enzyme-free electrochemical bio-sensing properties for uric acid[J].J Mater Chem,2012(33):17079-17085.
[21] Jiang X L,Zhang J,Yu L,et al.Synthesis of mono-dispersed ceria hollow nanospheres by a hydrothermal method[J].Micro & Nano Letters,2016,11(3):137-141.
[22] Liu W,Feng L,Zhang C,et al.A facile hydrothermal synthesis of 3D flowerlike CeO₂ via a cerium oxalate precursor[J].J Mater Chem A,2013,1(23):6942-6948.
[23] Guo Z Y,Du F L,Cui Z L.Hydrothermal synthesis of single-crystalline CeCO₃OH flower-like nanostructures and their thermal conversion to CeO₂[J].Materials Chemistry and Physics,2009,113(1):53-56.
[24] Zhong L S,Hu J S,Cao A M,et al.3D Flowerlike ceria micro/nanocomposite structure and its application for water treatment and CO Removal[J].Chem.Mater,2007,19:1648-1655.
[25] Wei J J,Yang Z J,Yang H X.A mild solution strategy for the synthesis of mesoporous CeO₂ nanoflowers derived from Ce(HCOO)₃[J].Cryst Eng Comm,2011,13:4950-4955.
[26] 朱园.二氧化铈的可控合成及其电化学性质研究[D].青岛:青岛科技大学,2014.
[27] Zhang C,Meng F M,Wang L N.Morphology-selective synthesis method of gear-like CeO₂ microstructures and their optical properties[J].Materials Letters,2014,130:202-205.
[28] Zhang C,Meng F M,Wang L N.Controlled synthesis and magnetic properties of bowknot-like CeO₂ microstructures by a CTAB-assisted hydrothermal method[J].Materials Letters,2014,119:1-3.
[29] Guo Z Y,Du F L,Li G C.Synthesis and characterization of single-crystal Ce(OH)CO₃ and CeO₂ triangular microplates[J].Inorganic Chemistry,2006,45(10):4167-4169.
[30] Li K,Zhao P S.Synthesis of single-crystalline Ce(CO₃)(OH) with novel dendrite morphology and their thermal conversion to CeO₂[J].Materials Research Bulletin,2010,45(2):243-246.