聚吡咯(PPy)是具有独特光电性能的功能聚合物,具有良好的光、电、磁特性,光吸收系数高。近年来,PPy及其衍生物、PPy与有机/无机复合物的制备及光性能的研究受到国内外研究者的重视,并取得了一系列研究成果。对PPy及其复合物的制备和光性能的研究进行了综述,讨论了其光学特性在光电器件、光催化剂和生命科学等领域的最新进展,并对相关领域的发展趋势进行展望。
Polypyrrole is a functional polymer with unique electrical,magnetic and optical properties,and has high absorption coefficients.In recent years,the preparation and optical properties of polypyrrole,including its derivatives,polypyrrole/inorganic composites and polypyrrole/organic composites are constantly explored,and a series of valuable insight into them has been achieved.The preparation and optical properties study of polypyrroles were summarized,and some of new developments of optical properties in optoelectronic devices,sensors,optical catalysts,life sciences and so on were discussed.
[1] Liang H C,Li X Z.Visible-induced photocatalytic reactivity of polymer-sensitized titania nanotube films[J].Applied Catalysis B:Environmental,2009,86(1-2):8-17.
[2] Wang W Q,Yu D M,Tian F.Synthesis and characterization of a new polypyrrole based on N-vinyl pyrrole[J].Synthetic Metals,2008,158(17-18):717-721.
[3] Coelho E C S,Nascimento V B,Ribeiro A S,et al.Electrochemical and optical properties of new electrochromic and fluorescent nitrobenzoyl polypyrrole derivatives[J].Electrochimica Acta,2014,123:441-449.
[4] Hu S Z,Ma L,Wang H Y,et al.Properties and photocatalytic performance of polypyrrole and polythiophene modified g-C3N4 nanocomposites[J].RSC Advances,2015,5(40):31947-31953.
[5] Luo Q Z,Li X Y,Wang D S,et al.Photocatalytic activity of polypyrrole/TiO2 nanocomposites under visible and UV light[J].Journal of Materials Science,2010,46(6):1646-1654.
[6] Zhang S,Chen Q Y,Wang Y H,et al.Synthesis and photoactivity of CdS photocatalysts modified by polypyrrole[J].International Journal of Hydrogen Energy,2012,37(17):13030-13036.
[7] Dimitrijevic N M,Tepavcevic S,Liu Y Z,et al.Nanostructured TiO2/polypyrrole for visible light photocatalysis[J].The Journal of Physical Chemistry C,2013,117(30):15540-15544.
[8] Zhang J R,Qiu T,Yuan H F,et al.The synthesis of Ag-polypyrrole nanocomposite coated latex particles and their application as a fluorescent quenching agent[J].Chinese Journal of Polymer Science,2013,31(3):434-443.
[9] Tan F,Cong L C,Li X N,et al.An electrochemical sensor based on molecularly imprinted polypyrrole/graphene quantum dots composite for detection of bisphenol A in water samples[J].Sensors and Actuators B:Chemical,2016,233:599-606.
[10] Etelino F D M,Kleber G B A,Severino A J,et al.Synthesis of fluorescent PVA/polypyrrole-ZnO nanofibers[J].Journal of Materials Science,2013,48(10):3652-3658.
[11] Wang X,Deng J X,DuanX J,et al.Fluorescent brightener CBS-X doped polypyrrole as smart electrode material for supercapacitors[J].Applied Energy,2015,153:70-77.
[12] Ke K M,Lin L S,Liang H,et al.Polypyrrole nanoprobes with low non-specific protein adsorption for intracellular mRNA detection and photothermal therapy[J].Chemical Communications,2015,51(31):6800-6803.
[13] Zhang S H,Wang G L,Lv G W,et al.Synthesis and fluorescence properties of a soluble polypyrrole derivative based on a dipyrrole monomer[J].Synthetic Metals,2014,195:185-192.
[14] Singh S K,Shukla R K.Optical and photoconductivity properties of pure polypyrrole and titanium dioxide-doped polypyrrole nanocomposites[J].Materials Science in Semiconductor Processing,2015,31:245-250.
[15] Cao S Q,Zhang H Y,Song Y Q,et al.Investigation of polypyrrole/polyvinyl alcohol-titanium dioxide composite films for photo-catalytic applications[J].Applied Surface Science,2015,342:55-63.
[16] Wang Q Z,Zheng L H,Chen Y T,et al.Synthesis and characterization of novel PPy/Bi2O2CO3 composite with improved photocatalytic activity for degradation of Rhodamine-B[J].Journal of Alloys and Compounds,2015,637:127-132.
[17] Sun L B,Shi Y C,Li B,et al.Preparation and characterization of polypyrrole/TiO2 nanocomposites by reverse microemulsion polymerization and its photocatalytic activity for the degradation of methyl orange under natural light[J].Polymer Composites,2013,34(7):1076-1080.
[18] Luo J,Ma Y,Wang H Y,et al.Preparation of polypyrrole sensitized TiO2 nanotube arrays hybrids for efficient photoelectrochemical water splitting[J].Electrochimica Acta,2015,167:119-125.
[19] Won D H,Chung J,Park S H,et al.Photoelectrochemical production of useful fuels from carbon dioxide on a polypyrrole-coated p-ZnTe photocathode under visible light irradiation[J].Journal of Materials Chemistry A,2015,3(3):1089-1095.
[20] Kumar D S,Nakamura K,Nishiyama S,et al.Optical and electrical characterization of plasma polymerized pyrrole films[J].Journal of Applied Physics,2003,93(5):2705.
[21] Yang P,Zhang J,Guo Y.Synthesis of intrinsic fluorescent polypyrrole nanoparticles by atmospheric pressure plasma polymerization[J].Applied Surface Science,2009,255(15):6924-6929.
[22] Mane A T,Navale S T,Pawar R C,et al.Microstructural,optical and electrical transport properties of WO3 nanoparticles coated polypyrrole hybrid nanocomposites[J].Synthetic Metals,2015,199:187-195.
[23] Zhou X,Ma P P,Wang A Q,et al.Dopamine fluorescent sensors based on polypyrrole/graphene quantum dots core/shell hybrids[J].Biosens & Bioelectron,2015,64:404-410.
[24] Zhang Q Q,Liu Z Y,Wang K F,et al.Organic/inorganic hybrid nanochannels based on polypyrrole-embedded alumina nanopore arrays:pH- and light-modulated ion transport[J].Advanced Functional Materials,2015,25(14):2091-2098.
[25] Harraz F A,Ismail A A,Al-Sayari S A,et al.Novel α-Fe2O3/polypyrrole nanocomposite with enhanced photocatalytic performance[J].Journal of Photochemistry and Photobiology A:Chemistry,2015,299:18-24.
[26] Duan F,Zhang Q H,Shi D J,et al.Enhanced visible light photocatalytic activity of Bi2WO6 via modification with polypyrrole[J].Applied Surface Science,2013,268:129-135.
[27] Antony M J,Jayakannan M.Amphiphilic azobenzenesulfonic acid anionic surfactant for water-soluble,ordered,and luminescent polypyrrole nanospheres[J].The Journal of Physical Chemistry B,2007,111(44):12772-12780.
[28] Kepinska D,Blanchard G J,Krysinski P,et al.Pyrene-loaded polypyrrole microvessels[J].Langmuir:the ACS Journal of Surfaces and Colloids,2011,27(20):12720-12729.
[29] Blinova N V,Stejskal J,Trchov M,et al.Polyaniline and polypyrrole:a comparative study of the preparation[J].European Polymer Journal,2007,43(6):2331-2341.
基金资助
陕西省科技攻关项目(2013k09-30)
PDF
