锂-空气电池是一种理论性能非常好的环保新型电池(比容量和比能量分别为3860mAh/g和11400Wh/kg)。若能将锂-空气电池成功开发,汽车对汽油的需求比重将会大大降低。然而,对它的研究认识还不够深入,距离实际产业化还有很多工作要做。介绍了有机体系锂-空气电池的研究情况和以后的应用与发展趋势。
Li-air battery has a good theoretical performance,which is friendly to environment (specific capacity and specific energy are 3860mAh/g and 11400Wh/kg,respectively).If the lithium-air battery is successfully developed,the proportion of car demand for gasoline will be greatly reduced.However,the research on lithium-air is not deep enough,and there is still a lot of work to be done before the actual industrialization.The research situation of lithium-air battery in organic system and its application and development trend were introduced.
[1] Girishkumar G,McCloskey B,Luntz A C,et al.Lithium-air battery:promise and challenges[J].Journal of Physical Chemistry Letters,2010,1(14):2193-2203.
[2] 王芳,梁春生,徐大亮,等.锂空气电池的研究进展[J].无机材料学报,2012,27(12):1233-1242.
[3] Read J.Ether-based electrolytes for the lithium/oxygen organic electrolyte battery[J].Journal of The Electrochemical Society,2006,153(1):A96-A100.
[4] Ogasawara T,Debart A,Holzapfel M,et al.Rechargeable Li2O2 electrode for lithium batteries[J].Journal of the American Chemical Society,2006,128(4):1390-1393.
[5] Debart A,Bao J,Armstrong G,et al.An O2 cathode for rechargeable lithium batteries:the effect of a catalyst[J].Journal Power Sources,2007,174(2):1177-1182.
[6] Debart A,Paterson A J,Bao J,et al.Alpha-MnO2 nanowires:a catalyst for the O2 electrode in rechargeable lithium batteries[J].Angewandte Chemie,2008,47(24):4521-4524.
[7] Lee J S,Tai S K,Cao R,et al.Metal-air batteries with high energy density:Li-air versus Zn-air[J].Advanced Energy Materials,2011,1(1):34-50.
[8] Christensen J,Albertus P,Sanchez-Carrera R S,et al.A critical review of Li/air batteries[J].Journal of the Electrochemical Society,2012,159(2):R1-R30.
[9] 卢凡亮.La0.8Sr0.2MnO3钙钛矿氧化物作为锂空气电池催化剂的设计与改性研究[D].苏州:苏州大学,2015.
[10] Schwager P,Fenske D,Wittstock G.Scanning electrochemical microscopy of oxygen permeation through air-electrodes in lithium-air batteries[J].Journal of Electroanalytical Chemistry,2015,740:82-87.
[11] Yuan J,Yu J S,Sunden B.Review on mechanisms and continuum models of multi-phase transport phenomena in porous structures of non-aqueous Li-Air batteries[J].Journal of Power Sources,2015,278:352-369.
[12] Cheng H,Scott K.Carbon-supported manganese oxide nanocatalysts for rechargeable lithium-air batteries[J].Journal of Power Sources,2010,195(5):1370-1374.
[13] Xiao J,Wang D,Xu W,et al.Optimization of air electrode for Li/air batteries[J].Journal of the Electrochemical Society,2010,157(4):A487-A492.
[14] Zhang C,Lv W,Tao Y,et al.Towards superior volumetric performance:design and preparation of novel carbon materials for energy storage[J].Energy & Environmental Science,2015,8(5):1390-1403.
[15] Tran C,Yang X Q,Qu D.Investigation of the gas-diffusion-electrode used as lithium/air cathode in non-aqueous electrolyte and the importance of carbon material porosity[J].Journal of Power Sources,2010,195(7):2057-2063.
[16] Zhang G Q,Zheng J P,Liang R,et al.Lithium-air batteries using SWNT/CNF buckypapers as air electrodes[J].Journal of the Electrochemical Society,2010,157(8):A953-A956.
[17] Zhang S S,Xu K,Read J.A non-aqueous electrolyte for the operation of Li/air battery in ambient environment[J].Journal of Power Sources,2011,196(8):3906-3910.
[18] Yang X,Xia Y.The effect of oxygen pressures on the electrochemical profile of lithium/oxygen battery[J].Journal of Solid State Electrochemistry,2010,14(1):109-114.
[19] Zhang Y,Zhang H,Li J,et al.The use of mixed carbon materials with improved oxygen transport in a lithium-air battery[J].Journal of Power Sources,2013,240:390-396.
[20] Zahoor A,Jang H Sm,Jeong J S,et al.A comparative study of nanostructured alpha and delta MnO2 for lithium oxygen battery application[J].Rsc Advances,2014,4(18):8973-8977.
[21] Débart A,Bao J,Armstrong G,et al.An O2 cathode for rechargeable lithium batteries:the effect of a catalyst[J].Journal of Power Sources,2007,174(2):1177-1182.
[22] Lu Y C,Gasteiger H A,Parent M C,et al.The influence of catalysts on discharge and charge voltages of rechargeable Li-oxygen batteries[J].Electrochemical and Solid-State Letters,2010,13(6):A69-A72.
[23] Du Z,Yang P,Wang L,et al.Electrocatalytic performances of LaNi1-xMgxO3 perovskite oxides as bi-functional catalysts for lithium air batteries[J].Journal of Power Sources,2014,265(11):91-96.
[24] Read J.Characterization of the lithium/oxygen organic electrolyte battery[J].Journal of the Electrochemical Society,2002,149(9):A1190-A1195.
[25] Lu Y C,Xu Z,Gasteiger H A,et al.Platinum-gold nanoparticles:a highly active bifunctional electrocatalyst for rechargeable lithium-air batteries[J].Journal of the American Chemical Society,2010,132(35):12170-12171.
[26] Xu W,Viswanathan V V,Wang D Y,et al.Investigation on the charging process of Li2O2-based air electrodes in Li-O2 batteries with organic carbonate electrolytes[J].Power Sources,2011,196(8):3894-3899.
[27] Chen Y,Freunberger S A,Peng Z,et al.Charging a Li-O2 battery using a redox mediator[J].Nature Chemistry,2013,5(6):489-494.
[28] Cai K,Pu W,Gao Y,et al.Investigation of ionic liquid composite electrolyte for lithium-oxygen battery[J].International Journal of Hydrogen Energy,2013,38(25):11023-11027.
[29] Choi N S,Lee Y M,Park J H,et al.Interfacial enhancement between lithium electrode and polymer electrolytes[J].Journal of Power Sources,2003,119/121(6):610-616.
[30] Choi N S,Lee Y M,Cho K Y,et al.Protective layer with oligo (ethylene glycol) borate anion receptor for lithium metal electrode stabilization[J].Electrochemistry Communications,2004,6(12):1238-1242.
[31] Kumar J,Kumar B.Developmemt of membranes and a study of their interfaces for rechangeable lithium-air battery[J].Journal of Power Sources,2009,194(2):1113-1119.
[32] Zhang D,Li R S,Huang T,et al.Novel composite polymer electrolyte for lithium air batteries[J].Journal of Power Sources,2010,195(4):1202-1206.
[33] Lee D J,Lee H,Song J C,et al.Composite protective layer for Li metal anode in high-performance lithium-oxygen batteries[J].Electrochemistry Communications,2014,40:45-48.
基金资助
国家自然科学基金(21106101);天津市应用基础及前沿技术研究计划项目(12JCZDJC29500)