With the continuous improvement of social requirements for material properties,continuous fiber reinforced resin composites have developed rapidly because of excellent properties.Basalt fiber reinforced poly (aryl ether nitrile) composites were prepared by preimpregnation and hot pressing.Detailed study on how heat treatment for the morphology,mechanical properties,thermal properties and dielectric properties of the composites were also applied.The results showed that the mechanical properties of the composites were greatly improved by adding basalt fibers,and the interfacial bonding strength between the matrix and the fibers was effectively improved by forming crosslinking network of some nitrile groups after heat treatment,so the mechanical properties of the composites were further improved.In addition,the composites also had excellent thermal stability and good electrical insulation performance.
Yin Hang, Tang Zili, Yang Junyi, Tang Hailong
. Study on structure and property of basalt fiber reinforced poly(arylene ether nitrile) composite[J]. New Chemical Materials, 2021
, 49(1)
: 72
-76
.
DOI: 10.19817/j.cnki.issn 1006-3536.2021.01.016
[1] Dhand V,Mittal G,Rhee K Y,et al.A short review on basalt fiber reinforced polymer composites[J].Composites Part B,2015,73:166-180.
[2] Li C,Gu Y,Liu X.Synthesis and properties of phenolphthalein-based polyarylene ether nitrile copolymers[J].Materials Letters,2006,60(1):137-141.
[3] Saxena A,Rao V L,Ninan K N.Synthesis and properties of polyether nitrile copolymers with pendant methyl groups[J].European Polymer Journal,2003,39(1):57-61.
[4] Cheng L,Han K,Xu K,et al.Modular synthesis and dielectric properties of high-performance fluorinated poly(arylene ether-1,3,4-oxadiazole)s[J].Polymer Chemistry,2013,4(8):2436-2439.
[5] Wang W,Lu X,Li Z,et al.One-dimensional polyelectrolyte/polymericsemiconductor core/shell structure:sulfonated poly(arylene ether ketone)/polyaniline nanofibers for organic field-effect transistors[J].Advanced Materials,2011,23(43):5109-5112.
[6] 张连来,顾宜.特种工程塑料—聚芳醚腈[J].中国塑料,1995,9(3):11-18.
[7] Giannelis E P.Polymer layered silicate nanocomposites[J].Advanced Materials,1996,8(1):29-35.
[8] Kiliaris P,Papaspyrides C D.Polymer/layered silicate (clay) nanocomposites:an overview of flame retardancy[J].Progress in Polymer Science,2010,35(7):902-958.
[9] Liu X,Wu Q.PP/clay nanocomposites prepared by grafting-melt intercalation[J].Polymer,2001,42(25):10013-10019.
[10] Yang J,Zhong J,Zhao R,et al.High-performance PEN/GF crosslinkable thermoplastic composites:preparation,properties,and crosslinking reaction[J].Journal of Composite Materials,2011,45(24):2587-2592.
[11] 刘孝波,李曹,雷毅,等.玻纤增强聚芳醚腈PEN(HQ/RS)/GF复合材料的制备及其性能研究[J].中国科技论文在线,2005,30(6):1-7..
[12] Zheng L,Liao G X,Gu T S,et al.Modified continuous carbon fiber-reinforced poly(phthalazinone ether sulfone ketone) composites by blending polyetherimide and polyethersulfone[J].Polymer Composites,2010,30(12):1842-1847.
[13] Zou Y,Liu X.Morphology,thermal and mechanical properties of glass fiber-reinforced crosslinkable poly(arylene ether nitrile)[J].Journal of Applied Polymer Science,2013,129(1):130-137.
[14] Abdi A,Eslami-Farsani R,Khosravi H.Evaluating the mechanical behavior of basalt fibers/epoxy composites containing surface-modified CaCO3 nanoparticles[J].Fibers & Polymers,2018,19(3):635-640.
[15] 温汉东,钟家春,杨建,等.聚芳醚腈连续纤维增强复合材料制备与性能研究[J].塑料工业,2011,39(8):81-84.
[16] 张军华,刘孝波,米军,等.酚酞型聚芳醚腈的合成与性能[J].塑料工业,1997(6):63-65.
[17] 唐安斌,朱蓉琪,蒋启泰,等.聚芳醚腈砜的研究进展[J].材料导报,1999(2):9-12.
[18] 杨建,钟家春,刘孝波.双酚A型聚芳醚腈共聚物的合成与性能[J].塑料工业,2010,38(4):10-13.
[19] 钟家春.聚芳醚腈共聚物及其介电功能复合材料研究[D].成都:电子科技大学,2011.
[20] Zhan Y,Zhang J,He S,et al.Thermally stable and dielectric nanocomposite based on poly(arylene ether nitrile) and BaTiO3 functionalized by modified mussel-inspired route[J].Journal of Polymer Research,2019,26(3):77.
[21] Xiao Q,Yang R,You Y,et al.Crystalline,mechanical and dielectric properties of polyarylene ether nitrile with multi-walled carbon nanotube filled with polyarylene ether nitrile[J].Journal of Nanoscience & Nanotechnology,2018,18(6):4311-4317.
