The properties of polylactic acid (PLA) resin were first studied.The air drafted PLA fibers were then manufactured by the spun-bonded nonwoven fabric equipment.The morphology,thermal properties and tensile properties of PLA fibers were characterized by the video microscope,differential scanning calorimeter and universal material tester.The results showed that the melting point of PLA resin was 168.7℃.The longitudinal surface of PLA fibers was smooth and straight,and the cross section was round.The linear density of PLA fibers decreased with the increase of intensity of air drafting.The breaking strength increased,whereas the elongation at break firstly increased and then decreased as the intensity of air drafting raised.Moreover,the glass transition temperature (Tg) and melting point (Tm) of PLA fibers increased,and the cold crystallization temperature (Tc) decreased via the air drafting.The crystallinity of PLA fibers firstly increased and then decreased with the increase of intensity of air drafting.
[1] Lv T X,Zhou C B,Li J Q,et al.New insight into the mechanism of enhanced crystallization of PLA in PLLA/PLDA mixture[J].Journal of Applied Polymer Science,2018,135(2):45663.
[2] 魏泽昌,蔡晨阳,王兴,等.生物可降解高分子增韧聚乳酸的研究进展[J].材料工程,2019,47(5):34-42.
[3] Zhang Y,Deng B Y,Liu Q S.Viscoelastic behavior and crystallization kinetics of poly (lactic acid)/silica nanocomposites[J].Journal of Reinforced Plastics and Composites,2014,33(9):875-882.
[4] 梁宁宁,熊祖江,王锐,等.聚乳酸纤维的制备及性能研究进展[J].合成纤维工业,2016,39(1):42-47.
[5] 齐悦,杨博,马慧玲,等.生物可降解聚乳酸纤维的发展现状及其改性研究[J].北京服装学院学报,2019,39(1):85-93.
[6] 潘晓娣,钱明球,戴钧明.聚乳酸纤维的国内外开发进展[J].合成技术及应用,2017,32(4):32-37.
[7] 芦长椿.生物基纺熔非织造布的研发现状与趋势[J].纺织导报,2017(10):36-42.
[8] 蔡云冰,刘志鹏,张子龙,等.聚乳酸材料在3D打印中的研究与应用进展[J/OL].应用化工,https://doi.org/10.16581/j.cnki.issn1671-3206.20190523.036.
[9] 常杰,刘亚,程博闻.聚乳酸纺粘非织造布的研究进展[J].天津工业大学学报,2013,32(4):37-42.
[10] 常过,邓炳耀,刘庆生,等.PLA纺粘非织造材料的制备和表征[J].纺织学报,2012,34(8):35-39.
[11] Zhao Bo.Experimental study and numerical analysis for prediction of the fiber diameter of polylactic acid (PLA) spunbonded nonwovens[J].Fibers & Textiles in Eastern Europe,2010,17(5):82-86.
[12] 马涛,马咏梅.聚乳酸在聚合物直接成网法非织造布中的研究进展[J].轻纺工业与技术,2011,40(2):55-59.
[13] 张越.共混改性聚乳酸复合材料的制备与结构性能研究[D].无锡:江南大学,2014.
[14] 邢剑,邓炳耀,刘庆生.聚偏氟乙烯熔纺纤维的制备与表征研究[J].化工新型材料,2016,44(5):97-99.
[15] 阮如玉,徐德华,梁子,等.PAN原丝取向行为与初生纤维结构的相关性[J].航空材料学报,2019,39(1):89-95.
[16] 刘淑强,张蕊萍,贾虎生,等.可生物降解聚乳酸长丝的熔融纺丝工艺[J].纺织学报,2012,33(11):11-15.
[17] 李旭明,孙西超,师利芬.增强增韧聚乳酸纤维的制备及其性能[J].纺织学报,2017,38(4):12-16.
[18] 李健,黄庆,李鑫.PGLA纤维拉伸过程中结晶与取向的变化[J].纺织学报,2011,31(1):1-5.
[19] 徐文华,杨智韬,殷小春.拉伸形变作用下PLA/PBS增韧共混物力学性能研究[J].中国塑料,2016,30(1):34-38.