Influence of characteristic viscosity of F2311 fluorine rubber on the forming and mechanical property of PBX

Expand
  • Institute of Chemical Materials,China Academy of Engineering Physics,Mianyang 621900

Online published: 2020-12-07

Abstract

Based on the requirements of material design and mechanical response of charge structure,ideal safety performance,detonation performance and mechanical performance can be obtained through the use of binder.Therefore,the forming density,compression strength,tensile strength and elastic modulus of HMX base polymer bonded explosive were tested for different viscosity characteristics of F2311 fluorine rubber.The results showed that the PBX195 of F2311 with a characteristic viscosity of 1.95dL/g had a tensile strength of 4.05MPa and a tensile strain of 1.56%,which was higher than that of other PBX formulations with a characteristic viscosity of F2311,and the tensile modulus of PBX195 was 0.668GPa,which was far lower than that of other PBX formulations with a characteristic viscosity of F2311.Therefore,it can be considered that F2311 with characteristic viscosity at 1.95dL/g was the most suitable for HMX base PBX formula,and its mechanical properties and molding properties were significantly improved.

Cite this article

Zhan Chunhong, Qu Yanyang, Shi Pengxiang, Pang Wanting, Xu Ruijuan . Influence of characteristic viscosity of F2311 fluorine rubber on the forming and mechanical property of PBX[J]. New Chemical Materials, 2020 , 48(11) : 77 -79 . DOI: 10.19817/j.cnki.issn 1006-3536.2020.11.017

References

[1] Gibbs T R,Popolato A.LASL high explosive property data[M].California:University of California Press,1980:1-30.
[2] 孙国祥.高分子混合炸药[M].北京:国防工业出版社,1984:1-60.
[3] 董海山,周芬芬.高能炸药及相关物性能[M].北京:科学出版社,1989:1-45.
[4] 孙业斌,惠君明,曹欣茂.军用混合炸药[M].北京:兵器工业出版社,1995:1-72.
[5] 谭惠明.高能推进剂的发展方向——NEPE推进剂[J].北京理工大学学报,1992,(12):1.
[6] Xiao J J,Fang G Y,Ji G F,et al.Simulation investigation in the binding energy and mechanical properties of HMX-based polymer-bonded explosives[J].Chinese Science Bulletin,2005,50:21-26.
[7] 肖继军,谷成刚,方国勇,等,TATB基PBX结合能和力学性能的理论研究[J].化学学报,2005,63(6):439.
[8] Xiao J J,Hu Y J,Huang Y C,et al.Molecular dynamics simulation of mechanical properties of TATB/flourine-polymer PBXs along different surfaces[J].Sci China Ser B,2005,48(6):504-510.
[9] Xu X J,Xiao H M,Xiao J J,et al.Molecular dynamics simulations for pure epsilon-CL-20 and epsilon-CL-20-based PBXs[J].J Phys Chem B,2006,110:7203-7207.
[10] Qiu L,Xiao H M,Zhu W H,et al.Abinitio and molecular dynamics studies of crystalline TNAD(trans-1,4,5,8-tetranitro-1,4,5,8-tetraazadecalin)[J].J Phys Chem B,2006,110:10651-10661.
[11] 胡英杰,黄玉成,肖继军,等.TATB/氟聚物PBX沿不同晶面力学性能的分子动力学模拟[J].中国科学,B辑化学,2005,35(3):194-199.
[12] Berenbaum R,Brodie I.Measurement of the tensile strength of brittle materials[J].British Journal of Applied Physics,1959,10:281-286.
[13] Johnson H D.Mechanical properties of LX-10-1 evaluated with the diametric disc test,MHSMP-79-08[R].Amarillo,T X,USA:Mason and Hanger-Silas Mason Co,Inc,1979.
[14] Johnson H D.Mechanical properties of high explosives,MHSMP-74-19[R].Amarillo,TX,USA:Mason and Hanger-Silas Mason Co,Inc,1974.
[15] 温茂萍,唐维,董平,等.粘结剂含量对热压TATB基PBX残余应力的影响[J].含能材料,2017,25(8):661-666.
[16] 王保国,张景林,陈亚芳,等.HMX/TATB基高聚物粘结传爆药的研究[J].含能材料,2007,15(1):9-11;15.
[17] 陈荣,一种PBX炸药试样在复杂应力动态加载下的力学性能实验研究[D].长沙:国防科学技术大学,2010.
[18] 翟海光,压装高聚物粘结炸药界面化学作用的研究[J].机械管理开发,2006,(1):26-28.
Options
Outlines

/