One kind of binary eutectic phase change material was prepared by melt blending method with lauric acid (LA) and myristic acid (MA).The effect of mass fraction on crystallization temperature of LA-MA mixture was conducted by step cooling curve method.The hypoeutectic point was obtained by drawing the phase diagram of the mixture system,where the mass ratio of LA to MA was 3:1 and the eutectic temperature was 32.7℃.The latent heat of the eutectic system was 160.5J/g.FT-IR experimental results shown that LA and MA were integrated under molecular force in the binary composite and no chemical reaction occurred.After 500 times of 20~70℃ thermocycling,the phase change temperature of the composite had little change,and it indicated that the stability of LA-MA mixture was good.TG tests shown that there was no obvious mass loss when the temperature was less than 100℃.LA-MA binary composite phase change material was suitable for wall and other building envelope.
Xu Feng, Sun Zhigao
. Preparation and property of lauric acid-myristic acid binary composite phase change material[J]. New Chemical Materials, 2021
, 49(11)
: 156
-159
.
DOI: 10.19817/j.cnki.issn 1006-3536.2021.11.033
[1] Fang Y T,Yu H M,Wan W J,et al.Preparation and thermal performance of polystyrene/n-tetradecane composite nanoencapsulated cold energy storage phase change materials[J].Energy Conversion and Management,2013,76:430-436.
[2] 何小芳,吴永豪,王月明,等.相变储能材料的研究进展[J].化工新型材料,2014,42(12):27-29.
[3] Zhao M X,Li M K,Wang L,et al.Preparation and characterization of paraffin@CLPS/MS phase change microcapsules for thermal energy storage[J].Chemistry Select,2020,5(24):7190-7196.
[4] 乔英杰,王德民,张晓红,等.复合相变储能材料研究与应用新进展[J].材料工程,2007(Z1):229-232.
[5] 刘晓,孙志高,陈之帆,等.肉豆蔻酸-十四醇二元复合相变材料的相变特性研究[J].化工新型材料,2019,47(8):131-134.
[6] 张焕芝,崔韦唯,夏永鹏,等.复合相变材料的制备及热性能研究进展[J].化工新型材料,2019,47(6):35-38,43.
[7] 刘凤利,胡国峰,刘俊华,等.癸酸-硬脂酸/有机膨胀蛭石相变蓄热砂浆的制备与性能研究[J].功能材料,2020,51(5):5007-5012.
[8] 陈久林,段洋,王志雄.相变储热技术的研究现状及应用[J].广东化工,2020,47(2):101-104,110.
[9] Sharma A,Tyagi V V,Chen C R,et al.Review on thermal energy storage with phase change materials and applications[J].Pergamon,2009,13(2):318-345.
[10] 于永生,井强山,孙雅倩.低温相变储能材料研究进展[J].化工进展,2010,29(5):896-900,913.
[11] Han G G D,Deru J H,Cho E N,et al.Optically-regulated thermal energy storage in diverse organic phase-change materials[J].Chemical Communications,2018,54(76):10722-10725.
[12] Sun D,Wang L J,Li C M.Preparation and thermal properties of paraffin/expanded perlite composite as form-stable phase change material[J].Materials Letters,2013,108:247-249.
[13] 胡大为,胡小芳,林丽莹.环氧树脂基含水定形相变材料制备[J].合成材料老化与应用,2006,34(3):12-15,26.
[14] 王博,朱孝钦,胡劲,等.利用纳米石墨强化正癸酸-十四醇复合相变材料的导热性能[J].材料导报,2019,33(22):3815-3819.
[15] 李玉洋,章学来,徐笑锋,等.正辛酸-癸酸/膨胀石墨低温复合相变材料的制备及热物性研究[J].化工新型材料,2019,47(8):39-43,48.
[16] Chen C Z,Wang L G,Huang Y.A novel shape-stabilized PCM:electrospun ultrafine fibers based on lauric acid/polyethylene terephthalate composite[J].Materials Letters,2008,62(20):3515-3517.
[17] 王立久,孟多.定形相变材料的制备与性能研究[J].新型建筑材料,2009,36(11):1-4.