Research progress on active packaging film based on PBAT and its application in food packaging

Chen Wenjun, Wang Lei, Yang Shaohua, Yang Fuxin, Chen Chenwei

doi:10.19817/j.cnki.issn 1006-3536.2021.06.047

New Chemical Materials >

2021 , Vol. 49 >Issue 6: 215 - 221

DOI: https://doi.org/10.19817/j.cnki.issn 1006-3536.2021.06.047

Research progress on active packaging film based on PBAT and its application in food packaging

Expand

1. College of Food Science and Technology,Shanghai Ocean University,Shanghai 201306;
2. Shanghai Engineering Research Center of Aquatic-Product Processing & Preservation,Shanghai 201306;
3. Laboratory of Quality and Safety Risk Assessment for Aquatic Products on Storage and Preservation (Shanghai),Ministry of Agriculture,Shanghai 201306;
4. National Experimental Teaching Demonstration Center for Food Science and Engineering (Shanghai Ocean University),Shanghai 201306

Received date: 2020-03-05

Revised date: 2021-03-08

Online published: 2021-06-29

Fold

Abstract

Poly (butyleneadipate-co-terephthalate) (PBAT) is an environmentally friendly material due to its biodegradation and excellent mechanical properties.It can be used as an active packaging material in food packaging.In order to get better application of PBAT,the research progress of PBAT based active packaging film and its application in food packaging was reviewed,mainly from three aspects:PBAT film blending modification,active film and its application in food packaging.Its future development trend was prospected,in order to provide reference for the research of PBAT active packaging film.

Key words： poly (butyleneadipate-co-terephthalate); blending modification; active packaging; active film; food packaging

Cite this article

Chen Wenjun, Wang Lei, Yang Shaohua, Yang Fuxin, Chen Chenwei . Research progress on active packaging film based on PBAT and its application in food packaging[J]. New Chemical Materials, 2021 , 49(6) : 215 -221 . DOI: 10.19817/j.cnki.issn 1006-3536.2021.06.047

References

[1] 骆双灵.聚己二酸/二甲酸丁二酯钠米复合食品包装薄膜的研究及其在冷鲜肉保鲜中的应用[D].杭州:浙江大学,2019.
[2] 王治洲,李晓芳,宋树鑫,等.PCL对PBAT薄膜气体透过率的影响[J].塑料科技,2017,45(11):56-61.
[3] Dobrucka R,Przekop R.New perspectives in active and intelligent food packaging[J].Journal of Food Processing and Preservation,2019,43(11):1-9.
[4] Venkatesan R,Rajeswari N,Tamilselvi A.Antimicrobial,mechanical,barrier,and thermal properties of bio-based poly (butylene adipate-co-terephthalate)(PBAT)/Ag₂O nanocomposite films for packaging application[J].Polymers for Advanced Technologies,2017,29(1):61-68.
[5] Jaramillo A F,Riquelme S A,Sánchez-Sanhueza G,et al.Comparative study of the antimicrobial effect of nanocomposites and composite based on poly(butylene adipate-co-terephthalate)using Cu and Cu/Cu₂O nanoparticles and CuSO₄[J].Nanoscale Research Letters,2019,14( ): - .
[6] Shankar S,Rhim J W.Tocopherol-mediated synthesis of silver nanoparticles and preparation of antimicrobial PBAT/silver nanoparticles composite films[J/OL].LWT-Food Science and Technology,2016,72:149-156.https://www.sciencedirect.com/science/article/abs/pii/S0144861715004166.
[7] Felipe Jaramillo A,Riquelme S,Montoya L F,et al.Influence of the concentration of copper nanoparticles on the thermo-mechanical and antibacterial properties of nanocomposites based on poly(butylene adipate-co-terephthalate)[J].Polymer Composites,2019,40(5):1870-1882.
[8] 云雪艳,道日娜,李晓芳,等.PBAT/PCL共混薄膜在草莓保鲜包装中的应用[J].包装工程,2017,38(19):92-97.
[9] 王治洲,道日娜,徐畅,等.PBAT/PCL可降解气调保鲜膜对双孢菇的保鲜效果[J].食品工业,2018,32(12):502-506.
[10] Wang L F,Rhim J W,Hong S I.Preparation of poly(lactide)/poly(butylene adipate-co-terephthalate)blend films using a solvent casting method and their food packaging application[J/OL].LWT-Food Science and Technology,2016,68:454-461.http://dx.doi.org/10.1016/j.lwt.2015.12.062.
[11] 杨冰,张自强,张以河,等.PBAT/PLA薄膜的制备及性能研究[J].中国塑料,2015,29(3):45-50.
[12] Ren Y,Hu J,Yang M,et al.Biodegradation behavior of poly (lactic acid)(PLA),poly (butylene adipate-Co-terephthalate)(PBAT),and their blends under digested sludge conditions[J/OL].Journal of Polymers and the Environment,2019,27(12):2784-2792.https://doi.org/10.1007/s10924-019-01563-3.
[13] Palsikowski P A,Roberto M M,Sommaggio L R D,et al.Ecotoxicity evaluation of the biodegradable polymers PLA,PBAT and its blends using allium cepa as test organism[J].Journal of Polymers and the Environment,2018,26(3):938-945.
[14] 齐迎珍,邹俊,徐海青.PBAT/PLA复合材料的制备及其微球发泡行为研究[J].塑料科技,2018,46(10):15-20.
[15] 陈小英,徐鼐,庞素娟,等.PLA增强改性PBAT共混物的制备及性能研究[J].化工新型材料,2016,44(6):122-125.
[16] 周志斌,刘跃军,崔玲娜,等.PLA/PBAT/PCL生物降解复合材料的制备及其性能分析[J].功能材料,2016,47(5):5231-5242.
[17] 颜祥禹,潘宏伟,王哲,等.PBAT/PLA/TPS生物降解薄膜的制备及性能研究[J].塑料工业,2016,44(10):9-13.
[18] 赛华捷,王翔宇,刘烨,等.PLA/PBAT/OMMT纳米复合材料的制备及其结构与性能研究[J].中国塑料,2018,32(7):53-57.
[19] 张妍洁,吴栓庆,钟勇星,等.多元环氧扩链剂对PLA增强PBAT性能的影响[J].工程塑料应用,2018,46(2):7-11.
[20] Li X,Ai X,Pan H,et al.The morphological,mechanical,rheological,and thermal properties of PLA/PBAT blown films with chain extender[J].Polymers for Advanced Technologies,2018,29(6):1706-1717.
[21] 艾雪,董丽松,于银雷,等.交联改性PLA/PBAT吹塑薄膜性能的研究[J].塑料工业,2018,46(5):63-80.
[22] Ai X,Li X,Yu Y,et al.The mechanical,thermal,rheological and morphological properties of PLA/PBAT blown films by using bis(tert-butyl dioxy isopropyl)benzene as crosslinking agent[J].Polymer Engineering and Science,2019,59:227-236.
[23] 朱立邦.PBAT/PLA生物降解树脂增容改性研究[D].泰安:山东农业大学,2018.
[24] Morro A,Catalina F,Sanchez-León E,et al.Photodegradation and biodegradation under thermophile conditions of mulching films based on poly(butylene adipate-co-terephthalate)and its blend with poly(lactic acid)[J/OL].Journal of Polymers and the Environment,2019,27(2):352-363.https://link-springer-com.e-resource.shou.edu.cn/article/10.1007/s10924-018-1350-0.
[25] Sousa F M,Costa A R M,Reul L T A,et al.Rheological and thermal characterization of PCL/PBAT blends[J/OL].Polymer Bulletin,2019,76(3):1573-1593.https://link-springer-com.e-resource.shou.edu.cn/article/10.1007/s00289-018-2428-5.
[26] Pan H,Hao Y,Zhao Y,et al.Improved mechanical properties,barrier properties and degradation behavior of poly(butylenes adipate-co-terephthalate)/poly(propylene carbonate)films[J].Korean Journal of Chemical Engineering,2017,34(5):1294-1304.
[27] 王勋林,张敬勋,赵保才,等.PPC/PBAT薄膜制品性能研究[J].塑料科技,2015,43(5):70-72.
[28] 易爱,刘跃军.PHBV/PBAT复合阻燃材料的燃烧性能、力学性能及流变性能研究[J/OL].湖南工业大学学报,2016,30(6):60-68.
[29] 欧阳春发,贾润萍,王霞,等.PHBV/PBAT共混物形态与性能研究[J].中国塑料,2008,22(6):44-48.
[30] Pawar S P,Misra A,Bose S,et al.Enzymatically degradable and flexible bio-nanocomposites derived From PHBV and PBAT blend:assessing thermal,morphological,mechanical,and biodegradation properties[J].Colloid and Polymer Science,2015,293(10):2921-2930.
[31] 宁平,甘典松,肖运鹤.PBAT/PVB共混物相容性及性能的研究[J].合成材料老化及应用,2010,39(2):12-17.
[32] 张倩,王建清,王玉峰.添加PBAT的PLA/PHB复合材料的性能研究[J].包装与食品机械,2017,35(4):6-10.
[33] 刘亚丽,揣成智.PBAT增韧改性交联PBS的性能研究[J].塑料工业,2014,42(11)30-33.
[34] Muthuraj R,Misra M,Mohanty A K.Biodegradable poly(butylene succinate)and poly(butylene adipate-co-terephthalate)blends:reactive extrusion and performance evaluation[J].Journal of Polymers and the Environment,2014,22(3):336-349.
[35] Dhandapani S,Nayak S K,Mohanty S.Analysis and evaluation of biobased polyester of PTT/PBAT blend:thermal,dynamic mechanical,interfacial bonding,and morphological properties[J].Polymers for Advanced Technologies,2016,27(7):938-945.
[36] 刁晓倩,翁云宣.淀粉基塑料研究进展及产业现状[J].中国塑料,2017,31(9):22-29.
[37] 宁平,陈明月,肖运鹤.淀粉填充改性PBAT的结构与性能研究[J].化工新型材料,2010,38(7):116-119.
[38] 李旭娟,钟淦基,冉蓉,等.PBAT/TPS共混物的结构、性能和断裂行为[J].中国塑料,2014,28(2):25-30.
[39] Da Silva J B A,Santana J S,De Almeida Lucas A,et al.PBAT/TPS-nanowhiskers blends preparation and application as food packaging[J].Journal of Applied Polymer Science,2019,136(26):1-10.
[40] 林泽声.离子/酸化改性对热塑性淀粉及其PBAT共混物的结构与性能影响[D].广州:华南理工大学,2018.
[41] 王香云.PBAT/改性纤维素复合材料的制备与性能研究[D].乌鲁木齐:新疆大学,2016.
[42] Giri J,Lach R,Grellmann W,et al.Compostable composites of wheat stalk micro- and nanocrystalline cellulose and poly(butylene adipate-co-terephthalate):surface properties and degradation behavior[J].Journal of Applied Polymer Science,2019,136(43):1-11.
[43] Malinowski R,Krasowska K,Sikorska W,et al.Studies on manufacturing,mechanical properties and structure of poly(butylene adipate-co-terephthalate)-based green composites modified by coconut fibers[J/OL].International Journal of Precision Engineering and Manufacturing-Green Technology,2020( ): - .
[44] Muthuraj R,Misra M,Mohanty A K.Biodegradable biocomposites from poly(butylene adipate-co-terephthalate)and miscanthus:preparation,compatibilization,and performance evaluation[J].Journal of Applied Polymer Science,2017,134(43):1-9.
[45] Pinheiro I F,Ferreira F V,Alves G F,et al.Biodegradable PBAT-Based nanocomposites reinforced with functionalized cellulose nanocrystals from pseudobombax munguba:rheological,thermal,mechanical and biodegradability properties[J/OL].Journal of Polymers and the Environment,2019,27(4):757-766.https://link-springer-com.e-resource.shou.edu.cn/article/10.1007/s10924-019-01389-z.
[46] Da Silva C G,Kano F S,Dos Santos Rosa D.Thermal stability of the pbat biofilms with cellulse nanostructures/essential oils for active packaging[J/OL].Journal of Thermal Analysis and Calorimetry,2019,138(4):2375-2386.https://doi.org/10.1007/s10973-019-08190-z.
[47] 邹阳雪.木质素/PBAT/PES复合材料的制备及性能研究[D].绵阳:西南科技大学,2016.
[48] 钟生缘.纳米木质素/PBAT复合材料的流变行为及其性能研究[D].绵阳:西南科技大学,2019.
[49] Tavares L B,Ito N M,Salvadori M C,et al.PBAT/Kraft lignin blend in flexible laminated food packaging:peeling resistance and thermal degradability[J/OL].Polymer Testing,2018,67(November 2017):169-176.https://doi.org/10.1016/j.polymertesting.2018.03.004.
[50] Guo G,Zhang C,Du Z,et al.Structure and property of biodegradable soy protein isolate/PBAT blends[J/OL].Industrial Crops and Products,2015,74:731-736.
[51] Moustafa H,Guizani C,Dufresne A.Sustainable biodegradable coffee grounds filler and its effect on the hydrophobicity,mechanical and thermal properties of biodegradable PBAT composites[J].Journal of Applied Polymer Science,2017,134(8):1-11.
[52] 谢东,张玉欣,崔跃飞,等.PBAT/纳米蒙脱土复合薄膜的制备及水蒸气阻隔性能研究[J].塑料科技,2018,46(10):40-44.
[53] 张玉欣.高阻隔PBAT/层状纳米无机物复合地膜的制备与性能研究[D].广州:华南理工大学,2018.
[54] Maldonado L F,Muñoz P A R,Fechine G J M.Transfer of graphene CVD to surface of low density polyethylene(LDPE)and poly(butylene adipate-co-terephthalate)(PBAT)films:effect on biodegradation process[J/OL].Journal of Polymers and the Environment,2018,26(8):3187-3196.http://dx.doi.org/10.1007/s10924-018-1202-y.
[55] Venkatesan R,Rajeswari N.Poly(butylene adipate-co-terephthalate)bionanocomposites:effect of SnO₂ NPs on mechanical,thermal,morphological,and antimicrobial activity[J].Advanced Composites and Hybrid Materials,2018,1(4):731-740.
[56] Shankar S,Rhim J W.Effect of types of zinc oxide nanoparticles on structural,mechanical and antibacterial properties of poly(lactide)/poly(butylene adipate-co-terephthalate)composite films[J/OL].Food Packaging and Shelf Life,2019,21:100327.https://doi.org/10.1016/j.fpsl.2019.100327.
[57] Venkatesan R,Rajeswari N.ZnO/PBAT nanocomposite films:investigation on the mechanical and biological activity for food packaging[J].Polymers for Advanced Technologies,2017,28(1):20-27.
[58] Mondal D,Bhowmick B,Mollick M M R,et al.Antimicrobial activity and biodegradation behavior of poly(butylene adipate-co-terephthalate)/clay nanocomposites[J].Journal of Applied Polymer Science,2014,131(7):1-9.
[59] Mondal D,Bhowmick B,Maity D,et al.Investigation on sodium benzoate release from poly(butylene adipate-co-terephthalate)/organoclay/sodium benzoate based nanocomposite film and their antimicrobial activity[J].Journal of Food Science,2015,80(3):602-609.
[60] Cardoso L G,Pereira Santos J C,Camilloto G P,et al.Development of active films poly(butylene adipate co-terephthalate)-PBAT incorporated with oregano essential oil and application in fish fillet preservation[J/OL].Industrial Crops and Products,2017,108(5):388-397.http://dx.doi.org/10.1016/j.indcrop.2017.06.058.
[61] De Medeiros J A S,Blick A P,Galindo M V,et al.Incorporation of oregano essential oil microcapsules in starch-poly(butylene adipate co-terephthalate)(PBAT)films[J].Macromolecular Symposia,2019,383(1):1-7.
[62] Pattanayaiying R,Sane A,Photjanataree P,et al.Thermoplastic starch/polybutylene adipate terephthalate film coated with gelatin containing nisin Z and lauric arginate for control of foodborne pathogens associated with chilled and frozen seafood[J/OL].International Journal of Food Microbiology,2019,290:59-67.https://doi.org/10.1016/j.ijfoodmicro.2018.09.015.
[63] Shankar S,Rhim J W.Preparation of antibacterial poly(lactide)/poly(butylene adipate-co-terephthalate)composite films incorporated with grapefruit seed extract[J/OL].International Journal of Biological Macromolecules,2018,120:846-852.https://doi.org/10.1016/j.ijbiomac.2018.09.004.
[64] 云雪艳,刘孟禹,李晓芳,等.PLLA/PBAT单轴拉共混膜的力学性能及气体透过性[J].包装工程,2017,38(13):84-89.
[65] 王治洲,李晓芳,宋树鑫,等.PCL对PBAT薄膜气体透过率的影响[J].塑料科技,2017,45(11):56-61.
[66] 王莉梅,王治洲,刘孟禹,等.PBAT/EVOH共混薄膜的制备及其包装特性[J].塑料科技,2018,46(9):99-103.
[67] 许思兰,许国志,孙辉.PBAT/PPC多层共挤薄膜的制备及其阻透性能研究[J].中国塑料,2016,30(3):38-42.
[68] 刘孟禹,王莉梅,宋志鑫,等.PBS/PBAT共混薄膜的热学力学及阻隔性能研究[J].塑料科技,2019,4(4):41-47.
[69] 王羽.适用于圣女果的自发气调保鲜膜制备及保鲜效果的研究[D].呼和浩特:内蒙古农业大学,2016.
[70] Stramm C,Gunes G.Gas permeabilities of polyurethane films for fresh produce packaging:response of O₂ permeability to temperature and relative humidity[J].Polymer Testing,2017,59:237-243.
[71] Schmid M,Zillinger W,Müller K,et al.Permeation of water vapour,nitrogen,oxygen and carbon dioxide through whey protein isolate based films and coatings-permselectivity and activation energy[J/OL].Food Packaging and Shelf Life,2015,6:21-29.http://dx.doi.org/10.1016/j.fpsl.2015.08.002.
[72] Tomé L C,Isik M,Freire C S R,et al.Novel pyrrolidinium-based polymeric ionic liquids with cyano counter-anions:high performance membrane materials for post-combustion CO₂ separation[J/OL].Journal of Membrane Science,2015,483:155-165.http://dx.doi.org/10.1016/j.memsci.2015.02.020.
[73] Leal I L,Da SilVa Rosa Y C,Da Silva Penha J,et al.Development and application starch films:pbat with additives for evaluating the shelf life of tommy atkins mango in the fresh-cut state[J].Journal of Applied Polymer Science,2019,136(43):1-19.

Options

Abstract

Outlines

模态框（Modal）标题

Abstract

Cite this article

References