Three benzoyl semicarbazide derivatives were designed and synthesized by using benzoic acid,acetylsalicylic acid and rhodamine B.The interaction of the acceptor molecules with anions (F-,Cl-,HSO-4,H2PO-4,Ac-,ClO-4) were studied using naked eye recognition,UV-Vis absorption spectra and fluorescence spectra.The results showed that in the acetonitrile solvent,the receptor molecules L1 and L2 showed higher selectivity for F-,and the addition of F- increased the absorbance of the receptor molecule.In the ethanol solvent,the UV absorption wavelength of the acceptor molecule L3 red shifts after the addition of F-and a new fluorescence value appeared at 620nm,which shown the selective recognition of F-.With the increase of the concentration of F-,the absorbance and fluorescence of receptor L3 increased in turn,showing gradient changes.
[1] 刘瑞源,勇雪,杨小东.基于2-硫代海因的氟离子探针[J].有机化学,2014,34(3):561-565.
[2] 王军,元以中,田晓慧.新型金属羰基红外化学传感器的合成及对氟离子的识别性能[J].化学研究,2013,24(4):339-343.
[3] 周应,李正钱,任君.对氟离子选择性识别的新型比色化学传感器分子的设计合成与性能[J].化学传感器,2012,32(4):44-48.
[4] 王润和,刘军民,麦健航.基于杯[6]芳烃的选择性识别氟离子和丙二酸的荧光传感器[J].有机化学,2008(7):1213-1217.
[5] 朱玉莲,张小燕,张岐.新型硫脲分子-Gd(Ⅲ)配合物对氟离子的选择性识别研究[J].化学学报,2011,69(6):709-712.
[6] 徐哲,付艳艳,苗自婷.席夫碱类高选择性氟离子化学传感器的研究[J].化学通报,2009,72(3):285-288.
[7] 孔祥娟,陈亚斌,王馨.一种新型比色荧光增强型探针识别氟离子[J].分析试验室,2017,36(10):1151-1155.
[8] 吕永军.一种氟离子比色探针的合成及识别研究[J].化学试剂,2015,37(6):555-557.
[9] 刘艳红,张曼,刘阁.一种硫脲受体的合成及其对阴离子识别的研究[J].化学研究与应用,2016,28(11):1605-1609.
[10] 杨世龙,姜维娜,印彬.槲皮素作为荧光探针对氟离子的识别作用[J].光谱学与光谱分析,2016,36(11):3582-3587.
[11] 张曼,赵敏.Co2+分子荧光探针的合成与表征[J].化工新型材料,2019,47(8):140-142,147.