综述与专论

高镍正极材料LiNi0.6Co0.2Mn0.2O2的研究进展

展开
  • 1.许昌职业技术学院园林与食品工程学院,许昌461000;
    2.许昌学院学报编辑部,许昌461000
邢晓柯(1980-),女,讲师,硕士,主要研究方向为分析化学。

收稿日期: 2019-11-11

  修回日期: 2020-12-29

  网络出版日期: 2021-05-10

基金资助

河南省科技厅项目(182102210501);许昌市科技攻关计划(20170211053)

Research progress on LiNi0.6Co0.2Mn0.2O2 rich-nickel anode material

Expand
  • 1. College of Landscape and Food Engineering,Xuchang Vocational Technical College, Xuchang 461000;
    2. Editorial Department of Journal,Xuchang University,Xuchang 461000

Received date: 2019-11-11

  Revised date: 2020-12-29

  Online published: 2021-05-10

摘要

高镍正极材料LiNi0.6Co0.2Mn0.2O2(NCM622)由于比容量高、价格低等优点,被认为是最有前景的正极材料之一。在介绍NCM622存在的问题的基础上,分别从合成方法、改进措施等方面进行总结,并对NCM622的未来发展进行展望。

本文引用格式

邢晓轲, 卫世乾 . 高镍正极材料LiNi0.6Co0.2Mn0.2O2的研究进展[J]. 化工新型材料, 2021 , 49(3) : 48 -52 . DOI: 10.19817/j.cnki.issn 1006-3536.2021.03.012

Abstract

LiNi0.6Co0.2Mn0.2O2,a high-nickel anode material,is considered as one of the most promising anode materials due to its advantages of high specific capacity and low price.Based on the introduction of the existing problems of NCM622,the synthesis methods and improvement measures were summarized,and prospected the future development of NCM622.

参考文献

[1] 关小云,洪朝钰,朱建平,等.高首效富镍正极材料LiNi0.6Co0.2Mn0.2O2的合成及电化学性能研究[J].电化学,2018,24(1):56-62.
[2] 唐盛贺,周汉章,刘更好,等.类单晶正极材料LiNi0.6Co0.2Mn0.2O2的制备与表征[J].化工新型材料,2017,45(4):139-141.
[3] Wang L,Mu D B,Wu B R,et al.Enhanced electrochemical performance of lithium metasilicate-coated LiNi0.6Co0.2Mn0.2O2,Ni-rich cathode for Li -ion batteries at high cutoff voltage[J].Electrochimica Acta,2016,222:806-813.
[4] 袁晶.锂离子电池正极材料LiNi0.6Co0.2Mn0.2O2的合成与改性[D].合肥:合肥工业大学,2017.
[5] 艾灵.锂离子电池三元正极材料LiNi0.6Co0.2Mn0.2O2的制备及改性研究[D].兰州:兰州理工大学,2019.
[6] Zhang Y,Cao H,Zhang J,et al.Synthesis of LiNi0.6Co0.2Mn0.2O2 cathode material by a carbonate co-precipitation method and its electrochemical characterization[J].Solid State Ionics,2006,177:3303-3307.
[7] Liang L W,Du K,Peng Z D,et al.Co-precipitation synthesis of Ni0.6Co0.2Mn0.2(OH)2 precursor and characterization of LiNi0.6Co0.2Mn0.2O2 cathode material for secondary lithium batteries[J].Electrochem Acta,2014,130:82-89.
[8] Lee S W,Kim H,Kim M S,et al.Improved electrochemical performance of LiNi0.6Co0.2Mn0.2O2 cathode material synthesized by citric acid assisted sol-gel method for lithium ion batteries[J].Journal of Power Sources,2016,315:261-268.
[9] 孙淑婷.锂离子电池三元正极材料LiNi0.6Co0.2Mn0.2O2的制备与改性[D].天津:天津大学,2015.
[10] Yue P,Wang Z,Guo H,et al.Effect of synthesis routes on the electrochemical performance of LiNi0.6Co0.2Mn0.2O2 for lithium ion batteries[J].Journal of Solid State Electrochemistry,2012,16(12):3849-3854.
[11] Li T,Li X H,Wang Z X,et al.Electrochemical properties of LiNi0.6Co0.2Mn0.2O2 as cathode by ultrasonic spray pyrolysis[J].Materials Letters,2015,159:39-42.
[12] 宗意恒.熔盐法制备高镍三元正极材料及其在锂电池领域的应用[D].北京:中国矿业大学,2019.
[13] Wang L,Wu B R,Mu D B,et al.Single-crystal LiNi0.6Co0.2Mn0.2O2 as high performance cathode materials for Li-ion batteries[J].Journal of Alloys and Compounds,2016,674:360-367.
[14] 盛锁江,王振伟,耿海龙,等.高温固相法合成LiNi0.6Co0.2Mn0.2O2的电化学性能[J].电池,2017,47(4):196-198.
[15] Luo X,Wang X,Liao L,et al.Synthesis and charaterization of high tap-density lanyeired Li[Ni1/3Co1/3Mn1/3]O2 cathode material via hydroxide coprecipition[J].Journal of Power Sources,2006,158(1):6.
[16] Yuan J,Wen J,Zhang J,et al.Influence of calcination atmosphere on structure and electrochemical behavior of LiNi0.6Co0.2Mn0.2O2 cathode material for lithium-ion batteries[J].Electrochimica Acta,2017,230:116-122.
[17] 陈道明.键离子电池三元正极材料的制备及其改性硏究[D].合肥:合肥工业大学,2016.
[18] 李邑柯,刘婧婧,吴开洪.压实密度对LiNi0.6Co0.2Mn0.2O2性能的影响[J].电池,2018,48(3):188-190.
[19] Wang R H,Xiao S H,Li X H,et al.Structural and electro-chemical performance of Na-doped Li3V2(PO4)3/C cathode materials for lithium-ion batteries via rheological phase reaction[J].J Alloys Compd,2013,575:268-272.
[20] Cheng K L,Mu D B,Wu B R,et al.Electrochemical performance of a nickel-rich LiNi0.6Co0.2Mn0.2O2 cathode material for lithium-ion batteries under different cut-off voltages[J].International Journal of Minerals Metallurgy and Materials,2017,24(3):342-351.
[21] 王宁.不同电解液体系对LiNi0.6Co0.2Mn0.2O2电极电化学性能的影响[D].北京:中国矿业大学,2019.
[22] Huang Z J,Wang Z X,Jing Q,et al.Investigation on the effect of Na doping on structure and Li-ion kinetics of layered LiNi0.6Co0.2Mn0.2O2 cathode material[J].Electrochimica Acta,2016,192:120-126.
[23] 郑卓,吴振国,向伟,等.Na+掺杂锂离子电池正极材料LiNi0.6Co0.2Mn0.2O2的制备及电化学性能[J].高等学校化学学报,2017,38(8):1458-1464.
[24] Huang Z J,Wang Z X,Zheng X B,et al.Effect of Mg doping on the structural and electrochemical performance of LiNi0.6Co0.2Mn0.2O2 cathode materials[J].Electrochimica Acta,2015,182:795-802.
[25] 夏云飞.层状三元材料LiNi0.6Co0.2Mn0.2O2的烧结工艺及其Al离子掺杂改性研究[D].哈尔滨:哈尔滨工业大学,2015.
[26] 邱世涛,钟盛文,李婷婷,等.Cu掺杂LiNi0.6Co0.2Mn0.2O2的电化学性能[J].有色金属科学与工程,2018,9(5):21-25.
[27] Schipper F,Dixit M,Kovacheva D,et al.Stabilizing nickel-rich layered cathode materials by a high-charge cation doping strategy:zirconium doped LiNi0.6Co0.2Mn0.2O2[J].Journal of Materials Chemistry A,2016,4:16073.
[28] 温张凡.石墨烯添加和钼掺杂对LiNi0.6Co0.2Mn0.2O2材料电化学性能的影响研究[D].南宁:广西大学,2019.
[29] 王东晨.锂离子电池正极材料LiNi0.6Co0.2Mn0.2O2的制备与改性研宄[D].南宁:广西大学,2017.
[30] 岳鹏.表面氟化提高LiNi0.6Co0.2Mn0.2O2正极材料的循环及存储性能[J].轻工科技,2016(9):29-30.
[31] Yue P,Wang Z,Li X,et al.The enhanced electrochemical performance of LiNi0.6Co0.2Mn0.2O2 cathode materials by low temperature fluorine substitution[J].Elecirochimica Acta,2013,95(11):112-118.
[32] 郭丽敏,顾志伟,刘全兵.LiNi0.6Co0.2Mn0.2O2正极材料碳包覆改性研究[J].电源技术,2019(8):1273-1274.
[33] 杨菲.富镍三元正极材料LiNi0.6Co0.2Mn0.2O2的制备工艺优化以及表面改性[D].兰州:西北师范大学,2017.
[34] Chen Y P,Zhang Y,Wang F,et al.Improve the structure and electrochemical performance of LiNi0.6Co0.2Mn0.2O2 cathode material by nano-Al2O3 ultrasonic coating[J].Journal of Alloys and Compounds,2014,611:135-141.
[35] 陶芬.锂离子电池正极材料LiNi0.6Co0.2Mn0.2O2的表面包覆改性研究[D].天津:天津大学,2016.
[36] 王梓.锂离子电池正极材料LiNi0.6Co0.2Mn0.2O2[D].昆明:昆明理工大学,2018.
[37] 左达先.层状正极材料均一化表面修饰及其电/化学性能研究[D].杭州:中国计量大学,2016.
[38] Jo C H,Cho D H,Noh H J,et al.An effective method to reduce residual lithium compounds on Ni-rich LiNi0.6Co0.2Mn0.2O2 active material using a phosphoric acid derived Li3PO4 nanolayer[J].Nano Research,2015,8:1464-1479.
[39] Liu S,Wu H,Huang L,et al.Synthesis of Li2Si2O5-coated LiNi0.6Co0.2Mn0.2O2 cathode materials with enhanced high-voltage electrochemical properties for lithium-ion batteries[J].Journal of Alloys and Compounds,2016,674:447-454.
[40] 王垒.高比容量锂离子电池正极材料LiNi0.6Co0.2Mn0.2O2的制备及其改性研究[D].北京:北京理工大学,2017.
[41] 朱春晓,向伟,吴振国,等.锂离子电池正极材料LiNi0.6Co0.2Mn0.2O2的LaF3包覆改性研究[J].广东化工,2018,45(10):11-13.
[42] 申静,王志斌,吴振国,等.LaF3包覆改性提升LiNi0.6Co0.2Mn0.2O2正极材料电化学性能的研究[J].化学研究与应用,2019,31(8):1518-1527.
[43] 王丽媛,李建刚,姚琼,等.高容量富锂三元材料xLiMn2O3·(1-x)LiNi0.6Co0.2Mn0.2O2的制备与性能研究[J].化工新型材料,2019,47(3):67-71.
[44] 王东晨,宋美霖,罗珑玲.PVP辅助LiMn2O4包覆LiNi0.6Co0.2Mn0.2O2正极材料的制备及其电化学性能[J].硅酸盐学报,2018(5):643-648.
[45] 要旭.锂离子电池层状三元材料LiNi0.6Co0.2Mn0.2O2的制备及其界面改性研究.电子科技大学,2016.
[46] 唐盛贺,周汉章,刘更好,等.类单晶正极材料LiNi0.6Co0.2Mn0.2O2的制备与表征[J].化工新型材料,2017,45(4):139-141.
[47] 杨娟,郑江峰,杨幸.锂离子电池单晶型LiNi0.6Co0.2Mn0.2O2正极材料的合成与研究[J].世界有色金属,2019(4月上):136-139.
[48] 贺雨阳.单晶LiNi0.6Co0.2Mn0.2O2正极材料的合成与改性[D].长沙:长沙矿冶研究院,2018.
[49] 孙一茗.不同核壳结构正极材料LiNi0.6Co0.2Mn0.2O2的设计、制备及电化学性能研究[D].天津:天津理工大学,2019.
Options
文章导航

/