类石墨烯MXene的制备及储氢研究进展

张绰, 李喜德, 邹浩然, 刘羽祚, 杨军胜

doi:10.19817/j.cnki.issn1006-3536.2021.04.002

化工新型材料 >

2021 , Vol. 49 >Issue 4: 6 - 10

DOI: https://doi.org/10.19817/j.cnki.issn1006-3536.2021.04.002

综述与专论

类石墨烯MXene的制备及储氢研究进展

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武汉轻工大学机械工程学院,武汉430023

张绰(1996-),男,硕士研究生,主要从事多孔材料、膜分离材料和微纳材料的研究。

收稿日期: 2020-01-06

修回日期: 2020-01-28

网络出版日期: 2021-05-07

基金资助

国家自然科学基金(51704221,51875418);武汉轻工大学杰出青年基金(2018J05)

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Research on preparation and hydrogen storage of graphene-like MXene

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Schoolof Mechanical Engineering,Wuhan Polytechnic University,Wuhan 430023

Received date: 2020-01-06

Revised date: 2020-01-28

Online published: 2021-05-07

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摘要

近年来,氢能源因燃烧性能好、发热值高、可再生、无污染等优点而被广泛关注,但由于其难以在高密度下存储,且在存储过程中会释放大量热量,因此寻找低温环境的储氢材料成为科学家面临的巨大挑战。MXene作为一种新型二维过渡金属碳化物或氮化物,因性能优异,具有高的比表面积、优异的热力学稳定性、可调控的层间距,而在储氢领域备受关注。综述了MXene材料的制备方法,并利用第一性原理从理论上分析其储氢机理,探究了MXene复合材料的储氢性能,指出现阶段MXene在储氢领域存在的问题并对其发展方向进行了展望。

关键词： MXene; 第一性原理; 复合材料; 制备; 储氢

本文引用格式

张绰, 李喜德, 邹浩然, 刘羽祚, 杨军胜 . 类石墨烯MXene的制备及储氢研究进展[J]. 化工新型材料, 2021 , 49(4) : 6 -10 . DOI: 10.19817/j.cnki.issn1006-3536.2021.04.002

Abstract

Recently,hydrogen energy has obtained widely attention due to its advantages such as good combustion performance,high heating value,renewable,and pollution-free.However it is difficult to store at high density,and it releases a lot of heat during the process of the storage.Therefore,it becomes a huge challenge for scientists to find hydrogen storage materials in the environment of low temperature.The MXene is a novel 2D transition metal carbide or nitride,which has attracted much attention in the field of hydrogen storage owing to its excellent performance,high specific surface area,excellent thermodynamic stability,and adjustable interlayer spacing.The preparation methods of MXene materials was reviewed,and analyzed its hydrogen storage mechanism by using the first-principle theoretically,and explored the hydrogen storage properties of MXene composites materials.It also pointed out the problems existing at the present stage,and looked forward to the development direction of MXene in the field of hydrogen storage.

Key words： MXene; first principles; composite material; preparation; hydrogen storage

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