开发与应用

聚苯胺在离子交换膜中的应用进展

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  • 1.兰州交通大学环境与市政工程学院,兰州730070;
    2.寒旱区水资源综合利用教育部工程研究中心,兰州730070
褚云晨(1995-),女,硕士研究生,主要从事离子交换膜的制备及改性研究。

网络出版日期: 2020-10-20

基金资助

国家自然科学基金(51804150);兰州交通大学优秀平台(201606)

Research progress on PANi Used in ion exchange membrane

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  • 1.School of Environmental and Municipal Engineering,Lanzhou Jiaotong University, Lanzhou 730070;
    2.Engineering Research Center for Cold and Arid Regions Water Resource Comprehensive Utilization,Ministry of Education,Lanzhou 730070

Online published: 2020-10-20

摘要

介绍了聚苯胺(PANi)在离子交换膜中的应用,综述了PANi对Nafion膜、聚偏氟乙烯(PVDF)膜和非氟离子交换膜性能的影响。发现PANi能有效地改善膜的含水率、离子传导率、选择透过性,以及应用于燃料电池时所需的阻醇性,最后提出了PANi在离子交换膜中的研究方向,为复合离子交换膜的研究与应用提供参考。

本文引用格式

褚云晨, 王三反, 张学敏 . 聚苯胺在离子交换膜中的应用进展[J]. 化工新型材料, 2020 , 48(10) : 258 -262 . DOI: 10.19817/j.cnki.issn 1006-3536.2020.10.055

Abstract

The application of polyaniline (PANi) in ion exchange membranes was briefly introduced.The effects of PANi on the properties of Nafion membrane,polyvinylidene fluoride (PVDF) membrane and non-fluoride ion exchange membrane were reviewed.It was found that PANi can effectively improve the water uptake,ion conductivity,permselectivity and methanol resistance required for fuel cells.Finally,the research direction of PANi used in ion exchange membrane was proposed,and provided a reference for the research and application of composite ion exchange membrane.

参考文献

[1] Villaluenga J P G, Barragan V M, lzquierdo-Gil MA, et al.Comparative study of liquid uptake and permeation characteristics of sulfonated cation-exchange membranes in water and methanol[J].Journal of Membrane Science, 2008, 323(2):421-427.
[2] Strathmann H.Electrodialysis, a mature technology with a multitude of new applications[J].Desalination, 2010, 264(3):268-288.
[3] Guler E, Van B W, Saakes M, et al.Monovalent-ion-selective membranes for reverse electrodialysis[J].Journal of Membrane Science, 2014, 455(4):254-270.
[4] Xu T, Huang C.Electrodialysis-based separation technologies:a critical review[J].AIChE Journal, 2008, 54(12):3147-3159.
[5] Molavian M R, Abdolmaleki A, Firouz Tadavani K, et al.A new sulfonated poly(ether sulfone) hybrid with low humidity dependence for high temperature proton exchange membrane fuel cell applications[J].Journal of Applied Polymer Science, 2017:45342.
[6] Thankamony R L, Won M, Kim T H.Terminally-crosslinked poly(ether sulfone) block copolymer, as a highly selective and stable polymer electrolyte membrane for DMFC applications[J].International Journal of Hydrogen Energy, 2013, 38(12):5084-5091.
[7] Sutharssan T, Montalvao D, Chen Y, et al.A review on prognostics and health monitoring of proton exchange membrane fuel cell[J].Renewable & Sustainable Energy Reviews, 2016, 75.
[8] Zhang H W, Chen D Z, Xianze Y, et al.Anion-exchange membranes for fuel cells:synthesis strategies, properties and perspectives[J].Fuel Cells, 2015, 15(6):761-780.
[9] Weiss R.Polymer blends based on sulfonated poly(ether ketone ketone) and poly(ether sulfone) as proton exchange membranes for fuel cells[J].Journal of Membrane Science, 2005, 256(1):122-133.
[10] Neburchilov V, Martin J, Wang H, et al.A review of polymer electrolyte membranes for direct methanol fuel cells[J].Journal of Power Sources, 2007, 169(2):221-238.
[11] 张宏伟, 沈培康.燃料电池聚合物电解质膜的研究进展[J].中国科学:化学, 2012(7):954-982.
[12] Lufrano F, Baglio V, Staiti P, et al.Polymer electrolytes based on sulfonated polysulfone for direct methanol fuel cells[J].Journal of Power Sources, 2008, 179(1):34-41.
[13] Hosseini S M, Madaeni S S, Khodabakhshi A R, et al.Preparation and surface modification of PVC/SBR heterogeneous cation exchange membrane with silver nanoparticles by plasma treatment[J].Journal of Membrane Science, 2010, 365(1):438-446.
[14] Hosseini S M, Madaeni S S, Khodabakhshi A R.Preparation and characterization of PC/SBR heterogeneous cation exchange membrane filled with carbon nano-tubes[J].Journal of Membrane Science, 2010, 362(1-2):550-559.
[15] Fan Z, Wang Z, Sun N, et al.Performance improvement of polysulfone ultrafiltration membrane by blending with polyaniline nanofibers[J].Journal of Membrane Science, 2008, 320(1-2):363-371.
[16] Zhao S, Wang Z, Wei X, et al.Performance improvement of polysulfone ultrafiltration membrane using PANiEB as both pore forming agent and hydrophilic modifier[J].Journal of Membrane Science, 2011, 385-386(none):251-262.
[17] Compan V, Riande E, Fernandez-Carretero F J, et al.Influence of polyaniline intercalations on the conductivity and permselectivity of perfluorinated cation-exchange membranes[J].Journal of Membrane Science, 2008, 318(1-2):255-263.
[18] Khan A A, Baig U.Electrically conductive membrane of polyaniline-titanium(Ⅳ)phosphate cation exchange nanocomposite:applicable for detection of Pb(Ⅱ) using its ion-selective electrode[J].Journal of Industrial and Engineering Chemistry, 2012, 18(6):1937-1944.
[19] Diaz L A, Abuin G C, Corti H R.Methanol sorption and permeability in Na[J].Journal of Membrane Science, 2012, 411-412(9):35-44.
[20] Zhang H, Huang H, Shen P K.Methanol-blocking Nafion composite membranes fabricated by layer-by-layer self-assembly for direct methanol fuel cells[J].International Journal of Hydrogen Energy, 2012, 37(8):6875-6879.
[21] Kundu P P, Kim B T, Ahn J E, et al.Formation and evaluation of semi-IPN of nafion 117 membrane for direct methanol fuel cell:1.Crosslinked sulfonated polystyrene in the pores of nafion 117[J].Journal of Power Sources, 2007, 171(1):86-91.
[22] Wang C H, Chen C C, Hsu H C, et al.Low methanol-permeable polyaniline/Nafion composite membrane for direct methanol fuel cells[J].Journal of Power Sources, 2009, 190(2):279-284.
[23] Kingshuk Dutta, Suparna Das, Patit Paban Kundu.Partially sulfonated polyaniline induced high ion-exchange capacity and selectivity of Nafion membrane for application in direct methanol fuel cells[J].Journal of Membrane Science, 2015, 473(1):94-101.
[24] Nasef M M, Aly A A.Water and charge transport models in proton exchange membranes:an overview[J].Desalination, 2012, 287(none):238-246.
[25] Yang J Y, Shen P K, Varcoe J, et al.Nafion/polyaniline composite membranes specifically designed to allow proton exchange membrane fuel cells operation at low humidity[J].Journal of Power Sources, 2009, 189(2):1016-1019.
[26] Farrokhzad H, Darvishmanesh S, Genduso G, et al.Development of bivalent cation selective ion exchange membranes by varying molecular weight of polyaniline[J].Electrochimica Acta, 2015, 158:64-72.
[27] Firdaous L, Maleriat J P, Schlumpf J P, et al.Transfer of monovalent and divalent cations in salt solutions by electrodialysis[J].Separation Science and Technology, 2007, 42(5):931-948.
[28] Zhang Y M, Zou L, Ladewig B P, et al.Synthesis and characterisation of superhydrophilic conductive heterogeneous PANI/PVDF anion-exchange membranes[J].Desalination, 2015, 362:59-67.
[29] Kusoglu A, Weber A.New insights into perfluorinated sulfonic-acid ionomers[J].Chemical Reviews, 2017, 117(3):987.
[30] Fechete R, Demco D E, Zhu X, et al.Water states and dynamics in perfluorinated ionomer membranes by 1H one- and two-dimensional NMR spectroscopy, relaxometry, and diffusometry[J].Chemical Physics Letters, 2014, 597:6-15.
[31] Sun P, Li Z F, Wang S W, et al.Performance enhancement of polybenzimidazole based high temperature proton exchange membranes with multifunctional crosslinker and highly sulfonated polyaniline[J].Journal of Membrane Science, 2018, 549(1):660-669.
[32] Chen Z, Huang W, Fang P F, et al.The hydrogen bond and free volume property of poly(ether-urethane) irradiated by neutron[J].Journal of Polymer Science Part B Polymer Physics, 2010, 48(3):381-388.
[33] Elakkiya S, Arthanareeswaran G, Lsmail A F, et al.Polyaniline coated sulfonated TiO2 nanoparticles for effective application in proton conductive polymer membrane fuel cell[J].European Polymer Journal, 2018.
[34] Elakkiya S, Arthanareeswaran G, Venkatesh K, et al.Enhancement of fuel cell properties in polyethersulfone and sulfonated poly (ether ether ketone) membranes using metal oxide nanoparticles for proton exchange membrane fuel cell[J].International Journal of Hydrogen Energy, 2018:1-10.
[35] Nagarale R K, Gohil G S, Shahi V K, et al.Sulfonated poly(ether ether ketone)/polyaniline composite proton-exchange membrane[J].Journal of Membrane Science, 2006, 280(1):389-396.
[36] Hasanisadrabadi M M, Dashtimoghadam E, Ghaffarian S R, et al.Novel high-performance nanocomposite proton exchange membranes based on poly (ether sulfone)[J].Renewable Energy, 2010, 35(1):226-231.
[37] Vijayalekshmi V, Khastgir D.Hybrid composite membranes of chitosan/sulfonated polyaniline/silica as polymer electrolyte membrane for fuel cells[J].Carbohydrate Polymers, 2017.
[38] Varghese J G, Kittur A A, Rachipudi P S, et al.Synthesis, characterization and pervaporation performance of chitosan-g-polyaniline membranes for the dehydration of isopropanol[J].Journal of Membrane Science, 2010, 364(1):111-121.
[39] Hosseini S M, Jeddi F, Nemati M, et al.Electrodialysis heterogeneous anion exchange membrane modified by PANI/MWCNT composite nanoparticles:Preparation, characterization and ionic transport property in desalination[J].Desalination, 2014, 341:107-114.
[40] Zhao S, Wang Z, Wang J, et al.PSF/PANI nanocomposite membrane prepared by in situ blending of PSF and PANI/NMP[J].Journal of Membrane Science, 2011, 376(1):83-95.
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