科学研究

元明粉表面接枝甲基丙烯酸甲酯/聚甲基乙撑碳酸酯复合材料的制备与性能研究

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  • 贵州大学材料与冶金学院,贵阳550025
赵平源(1963-),男,专科,实验师,主要研究方向为有色金属冶金。

收稿日期: 2019-04-19

  修回日期: 2020-05-28

  网络出版日期: 2020-10-23

基金资助

国家自然科学基金(51764006和51864012);贵州省科学合作计划项目([2019]1411、[2017]5788、[2018]5781、[2016]5302和[2019]2841)

Study on preparation and property of MMA/PPC composite grafted with sodium sulfate

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  • School of Materials and Metallurgy,Guizhou University,Guiyang 550025

Received date: 2019-04-19

  Revised date: 2020-05-28

  Online published: 2020-10-23

摘要

以元明粉(Na2SO4,简称S)作为改性剂,甲基丙烯酸甲酯(MMA)、聚甲基乙撑碳酸酯(PPC)为基体,通过密炼机进行熔融共混制得元明粉-MMA/PPC复合材料。采用拉伸、热失重及扫描电镜对S-MMA/PPC复合材料进行拉伸性能、热力学性能以及微观形貌的分析。结果表明:随着S-MMA接枝聚合物含量的增加,S-MMA/PPC复合材料的拉伸强度逐渐增加,断裂伸长率逐渐下降;S-MMA提高了PPC的结晶性和热稳定性,同时S-MMA/PPC复合材料的相容性较好。

本文引用格式

赵平源, 秦吉涛 . 元明粉表面接枝甲基丙烯酸甲酯/聚甲基乙撑碳酸酯复合材料的制备与性能研究[J]. 化工新型材料, 2020 , 48(8) : 149 -151 . DOI: 10.19817/j.cnki.issn 1006-3536.2020.08.032

Abstract

Sodium sulfate(S) was used as a modifier,methyl methacrylate (MMA) and polymethylethylene carbonate (PPC) were used as the matrix,and melted and blended by an internal mixer to obtain S-MMA/PPC composite.The tensile properties,thermodynamic properties and microstructure of S-MMA/PPC were analyzed by tensile,thermogravimetric and scanning electron microscopy.The results shown that with the increase of S-MMA graft polymer content,the tensile strength of S-MMA/PPC composite increased gradually,and the elongation at break decreased gradually.S-MMA improved the crystallinity and thermal stability of PPC.At the same time,the compatibility of S-MMA/PPC was better.

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