科学研究

CTS/纳米CaCO3的制备及对水中Cu(Ⅱ)吸附性能研究

  • 陶萍芳 ,
  • 龙静雯 ,
  • 黄花粉 ,
  • 陈珊 ,
  • 陈志林 ,
  • 黄国保 ,
  • 杨炳枚 ,
  • 刘敏 ,
  • 林韦 ,
  • 罗志辉
展开
  • 玉林师范学院,化学与食品科学学院,广西农产资源化学与生物技术重点实验室,广西高校桂东南特色农产资源高效利用重点实验室,玉林537000
陶萍芳(1982-),女,硕士,高级实验师,主要从事无机功能材料研究。

收稿日期: 2021-03-05

  修回日期: 2021-06-23

  网络出版日期: 2021-08-19

基金资助

国家自然科学基金(21961042);广西创新驱动发展专项资金项目(桂科AA18242015);玉林师范学院市校合作项目(YLSXZD2019017);玉林师范学院大学生创新创业训练计划项目(202010606037,202010606145,202110606034)

Study on the preparation of CTS/nano CaCO3 and its adsorption property of Cu(Ⅱ) in water

  • Tao Pingfang ,
  • Long Jingwen ,
  • Huang Huafen ,
  • Chen Shan ,
  • Chen Zhilin ,
  • Huang Guobao ,
  • Yang Bingmei ,
  • Liu Min ,
  • Lin Wei ,
  • Luo Zhihui
Expand
  • Guangxi Key Laboratory of Agricultural Resources Chemistry and Biotechnology,Colleges and Universities Key Laboratory for Efficient Use of Agricultural Resources in the Southeast of Guangxi,College of Chemistry and Food Science,Yulin Normal University,Yulin 537000

Received date: 2021-03-05

  Revised date: 2021-06-23

  Online published: 2021-08-19

摘要

以壳聚糖(CTS)与纳米CaCO3为原料,采用简单的凝胶改性法,制备出吸附性能更佳的CTS/纳米CaCO3复合材料。利用XRD,SEM,FT-IR以及AAS等对其进行结构和性能分析。以硝酸铜溶液为模拟废液进行吸附实验,探讨CTS/纳米CaCO3复合吸附材料的吸附性能。通过简单的改性实验,成功制备了CTS/纳米CaCO3复合吸附材料。在28℃下,探究了吸附时间,模拟溶液pH,以及Cu2+的不同初始浓度对吸附性能的影响。

本文引用格式

陶萍芳 , 龙静雯 , 黄花粉 , 陈珊 , 陈志林 , 黄国保 , 杨炳枚 , 刘敏 , 林韦 , 罗志辉 . CTS/纳米CaCO3的制备及对水中Cu(Ⅱ)吸附性能研究[J]. 化工新型材料, 2021 , 49(7) : 185 -189 . DOI: 10.19817/j.cnki.issn 1006-3536.2021.07.042

Abstract

Using CTS and nano calcium carbonate (CaCO3) as raw materials,CTS/Nano CaCO3 composite materials with better adsorption properties were prepared through gel method.The structural characteristics were analyzed by XRD,SEM,FTIR and AAS.The adsorption properties of the CTS/nano CaCO3 were evaluated by using Cu(Ⅱ) nitrate solution as a simulated adsorption experiment.The results showed that the CTS/nano CaCO3 were successfully prepared.The effects of adsorption time,pH value of simulated solution,and different initial concentrations of Cu(Ⅱ) on adsorption performance were investigated at 28℃.The results shown that the adsorption performance of CTS/nano CaCO3,obtained by composite modification,was better than that of CTS or nano CaCO3.

参考文献

[1] 李珂珂,段正洋,云露,等.改性壳聚糖材料在含重金属废水处理中的应用研究进展[J].硅酸盐通报,2018,37(5):1637-1642.
[2] 梁栋,刘伟,杨仲田.丙烯酰胺改性壳聚糖处理含Co2+模拟放射性废水吸附工艺研究[J].化工新型材料,2019,47(11):204-208.
[3] 张毅,张转玲,黎淑婷,等.壳聚糖对重金属离子的吸附性能[J].天津工业大学学报,2016,35(3):16-20.
[4] 林越呈,王宏鹏,龚金炎,等.改性壳聚糖微球制备及其对阴离子染料的吸附行为研究[J].高校化学工程学报,2017,31(2):470-477.
[5] 熊鑫,王明强,范倩,等.改性壳聚糖微球合成及对Cu2+吸附性能的研究[J].化工新型材料,2017,45(12):160-163.
[6] 肖芳芳,张莹莹,程建华,等.壳聚糖/磁性生物碳对重金属Cu(Ⅱ)的吸附性能[J].环境工程学报,2019,13(5):1048-1055.
[7] 李林波,马键.氧化石墨烯/改性磁性壳聚糖复合材料对Cu2+的吸附研究[J].化工新型材料,2019,47(8):261-264.
[8] 王勇力,刘妮,李海洋,等.硅胶改性壳聚糖膜的制备及其对Cu2+的吸附性能[J].无机盐工业,2019,51(8):60-63.
[9] 傅明连,高果,韩煜,等.磁性交联壳聚糖微球对Cu2+的吸附性能研究[J].化学研究与应用,2020,32(4):664-670.
[10] 刘珊,赵春朋,李涛,等.改性壳聚糖凝胶球对Cu(Ⅱ)的吸附[J].环境化学,2020,39(7):2013-2021.
[11] 王萌,罗运柏,于萍.壳聚糖改性活性炭纤维毡处理含铜废水的研究[J].工业水处理,2019,39(2):62-66.
[12] 郭逗逗,庞浩,刘海露,等.壳聚糖复合水凝胶对水溶液中铜离子(Ⅱ)的高效吸附[J].林产化学与工业,2014,34(1):8-12.
[13] Sutirman Z A,Rahim E A,Sanagi M M,et al.New efficient chitosan derivative for Cu(Ⅱ) ions removal:Characterization and adsorption performance[J].International Journal of Biological Macromolecules,2020,153(15):513-522.
[14] 徐晓玲,梅安待,罗自生,等.壳聚糖添加纳米碳酸钙助剂涂膜对枇杷品质的影响[J].食品与发酵工业,2008,34(4):142-145.
[15] 段贤扬,何梦奇,徐继红,等.CTS-g-PAA/ATP水凝胶制备及对染料的吸附性能[J].功能材料,2020,51(2):2203-2208.
Options
文章导航

/