Research progress on preparation and application of graphene/TiO2-based ternary composite
Xin Wangpeng1, Li Yanjing1,2, Zhou Guowei1
1.Key Laboratory of Fine Chemicals in Universities of Shandong,School of Chemistry and Pharmaceutical Engineering,Qilu University of TechnologyShandong Academy of Sciences,Jinan 250353; 2.Yanzhou Coal Mining Company Limited,Zoucheng 273500
Abstract: Graphene/TiO2-based ternary composites have excellent physical and chemical properties.Compared with graphene/TiO2 cmposites,ternary composites have more excellent electrochemical properties and photocatalytic activity.The preparation methods of graphene/TiO2/metal element,graphene/TiO2/metal oxide,graphene/TiO2/metal sulfide were reviewed.Furthermore,the applications of these composites for lithium ion battery,dye-sensitized solar cells and photocatalysis were discussed.The synthesis and application about graphene/TiO2-based ternary composites were outlooked.
辛王鹏, 李艳敬, 周国伟. 石墨烯/TiO2基三元复合材料的制备及应用研究进展[J]. 化工新型材料, 2019, 47(6): 1-6.
Xin Wangpeng, Li Yanjing, Zhou Guowei. Research progress on preparation and application of graphene/TiO2-based ternary composite. New Chemical Materials, 2019, 47(6): 1-6.
Novoselov K S,Geim A K,Morozov S V,et al.Electric field effect in atomically thin carbon films[J].Science,2004,306(5696):666-669.
[2]
Zhang Z Y,Xiao F,Guo Y L,et al.One-pot self-assembled three-dimensional TiO2-graphene hydrogel with improved adsorption capacities and photocatalytic and electrochemical activities[J].ACS Applied Materials & Interfaces,2013,5(6):2227-2233.
[3]
Cheng G,Akhtar M S,Yang O B,et al.Novel preparation of anatase TiO2@reduced graphene oxide hybrids for high-performance dye-sensitized solar cells[J].Applied Materials & Interfaces,2013,5(14):6635-6642.
[4]
Li Y,Cui W Q,Liu L,et al.Removal of Cr(Ⅵ) by 3D TiO2-graphene hydrogel via adsorption enriched with photocatalytic reduction[J].Applied Catalysis B Environmental,2016,199:412-423.
[5]
Liu Y P,Gao T T,Xiao H,et al.One-pot synthesis of rice-like TiO2/graphene hydrogels as advanced electrodes for supercapacitors and the resulting aerogels as high-efficiency dye adsorbents[J].Electrochimica Acta,2017,229:239-252.
[6]
Qian W,Greaney P A,Fowler S,et al.Low-temperature nitrogen doping in ammonia solution for production of N-doped TiO2-hybridized graphene as a highly efficient photocatalyst for water treatment[J].ACS Sustainable Chemistry & Engineering,2014,2(7):1802-1810.
[7]
Wang P,Han L,Zhu C Z,et al.Aqueous-phase synthesis of Ag-TiO2-reduced graphene oxide and Pt-TiO2-reduced graphene oxide hybrid nanostructures and their catalytic properties[J].Nano Research,2011,4(11):1153-1162.
[8]
Liu X J,Pan L K,Lv T,et al.Investigation of photocatalytic activities over ZnO-TiO2-reduced graphene oxide composites synthesized via microwave-assisted reaction[J].Journal of Colloid & Interface Science,2013,394:441-444.
[9]
Zhang N,Zhang Y H,Pan X Y,et al.Constructing ternary CdS-Graphene-TiO2 hybrids on the flatland of graphene oxide with enhanced visible-light photoactivity for selective transformation[J].Journal of Physical Chemistry C,2012,116(34):18023-18031.
[10]
Jia Q,Wang W Z,Zhao J,et al.Synthesis and characterization of TiO2/polyaniline/graphene oxide bouquet-like composites for enhanced microwave absorption performance[J].Journal of Alloys & Compounds,2017,710:717-724.
[11]
Liang J C,Wang J,Zhou M X,et al.A graphene-SnO2-TiO2 ternary nanocomposite electrode as a high stability lithium-ion anode material[J].Journal of Alloys & Compounds,2016,673:144-148.
[12]
Jiang X,Yang X L,Zhu Y H,et al.Designed synthesis of grapheme-TiO2-SnO2 ternary nanocomposites as lithium-ion anode materials[J].New Journal of Chemistry,2013,37(11):3671-3678.
[13]
Alam U,Fleisch M,Kretschmer I,et al.One-step hydrothermal synthesis of Bi-TiO2 nanotube/graphene composites:an efficient photocatalyst for spectacular degradation of organic pollutants under visible light irradiation[J].Applied Catalysis B Environmental,2017,218:758-769.
[14]
Xiang Q J,Yu J G,Jaroniec M.Synergetic effect of MoS2 and graphene as cocatalysts for enhanced photocatalytic H2 production activity of TiO2 nanoparticles[J].Journal of the American Chemical Society,2012,134(15):6575-6578.
[15]
Zhang H,Guo L H,Wang D B,et al.Light-induced efficient molecular oxygen activation on a Cu(Ⅱ)-grafted TiO2/graphene photocatalyst for phenol degradation[J].ACS Applied Materials & Interfaces,2015,7(3):1816-1823.
[16]
Pang Q,Zhao Y Y,Bian X F,et al.Hybrid Graphene@MoS2@TiO2 microspheres for use as a high performance negative electrode material for lithium ion batteries[J].Journal of Materials Chemistry A,2017,5(7):3667-3674.
[17]
Nimbalkar D B,Lo H H,Ramacharyulu P V R K,et al.Improved photocatalytic activity of RGO/MoS2 nanosheets decorated on TiO2 nanoparticles[J].RSC Advances,2016,6(38):31661-31667.
[18]
Mohamed I M A,Dao V D,Yasin A S,et al.Synthesis of novel ZrO2&GO@TiO2,nanocomposite as an efficient photoanode in dye-sensitized solar cells[J].Superlattices & Microstructures,2016,102:235-245.
[19]
Luo J,Li D L,Yang Y,et al.Preparation of Au/reduced graphene oxide/hydrogenated TiO2,nanotube arrays ternary composites for visible-light-driven photoelectrochemical water splitting[J].Journal of Alloys & Compounds,2016,661:380-388.
[20]
Wang P,Han L,Zhu C Z,et al.Aqueous-phase synthesis of Ag-TiO2-reduced graphene oxide and Pt-TiO2-reduced graphene oxide hybrid nanostructures and their catalytic properties[J].Nano Research,2011,4(11):1153-1162.
[21]
Teranishi M,Naya S,Tada H.In situ liquid phase synthesis of hydrogen peroxide from molecular oxygen using gold nano-particle-loaded titanium(Ⅳ) dioxide photocatalyst[J].Journal of the American Chemical Society,2010,132(23):7850-7851.
[22]
Vijayan B K,Dimitrijevic N M,Wu J S,et al.The effects of Pt doping on the structure and visible light photoactivity of titania Nanotubes[J].Journal of Physical Chemistry C,2010,114(49):21262-21269.
[23]
Khan M,Tahir M N,Adil S F,et al.Graphene based metal and metal oxide nanocomposites:synthesis,properties and their applications[J].Journal of Materials Chemistry A,2015,3(37):18753-18808.
[24]
Su P G,Chen F Y,Wei C H,et al.Simple one-pot polyol synthesis of Pd nanoparticles,TiO2 microrods and reduced graphene oxide ternary composite for sensing NH3 gas at room temperature[J].Sensors and Actuators B,2018,254:1125-1132.
[25]
Gao W Y,Wang M Q,Ran C X,et al.One-pot synthesis of Ag/r-GO/TiO2 nanocomposites with high solar absorption and enhanced anti-recombination in photocatalytic applications[J].Nanoscale,2014,6(10):5498-5508.
[26]
Khalid N R,Ahmed E,Ahmad M,et al.Microwave-assisted synthesis of Ag-TiO2/graphene composite for hydrogen production under visible light irradiation[J].Ceramics International,2016,42(16):18257-18263.
[27]
Cho Y J,Kim H I,Lee S,et al.Dual-functional photocatalysis using a ternary hybrid of TiO2,modified with graphene oxide along with Pt and fluoride for H2-producing water treatment[J].Journal of Catalysis,2015,330:387-395.
[28]
Xiao H,Guo W J,Sun B,et al.Mesoporous TiO2 and Co-doped TiO2 nanotubes/reduced graphene oxide composites as electrodes for supercapacitors[J].Electrochimica Acta,2016,190:104-117.
[29]
Jang J S,Yoon K Y,Xiao X Y,et al.Development of a potential Fe2O3-based photocatalyst thin film for water oxidation by scanning electrochemical microscopy:effects of Ag-Fe2O3 nanocomposite and Sn doping[J].Chemistry of Materials,2009,21(20):4803-4810.
[30]
Pan L,Liu Y T,Xie X M,et al.Multi-dimensionally ordered,multi-functionally integrated r-GO@TiO2(B)@Mn3O4 yolk-membrane-shell superstructures for ultrafast lithium storage[J].Nano Research,2016,9(7):2057-2069.
[31]
Zeng X K,Wang Z Y,Wang G,et al.Highly dispersed TiO2 nanocrystals and WO3 nanorods on reduced graphene oxide:Z-scheme photocatalysis system for accelerated photocatalytic water disinfection[J].Applied Catalysis B Environmental,2017,218:163-173.
[32]
Kumar A,Rout L,Achary L S K,et al.An investigation into the solar light-driven enhanced photocatalytic properties of a graphene oxide-SnO2-TiO2 ternary nanocomposite[J].RSC Advances,2016,6(38):32074-32088.
[33]
Bai X,Lyu L L,Ma W Q,et al.Heterogeneous UV/Fenton degradation of bisphenol a catalyzed by synergistic effects of FeCo2O4/TiO2/GO[J].Environmental Science & Pollution Research,2016,23(22):1-10.
[34]
Yun Y J,Kim J K,Ju J Y,et al.A morphology,porosity and surface conductive layer optimized MnCo2O4 microsphere for compatible superior Li+ ion/air rechargeable battery electrode materials[J].Dalton Transactions,2016,45(12):5064-5070.
[35]
Li G H,Dimitrijevic N M,Chen L,et al.Role of surface/interfacial Cu2+ sites in the photocatalytic activity of coupled CuO-TiO2 nanocomposites[J].Journal of Physical Chemistry C,2008,112(48):19040-19044.
[36]
Yu Y Q,Yan L,Cheng J M,et al.Mechanistic insights into TiO2 thickness in Fe3O4@TiO2-GO composites for enrofloxacin photodegradation[J].Chemical Engineering Journal,2017,325:647-654.
[37]
Li Z J,Huang Z W,Guo W L,et al.Enhanced photocatalytic removal of uranium(Ⅵ) from aqueous solution by magnetic TiO2/Fe3O4 and its graphene composite[J].Environmental Science & Technology,2017,51(10):5666-5674.
[38]
Sharma A,Lee B K.Integrated ternary nanocomposite of TiO2/NiO/reduced graphene oxide as a visible light photoca-talyst for efficient degradation of o-chlorophenol[J].Journal of Environmental Management,2016,181:563-573.
[39]
Xiang Q J,Yu J G,Jaroniec M.Synergetic effect of MoS2 and graphene as cocatalysts for enhanced photocatalytic H2 production activity of TiO2 nanoparticles[J].Journal of the American Chemical Society,2012,134(15):6575-6578.
[40]
Luo J S,Ma L,He T C,et al.TiO2/(CdS,CdSe,CdSeS) nanorod heterostructures and photoelectrochemical properties[J].Journal of Physical Chemistry C,2012,116(22):11956-11963.
[41]
Gao N,Fang X S.Synthesis and development of graphene-inorganic semiconductor nanocomposites[J].Chemical Reviews,2015,115(16):8294-8343.
[42]
Lv T,Pan L K,Liu X J,et al.One-step synthesis of CdS-TiO2-chemically reduced graphene oxide composites via microwave-assisted reaction for visible-light photocatalytic degradation of methyl orange[J].Catalysis Science & Technology,2012,2(4):754-758.
[43]
Han W J,Ren L,Gong L J,et al.Self-assembled three-dimensional graphene-based aerogel with embedded multifarious functional nanoparticles and its excellent photoelectrochemical activities[J].ACS Sustainable Chemistry & Engineering,2014,2(4):741-748.
[44]
Reddy M V,Subba Rao G V,Chowdari B V.Metal oxides and oxysalts as anode materials for Li ion batteries[J].Chemical Reviews,2013,113(7):5364-5457.
[45]
Cheong J Y,Kim C,Jang J S,et al.Rational design of Sn-based multicomponent anodes for high performance lithium-ion batteries:SnO2@TiO2@reduced graphene oxide nanotubes[J].RSC Advances,2016,6(4):2920-2925.
[46]
Johra F T,Jung W G.RGO-TiO2-ZnO composites:synthesis,characterization,and application to photocatalysis[J].Applied Catalysis A General,2015,491:52-57.
[47]
Almeida B M,Jr M A M,Bettini J,et al.A novel nanocompo-site based on TiO2/Cu2O/reduced graphene oxide with enhanced solar-light-driven photocatalytic activity[J].Applied Surface Science,2015,324:419-431.
[48]
Zeng X K,Wang Z Y,Meng N,et al.Highly dispersed TiO2 nanocrystals and carbon dots on reduced graphene oxide:ternary nanocomposites for accelerated photocatalytic water disinfection[J].Applied Catalysis B Environmental,2017,202:33-41.
[49]
Yang L X,Li Z Y,Jiang H M,et al.Photoelectrocatalytic oxidation of bisphenol a over mesh of TiO2/graphene/Cu2O[J].Applied Catalysis B Environmental,2016,183:75-85.
[50]
Hagfeldt A,Boschloo G,Sun L C,et al.Dye-sensitized solar cells[J].Chemical Reviews,2010,110(11):6595-6663.
[51]
Wei L G,Chen S S,Yang Y L,et al.Reduced graphene oxide modified TiO2 semiconductor materials for dye-sensitized solar cells[J].RSC Advances,2016,6(103):100866-100875.
[52]
Yang Y B,Peng X,Chen S,et al.Performance improvement of dye-sensitized solar cells by introducing a hierarchical compact layer involving ZnO and TiO2 blocking films[J].Ceramics International,2014,40(9):15199-15206.
[53]
Taguchi T,Zhang X T,Sutanto I,et al.Improving the performance of solid-state dye-sensitized solar cell using MgO-coated TiO2 nanoporous film[J].Chemical Communications,2003,19(19):2480-2481.
[54]
Ho P,Bao L Q,Ahn K S,et al.P-type dye-sensitized solar cells:enhanced performance with a NiO compact blocking layer[J].Synthetic Metals,2016,217:314-321.
[55]
Mohamed I M A,Dao V D,Yasin A S,et al.Facile synthesis of GO@SnO2/TiO2 nanofibers and their behavior in photovoltaics[J].Journal of Colloid & Interface Science,2017,490:303-313.