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化工新型材料  2019, Vol. 47 Issue (3): 88-93    
  新材料与新技术 本期目录 | 过刊浏览 | 高级检索 |
巯基改性碳纳米管的制备与表征
冒俊霞,王彦*,胡祖明,于俊荣,诸静
纤维材料改性国家重点实验室,东华大学材料科学与工程学院,上海201620
Preparation and characterization of thiol-modified carbon nanotube
Mao Junxia ,Wang Yan ,Hu Zuming,Yu Junrong, Zhu Jing
State Key Laboratory of Modification of Fiber Materials,College of Materials Science and Engineering,Donghua University,Shanghai 201620
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摘要 采用一种新颖、高效的方法,将元素硫应用于碳纳米管(CNTs)的表面改性,在CNTs表面通过硫自由基加成随后还原的方法接枝巯基基团,这种改性方法步骤简单、安全,且不会破坏CNTs的内部结构,可以应用于更多领域。利用该方法分别对多壁碳纳米管和单壁碳纳米管进行表面改性,制备了巯基改性碳纳米管,确定了巯基改性多壁碳纳米管的最佳反应条件并采用傅里叶变换红外光谱仪、拉曼光谱仪、热重分析仪和X射线光电子能谱对所制样品进行表征。
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冒俊霞
王彦
胡祖明
于俊荣
诸静
关键词:  碳纳米管    巯基  表面改性    
Abstract: A novel and effective method was applied to the surface modification of carbon nanotubes (CNTs) by using element sulfur.The thiol groups were grafted onto the surface of CNTs by addition of sulfur radicals followed by reduction.The new method was simple and safe,with no destroy to the internal structure of CNTs,which was expected to be applied in more fields.Thiol-modified multi walled CNTs and thiol-modified single walled CNTs were prepared using this method.Fourier transform infrared spectroscopy (FT-IR),Raman spectroscopy,thermogravimetric analysis and X-ray photoelectron spectroscopy were used to characterize the thiol groups grafted in the surface of CNTs.
Key words:  carbon nanotube    sulfur    thiol    surface modification
               出版日期:  2019-03-20      发布日期:  2019-03-20      期的出版日期:  2019-03-20
通讯作者:  王彦(1986-),男,副教授,从事高性能聚合物、功能性聚合物及聚合物纳米复合材料研究工作。   
作者简介:  冒俊霞(1993-),女,硕士研究生,主要研究方向为碳纳米管的表面改性。
引用本文:    
冒俊霞,王彦,胡祖明,于俊荣,诸静. 巯基改性碳纳米管的制备与表征[J]. 化工新型材料, 2019, 47(3): 88-93.
Mao Junxia ,Wang Yan ,Hu Zuming,Yu Junrong, Zhu Jing. Preparation and characterization of thiol-modified carbon nanotube. New Chemical Materials, 2019, 47(3): 88-93.
链接本文:  
http://www.hgxx.org/CN/  或          http://www.hgxx.org/CN/Y2019/V47/I3/88
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