Abstract: By the reaction of cyanuric chloride (TCT) with p-phenylenediamine (PPD),a microporous polymer based on triazine structure (N-CTF) was successfully synthesized,and the N-CTF was carbonized at 700~1000℃ subsequently.The results showed that the electrochemical performance of the N-CTF-900 sample carbonized at 900℃ was the best,with a specific capacitance of 264.2F·g-1 at current density of 1A·g-1.After 10000 cycles of charging and discharging,the capacitance retention rate reached 91%.The N-CTF-900 could be used as electrode material for supercapacitors due to its excellent cycling stability and rate performance.In addition,the degree of carbonization,conductivity,porosity and micropore volume of the sample all increased with the increase of carbonization temperature.
程广鸿, 曹小凤, 王利魁, 刘云, 石刚, 姚伯龙. 三嗪基氮掺杂碳材料的制备及其在超级电容器中的应用研究[J]. 化工新型材料, 2023, 51(5): 240-243.
Cheng Guanghong, Cao Xiaofeng, Wang Likui, Liu Yun, Shi Gang, Yao Bolong. Preparation and application of triazine-based nitrogen-doped carbon materials for supercapacitors. New Chemical Materials, 2023, 51(5): 240-243.
[1] Sankarananth S,Karthiga M,Karthikeyan C,et al.A novel battery and super capacitor using IOT to interface renewable energy sources with dual direction and its application[J].Journal of Computational and Theoretical Nanoscience,2018,15(5):1615-1624. [2] Duan M,Cao X,Zhang Q,et al.Research and application of supercapacitor charging system[J].Open Access Library Journal,2018,05:1-6. [3] Li F W,Gang Z.Application of advanced energy storage in renewable energy power generation[J].Information Management and Computer Science,2018,1:09-14. [4] Tian J,Zhang T,Talifu D,et al.Porous carbon materials derived from waste cotton stalk with ultra-high surface area for high performance supercapacitors[J].Materials Research Bulletin,2021,143:111457. [5] Su X,Jiang S,Zheng X,et al.Hierarchical porous carbon materials from bio waste-mango stone for high-performance supercapacitor electrodes[J].Materials Letters,2018,230:123-127. [6] Li Q,Mu J,Zhou J,et al.Avoiding the use of corrosive activator to produce nitrogen-doped hierarchical porous carbon materials for high-performance supercapacitor electrode[J].Journal of Electroanalytical Chemistry,2019,832:284-292. [7] Zhao Z,Das S,Xing G,et al.A 3D organically synthesized porous carbon material for lithium-ion batteries[J].Angewandte Chemie International Edition,2018,57(37):11952-11956. [8] Liu Y,Chang Z,Yao L,et al.Nitrogen/sulfur dual-doped sponge-like porous carbon materials derived from pomelo peel synthesized at comparatively low temperatures for superior-performance supercapacitors[J].Journal of Electroanalytical Chemistry,2019,847:113111. [9] Zhang Z,Gao Z,Zhang Y,et al.Hierarchical porous nitrogen-doped graphite from tissue paper as efficient electrode material for symmetric supercapacitor[J].Journal of Power Sources,2021,492:229670. [10] Jin H,Feng X,Li J,et al.Heteroatom-doped porous carbon materials with unprecedented high volumetric capacitive performance[J].Angewandte Chemie International Edition,2019,58(8):2397-2401. [11] Cao X,Li Z,Chen H,et al.Synthesis of biomass porous carbon materials from bean sprouts for hydrogen evolution reaction electrocatalysis and supercapacitor electrode[J].International Journal of Hydrogen Energy,2021,46(36):18887-18897. [12] Liu H,Hu H,Wang J,et al.Hierarchical ternary MoO2/MoS2/heteroatom-doped carbon hybrid materials for high-performance lithium-ion storage[J].ChemElectroChem,2016,3(6):922-932. [13] Liang J,Xiao C,Chen X,et al.Porous γ-Fe2O3 spheres coated with N-doped carbon from polydopamine as Li-ion battery anode materials[J].Nanotechnology,2016,27(21):215403. [14] Zhu H,Yin J,Wang X,et al.Microorganism-derived heteroatom-doped carbon materials for oxygen reduction and supercapacitors[J].Advanced Functional Materials,2013,23(10):1305-1312. [15] Rangraz Y,Heravi M M,Elhampour A.Recent advances on heteroatom-doped porous carbon/metal materials:fascinating heterogeneous catalysts for organic transformations[J].The Chemical Record,2021,21(8):1985-2073. [16] Pan Q Y,Jiang S,Li Z,et al.Highly porous single ion conducting membrane via a facile combined “structural self-assembly” and in-situ polymerization process for high performance lithium metal batteries[J].Journal of Membrane Science,2021,636:119601. [17] Liu B,Sun H,Peng T,et al.3D core-shell poly(aniline-co-pyrrole)/reduced graphene oxide composite for supercapacitor performance[J].Diamond and Related Materials,2021,118:108498. [18] Liang H X,Sun R R,Song B,et al.Preparation of nitrogen-doped porous carbon material by a hydrothermal-activation two-step method and its high-efficiency adsorption of Cr(Ⅵ)[J].Journal of Hazardous Materials,2020,387:121987. [19] Liu X,Liu Y,Wang Y,et al.Preparation of porous carbon materials by polyphosphazene as precursor for sorption of U(Ⅵ)[J].Colloid and Interface Science Communications,2021,41:100387. [20] Rong Y,Wang S,Jia D,et al.Preparation of porous carbon material by carbonizing polyacrylonitrile microspheres[J].Applied Mechanics and Materials,2012,253-255:884-887.