Abstract: Phosphonitrilic-based flame retardants have good flame retardant effect on the polymer.Now hexachlorocyclotriphosphazene(HCCP) as a second generation of phosphorus-nitrogen intumescent flameretardant,duo to it has excellent molecular structural design characteristics,and people has been done a lot of research based on its derivative.The effects of different kinds of HCCP derivatives on the flame retardant of epoxy resin and its composite were introduced.The results showed that HCCP derivatives had good flame retardant to epoxy resin.
于永建,李玲,段宪法. 环三磷腈衍生物在环氧树脂阻燃方面的应用[J]. 化工新型材料, 2019, 47(4): 230-234.
Yu Yongjian, Li Ling, Duan Xianfa. Application of hexachlorocyclotriphosphazene derivative in flame retardant of epoxy resin. New Chemical Materials, 2019, 47(4): 230-234.
[1] Paluvai N R,Mohanty S,Nayak S K.Synthesis and modifications of epoxy resins and their composites:a review[J].Polymer-Plastics Technology and Engineering,2014,53(16):1723-1758. [2] Qian L J,Ye L J,Xu G Z,et al.The non-halogen flame retardant epoxy resin based on a novel compound with phosphaphenanthrene and cyclotriphosphazene double functional groups[J].Polymer Degradation & Stability,2011,96(6):1118-1124. [3] Gouri M E,Bachiri A E,Hegazi S E,et al.A phosphazene compound multipurpose application-Composite material precursor and reactive flame retardant for epoxy resin materials[J].Journal of Materials & Environmental Science,2011,2(4). [4] Liu H,Wang X,Wu D.Preparation,isothermal kinetics,and performance of a novel epoxy thermosetting system based on phosphazene-cyclomatrix network for halogen-free flame retardancy and high thermal stability[J].Thermochimica Acta,2015,607:60-73. [5] Qian L,Ye L,Qiu Y,et al.Thermal degradation behavior of the compound containing phosphaphenanthrene and phosphazene groups and its flame retardant mechanism on epoxy resin[J].Polymer,2011,52(24):5486-5493. [6] 蒋立,丁斌,郝凤岭,等.环三磷腈类阻燃剂的研究现状[J].印染助剂,2017,34(4):6-11. [7] Xu J,He Z,Wu W,et al.Study of thermal properties of flame retardant epoxy resin treated with hexakis[p-(hydroxymethyl)phenoxy]cyclotriphosphazene[J].Journal of Thermal Analysis & Calorimetry,2013,114(3):1341-1350. [8] Liu R,Wang X.Synthesis,characterization,thermal properties and flame retardancy of a novel nonflammable phosphazene-based epoxy resin[J].Polymer Degradation & Stability,2009,94(4):617-624. [9] Xu G R,Xu M J,Li B.Synthesis and characterization of a novel epoxy resin based on cyclotriphosphazene and its thermal degradation and flammability performance[J].Polymer Degradation & Stability,2014,109(109):240-248. [10] Qian L J,Ye L J,Xu G Z,et al.The non-halogen flame retardant epoxy resin based on a novel compound with phosphaphenanthrene and cyclotriphosphazene double functional groups[J].Polymer Degradation & Stability,2011,96(6):1118-1124. [11] Xu M J,Xu G R,Leng Y,et al.Synthesis of a novel flame retardant based on cyclotriphosphazene and DOPO groups and its application in epoxy resins[J].Polymer Degradation & Stability,2016,123:105-114. [12] Liu H,Wang X,Wu D.Novel cyclotriphosphazene-based epoxy compound and its application in halogen-free epoxy thermosetting systems:synthesis,curing behaviors,and flame retardancy[J].Polymer Degradation & Stability,2014,103(1):96-112. [13] Zhao B,Liang W J,Wang J S,et al.Synthesis of a novel bridged-cyclotriphosphazene flame retardant and its application in epoxy resin[J].Polymer Degradation & Stability,2016,133:162-173. [14] Liang W J,Zhao B,Zhao P H,et al.Bisphenol-S bridged penta(anilino)cyclotriphosphazene and its application in epoxy resins:synthesis,thermal degradation,and flame retardancy[J].Polymer Degradation & Stability,2017,135:140-151. [15] Liu F F,Hao W,Huang X B,et al.Preparation and properties of novel inherent flame-retardant cyclotriphosphazene-containing epoxy resins[J].Journal of Macromolecular Science Part B,2010,49(5):1002-1011. [16] Bai Y,Wang X,Wu D.Novel cyclolinear cyclotriphosphazene-linked epoxy resin for halogen-free fire resistance:synthesis,characterization,and flammability characteristics[J].Industrial & Engineering Chemistry Research,2012,51(46):15064-15074. [17] Kang N,Du Z,Li H,et al.Synthesis and characterization of P/Si flame retardant and its application in epoxy systems[J].Polymers for Advanced Technologies,2012,23(10):1329-1334. [18] Yamauchi T,Yuuki A,Wei G,et al.Immobilization of flame retardant onto silica nanoparticle surface and properties of epoxy resin filled with the flame retardant-immobilized silica[J].Journal of Polymer Science Part A Polymer Chemistry,2010,47(22):6145-6152. [19] Kawahara T,Yuuki A,Hashimoto K,et al.Immobilization of flame-retardant onto silica nanoparticle surface and properties of epoxy resin filled with the flame-retardant-immobilized silica (2)[J].Reactive & Functional Polymers,2013,73(3):613-618. [20] Gu X,Huang X,Wei H,et al.Synthesis of novel epoxy-group modified phosphazene-containing nanotube and its reinforcing effect in epoxy resin[J].European Polymer Journal,2011,47(5):903-910. [21] Qiu S,Wang X,Yu B,et al.Flame-retardant-wrapped polyphosphazene nanotubes:a novel strategy for enhancing the flame retardancy and smoke toxicity suppression of epoxy resins[J].Journal of Hazardous Materials,2017,325:327. [22] Ma H,Zhao L,Liu J,et al.Functionalizing carbon nanotubes by grafting cyclotriphosphazene derivative to improve both mechanical strength and flame retardancy[J].Polymer Composites,2015,35(11):2187-2193. [23] Pan M,Huang R,Wang T,et al.Preparation and properties of epoxy resin composites containing hexaphenoxycyclotriphosphazene[J].High Performance Polymers,2014,26(1):114-121. [24] Sun J,Wang X,Wu D.Novel spirocyclic phosphazene-based epoxy resin for halogen-free fire resistance:synthesis,curing behaviors,and flammability characteristics[J].Acs Applied Materials & Interfaces,2012,4(8):4047. [25] Yang S,Wang J,Huo S,et al.Synthesis of a phosphorus/nitrogen-containing compound based on maleimide and cyclotriphosphazene and its flame-retardant mechanism on epoxy resin[J].Polymer Degradation & Stability,2016,126:9-16. [26] Liu H,Wang X,Wu D.Preparation,isothermal kinetics,and performance of a novel epoxy thermosetting system based on phosphazene-cyclomatrix network for halogen-free flame retardancy and high thermal stability[J].Thermochimica Acta,2015,607:60-73. [27] You G Y,Cai Z,Peng H,et al.A well-defined cyclotriphosphazene-based epoxy monomer and its application as a novel epoxy resin:synthesis,curing behaviors,and flame retardancy[J].Phosphorus Sulfur & Silicon & the Related Elements,2014,189(4):541-550.