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化工新型材料  2018, Vol. 46 Issue (12): 172-174    
  科学研究 本期目录 | 过刊浏览 | 高级检索 |
非对称苝酰亚胺衍生物的研究
杨志胜1,2, 柯蔚芳3, 王艳香2, 黄丽群2, 朱华4
1.上饶师范学院物理与电子信息系,上饶334001;
2.景德镇陶瓷大学材料科学与工程学院,景德镇333403;
3.景德镇陶瓷大学陶瓷美术学院,景德镇333403;
4.景德镇陶瓷大学机电学院,景德镇333403
Study on asymmetric perylene diimide derivative
Yang Zhisheng1,2, Ke Weifang3, Wang Yanxiang2, Huang Liqun2, Zhu Hua4
1.Department of Physics and Electronics,Shangrao Normal University,Shangrao 334001;
2.Department of Materials Science and Engineering,Jingdezhen Ceramic Institute,Jingdezhen 333403;
3.Department of Ceramic Art,Jingdezhen Ceramic Institute,Jingdezhen 333403;
4.Department of Mechanical and Electrical Engineering,Jingdezhen Ceramic Institute,Jingdezhen 333403;
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摘要 有机半导体材料具有低成本、可制备柔性器件等优点,广泛应用于有机薄膜光电器件。如今迫切需求同时具有较高迁移率和较好溶解性能可溶液加工的有机电子传输材料来支撑其发展。但分子的功能化使其刚性越来越大,溶解性能受到了影响。设计合成了N,N′-二苯基苝四羧基二酰亚胺(DiPP)和N-十二烷基-N′-苯基-苝酰亚胺(DoPP)两种苝酰亚胺衍生物,研究长链烷基对苝酰亚胺衍生物性能的影响。结果表明,长链烷基的引入大幅度提升了苝酰亚胺衍生物的溶解性能,但是其在空气中的热稳定性和抗氧化性有所降低。
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杨志胜
柯蔚芳
王艳香
黄丽群
朱华
关键词:  苝酰亚胺  长链烷基  非对称    
Abstract: Organic semiconductor materials are widely used in thin-film organic devices due to their advantages of low cost and flexible.There is an urgent need to support the development of organic semiconductor materials that have both high mobility and good solubility.However,the functionalization of molecules make it more rigid and solubility is limited.Two kinds of perylene imide derivatives,N,N′-diphenyl perylene tetracarboxylic diimide (DiPP) and N-dodecyl N′-phenyl perylene imide (DoPP) were synthesized to study the effect of long chain alkyl groups on the performance of perylene imide derivatives.The results showed that the introduction of long-chain alkyl greatly improved the solubility of perylene imide derivative,but its thermal stability and oxidation resistance in air decreased.
Key words:  perylene diimide    long chain of alkyl    asymmetry
收稿日期:  2017-12-19                     发布日期:  2019-01-07      期的出版日期:  2018-12-20
基金资助: 国家自然科学基金(51403090,51863010);江西省教育厅青年自然科学基金(GJJ150897)
作者简介:  杨志胜(1981-),男,博士,副教授,主要研究杂化太阳能电池材料及器件。
引用本文:    
杨志胜, 柯蔚芳, 王艳香, 黄丽群, 朱华. 非对称苝酰亚胺衍生物的研究[J]. 化工新型材料, 2018, 46(12): 172-174.
Yang Zhisheng, Ke Weifang, Wang Yanxiang, Huang Liqun, Zhu Hua. Study on asymmetric perylene diimide derivative. New Chemical Materials, 2018, 46(12): 172-174.
链接本文:  
http://www.hgxx.org/CN/  或          http://www.hgxx.org/CN/Y2018/V46/I12/172
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