Please wait a minute...
 首页  期刊简介 期刊订阅 广告合作 联系我们
 
最新录用  |  当期目录  |  过刊浏览  |  热点文章  |  阅读排行
化工新型材料  2018, Vol. 46 Issue (11): 202-204    
  科学研究 本期目录 | 过刊浏览 | 高级检索 |
咔唑基杂化钙钛矿材料的研究
杨志胜1,3, 柯蔚芳2, 王艳香1, 黄丽群1, 洪筠1
1.景德镇陶瓷大学材料科学与工程学院,景德镇333403;
2.景德镇陶瓷大学陶瓷美术学院,景德镇333403;
3.上饶师范学院物理与电子信息系,上饶334001
Study on carbazole based hybrid perovskite material
Yang Zhisheng1,3, Ke Weifang2, Wang Yanxiang1, Huang Liqun1, Hong Yun1
1.Department of Materials Science and Engineering,Jingdezhen Ceramic Institute,Jingdezhen 333403;
2.Department of Ceramic Art,Jingdezhen Ceramic Institute,Jingdezhen 333403;
3.Department of Physics and Electronics,Shangrao Normal University,Shangrao 334001
下载:  PDF (1210KB) 
输出:  BibTeX | EndNote (RIS)      
摘要 有机/无机杂化钙钛矿材料是一种综合性能良好的有序复合光电材料。选择具有较大共轭的咔唑类铵盐作为杂化钙钛矿的有机组分,合成氯化锌基杂化钙钛矿[(C6H4)2N(CH2)6NH3]2ZnCl4(N6AHMC-ZnCl4)。发现在该杂化钙钛矿材料中,由于有机/无机协同增强作用,使得该材料在紫外光区239nm、265nm、298nm、336nm和351nm处有较强的吸收峰,在分解温度为243℃条件下的失重率为5%,具有较好的热性能。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
杨志胜
柯蔚芳
王艳香
黄丽群
洪筠
关键词:  有机/无机杂化  钙钛矿  紫外探测    
Abstract: Organic-inorganic hybrid perovskite material are ordered high-performance photoelectric materials.Carbazole derivative amine salt with long conjugated chain was selected to synthesize ZnCl2 based hybrid perovskite [(C6H4)2N(CH2)6NH3]2ZnCl4.(N6AHMC-ZnCl4).The result showed that this perovskite material had strong absorption peak in the ultraviolet region located in 239nm,265nm,298nm,336nm and 351nm respectively.At the decomposition temperature of 243℃,the weight loss rate of material was 5%,because of the organic/inorganic coordination enhancement absorption effect,demonstrating a promising application prospect in the ultraviolet detecting field.
Key words:  organic-inorganic hybrid    perovskite    ultraviolet detecting
收稿日期:  2017-07-10                出版日期:  2018-11-20      发布日期:  2018-12-04      期的出版日期:  2018-11-20
基金资助: 国家自然科学基金(51403090,51863010,51462015);国际科技合作专项(2013DFA51000);江西省教育厅青年自然科学基金(GJJ150897)
作者简介:  杨志胜(1981-),男,博士,副教授,主要研究杂化太阳电池材料及器件。
引用本文:    
杨志胜, 柯蔚芳, 王艳香, 黄丽群, 洪筠. 咔唑基杂化钙钛矿材料的研究[J]. 化工新型材料, 2018, 46(11): 202-204.
Yang Zhisheng, Ke Weifang, Wang Yanxiang, Huang Liqun, Hong Yun. Study on carbazole based hybrid perovskite material. New Chemical Materials, 2018, 46(11): 202-204.
链接本文:  
http://www.hgxx.org/CN/  或          http://www.hgxx.org/CN/Y2018/V46/I11/202
[1] Peter S,Kan M.AlxGa1-xN for solar-blind UV detectors[J].Journal of Crystal Growth,2001,231(3):366-370.
[2] 胡彩玲,李俊.TiO2纳米棒花状结构的紫外探测性能研究[J].化工新型材料,2015,43(5):74-76.
[3] Vassilakopoulou A,Papadatos D,Zakouras I,et al.Excitonic many-body interactions in two-dimensional lead iodide perovskite quantum wells[J].Journal of Alloys and Compounds,2017,692:589-598.
[4] 刘崭,石高全,陈凤恩,等.正十二烷基胺支撑的四碘化锡层状半导体材料的研究[J].无机化学学报,2003,19(11):1185-1190.
[5] Gan X Y,Wang O,Liu K Y,et al.Photovoltaic properties of two-dimensional (CH3NH3)2Pb(SCN)2I2 perovskite:a combined experimental and density functional theory study[J].Solar Energy Materials and Solar Cells,2017,162:93-102.
[6] Mitzi D B.A layered solution crystal growth technique and the crystal structure of (C6H5C2H4NH3)2PbCl4[J].Journal of Solid State Chemistry,1999,145(2):694-704.
[7] Era M,Miyake K,Yoshida Y,et al.Orientation of azobenzene chromophore incorporated into metal halide-based layered perovskite having organic-inorganic superlattice structure[J].Thin Solid Films,2001,393:24-27.
[8] Era M,Yoneda S,Sano T,et al.Preparation of amphiphilic poly(thiophene)s and their application for the construction of organic-inorganic superlattice[J].Thin Solid Films,2003,438/439:322-325.
[9] Kosuge H,Okada S,Oikawa H.Polydiacetylenes in organic-inorganic hybrid systems[J].Molecular Crystals and Liquid Crystals,2002,377(1):13-18.
[10] Era M,Kobayashi T,Noto M.PbBr-based layered perovskite organic-inorganic superlattice having hole-transporting carbazole chromophore in organic layer[J].Current Applied Physics,2005,5(1):67-70.
[11] Cheng Z Y,Gao B X,Pang M L,et al.Preparation and characterization of a novel layered perovskite-type organic/inorganic hybrid material containing silica networks[J].Chemistry of Materials,2003,15:4705-4708.
[1] 张艳苹, 刘海峰, 霍冀川. 钙钛矿型氧化物薄膜的制备及光催化降解染料的研究进展[J]. 化工新型材料, 2018, 46(9): 55-59.
[2] 闫春花, 刘志勇, 贾福金, 车俐佳, 谷朝辉, 郭艳群, 曾琳, 白传易, 鲁玉明, 范峰, 蔡传兵. Ag电极对钙钛矿太阳能电池性能的影响[J]. 化工新型材料, 2018, 46(7): 185-190.
[3] 郭瑞华, 郭乐乐, 张捷宇, 周国治, 安胜利. 双钙钛矿结构固体氧化物燃料电池阴极SmBaFe2-xCoxO5+δ的制备与性能研究[J]. 化工新型材料, 2018, 46(3): 183-186.
[4] 李春静, 杨瑞霞, 马浩, 金慧娇, 石晓东, 马文静. CH3NH3PbI2Br光吸收层薄膜的制备[J]. 化工新型材料, 2018, 46(2): 155-159.
[5] 吴亚楠, 李松波, 安胜利, 李向国. 固体氧化物燃料电池阴极材料La0.7Sr0.3FexCo1-xMe0.1O3-δ的制备与性能[J]. 化工新型材料, 2018, 46(11): 188-192.
[6] 陈彦广, 安宏宇, 韩洪晶, 王海英, 王新惠, 赵宏志, 宋华. 木质素催化氧化研究进展[J]. 化工新型材料, 2018, 46(11): 245-248.
No Suggested Reading articles found!
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
京ICP备09035943号-38
版权所有 © 《化工新型材料》编辑部
本系统由北京玛格泰克科技发展有限公司设计开发 技术支持:support@magtech.com.cn