1.Faculty of Environmental Science and Engineering,Kunming University of Science and Technology,Kunming 650500; 2.Yunnan Beikong Water Co.,Ltd.,Kunming 650500
Abstract: The zirconium (Zr)-based metal-organic frameworks (Zr-MOFs),which was hydrothermal synthesized used zirconium chloride (ZrCl4) and 1,4-benzenedicarboxylic acid (H2BDC),modified by acetic acid and hydrochloric acid solvent,which could be used for carbon dioxide (CO2) capture and separation as a suitable candidate material.The results showed that the adsorption capacity of Zr-MOFs was 1.47mmol/g and 0.089mmol/g on CO2 and N2,respectively,under the condition of 25℃ and 0.1MPa,which had good adsorption property for CO2.
牛照栋,张德华,孟凡凡,庙荣荣,陈秋玲,宁平,谷俊杰,关清卿. 锆基金属有机骨架材料的合成及其对CO2/N2的 吸附与分离性能研究[J]. 化工新型材料, 2018, 46(10): 123-125.
Niu Zhaodong,Zhang Dehua,Meng Fanfan,Miao Rongrong,Chen Qiuling,Ning Ping,Gu Junjie,Guan Qingqing. Synthesis of Zr-based metal organic frameworks and its CO2/N2 capture and separation. New Chemical Materials, 2018, 46(10): 123-125.
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