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化工新型材料  2018, Vol. 46 Issue (10): 123-125    
  新材料与新技术 本期目录 | 过刊浏览 | 高级检索 |
锆基金属有机骨架材料的合成及其对CO2/N2的 吸附与分离性能研究
牛照栋1,张德华1*,孟凡凡2,庙荣荣1,陈秋玲1,宁平1,谷俊杰1,关清卿1
1.昆明理工大学环境科学与工程学院,昆明650500;
2.云南北控水务有限公司,昆明650500
Synthesis of Zr-based metal organic frameworks and its CO2/N2 capture and separation
Niu Zhaodong1,Zhang Dehua1,Meng Fanfan2,Miao Rongrong1,Chen Qiuling1,Ning Ping1,Gu Junjie1,Guan Qingqing1
1.Faculty of Environmental Science and Engineering,Kunming University of Science and Technology,Kunming 650500;
2.Yunnan Beikong Water Co.,Ltd.,Kunming 650500
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摘要 采用氯化锆(ZrCl4)和对苯二甲酸(H2BDC),通过冰乙酸和盐酸改良的溶剂热法合成锆基金属有机骨架材料(Zr-MOFs),可作为理想的二氧化碳(CO2)捕集与分离材料。研究结果表明:在25℃,吸附压力0.1MPa条件下,Zr-MOFs对CO2和N2的吸附量分别为1.47mmol/g和0.089mmol/g,并且在CO2/N2体系中对CO2有较高的分离性能。
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牛照栋
张德华
孟凡凡
庙荣荣
陈秋玲
宁平
谷俊杰
关清卿
关键词:  金属有机骨架  CO2  吸附与分离    
Abstract: The zirconium (Zr)-based metal-organic frameworks (Zr-MOFs),which was hydrothermal synthesized used zirconium chloride (ZrCl4) and 1,4-benzenedicarboxylic acid (H2BDC),modified by acetic acid and hydrochloric acid solvent,which could be used for carbon dioxide (CO2) capture and separation as a suitable candidate material.The results showed that the adsorption capacity of Zr-MOFs was 1.47mmol/g and 0.089mmol/g on CO2 and N2,respectively,under the condition of 25℃ and 0.1MPa,which had good adsorption property for CO2.
Key words:  metal organic frameworks    CO2    capture and separation
                    发布日期:  2018-11-06      期的出版日期:  2018-11-06
基金资助: 国家自然科学基金(21307049);云南省高端科技人才引进项目(2010CI110)
通讯作者:  张德华,博士,副教授。   
作者简介:  牛照栋(1991-),男,硕士,主要研究方向为新型多孔材料对气体的吸附和分离。
引用本文:    
牛照栋,张德华,孟凡凡,庙荣荣,陈秋玲,宁平,谷俊杰,关清卿. 锆基金属有机骨架材料的合成及其对CO2/N2的 吸附与分离性能研究[J]. 化工新型材料, 2018, 46(10): 123-125.
Niu Zhaodong,Zhang Dehua,Meng Fanfan,Miao Rongrong,Chen Qiuling,Ning Ping,Gu Junjie,Guan Qingqing. Synthesis of Zr-based metal organic frameworks and its CO2/N2 capture and separation. New Chemical Materials, 2018, 46(10): 123-125.
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http://www.hgxx.org/CN/  或          http://www.hgxx.org/CN/Y2018/V46/I10/123
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