Research progress of microcapsule intelligent self-healing material
He Ziteng1, Zhang Wei1, Ma Wanpeng2, Yu Helong1, Zhao Yang1
1.Science and Technology on Remanufacturing Laboratory,Academy of Armored Force Engineering,Beijing 100072; 2.Army Aviation Research Institution,Beijing 101121
Abstract: Microcapsule self-healing material is an intelligent self-healing system inspired by the mechanism of organism wound healing.The microcapsule self-healing material can realize its own energy and material replenish intelligently,to a certain extent,enhance the mechanical properties of material and prolong the service life.The preparation technology of microcapsule,self-healing mechanism of microcapsule and self-healing system were studied,and the evaluation method of self restoring effect was briefly summarized.The development prospect of microcapsule self-healing materials was prospected.
[1]Yang Y,Urban M W.Self-healing polymeric materials[J].Chemical Society Reviews,2013,42(17):7446-7467. [2]Habault D,Zhang H,Zhao Y.Light-triggered self-healing and shape-memory polymers[J].Chemical Society Reviews,2013,42(17):7244-7256. [3]Herbst F,Döhler D,Michael P,et al.Self-healing polymers via supramolecular forces[J].Macromolecular Rapid Communications,2013,34(3):203-220. [4]Nguyen L T T,Nguyen H T,Truong T T.Thermally mendable material based on a furyl-telechelic semicrystalline polymer and a maleimide crosslinker[J].Journal of Polymer Research,2015,22(9):1-9. [5]Burnworth M,Tang L,Kumpfer J R,et al.Optically healable supramolecular polymers[J].Nature,2011,472(7343):334-337. [6]Dry C.Matrix cracking repair and filling using active and passive modes for smart time release of chemicals from fibers into cement matrices[J].Smart Mater Struct,1994,3:118-223. [7]Kessler M R,Sottos N R,White S R.Self-healing structural composite materials[J].Composites Part A,2003,34:743-753. [8]Wu W,Hansen C J,Aragón A M,et al.Direct-write assembly of biomimetic microvascular networks for efficient fluid transport[J].Soft Matter,2010,6(4):739-742. [9]Youngblood J P,Sottos N R.Bioinspired materials for self-cleaning and self-healing[J].Mrs Bulletin,2008,33(8):732-741. [10]White S R,Sottos N R,Geubelle P H,et al.Autonomic healing of polymer composites[J].Nature,2001,409(6822):794-797. [11]Yuan H,Li G,Yang L,et al.Development of melamine-formaldehyde resin microcapsules with low formaldehyde emission suited for seed treatment[J].Colloids and Surfaces B:Biointerfaces,2015,128:149-154. [12]Rajam R,Anandharamakrishnan C.Microencapsulation of lactobacillus plantarum (MTCC 5422) with fructooligosaccharide as wall material by spray drying[J].LWT-Food Science and Technology,2015,60(2):773-780. [13]Ullah H,M Azizli K A,Man Z B,et al.The potential of microencapsulated self-healing materials for microcracks recovery in self-healing composite systems:a review[J].Polymer Reviews,2016,56(3):429-485. [14]Asua J M.Miniemulsion polymerization[J].Progress in Polymer Science,2002,27(7):1283-1346. [15]Koh E,Kim N K,Shin J,et al.Polyurethane microcapsules for self-healing paint coatings[J].RSC Advances,2014,4(31):16214-16223. [16]Yang Z,Hollar J,He X,et al.A self-healing cementitious composite using oil core/silica gel shell microcapsules[J].Cement and Concrete Composites,2011,33(4):506-512. [17]Li Q,Mishra A K,Kim N H,et al.Effects of processing conditions of poly (methylmethacrylate) encapsulated liquid curing agent on the properties of self-healing composites[J].Composites Part B:Engineering,2013,49:6-15. [18]Zhu D Y,Rong M Z,Zhang M Q.Self-healing polymeric materials based on microencapsulated healing agents:from design to preparation[J].Progress in Polymer Science,2015,49:175-220. [19]Brown E N,Kessler M R,Sottos N R,et al.In situ poly(urea-formaldehyde) microencapsulation of dicyclopentadiene[J].Journal of Microencapsulation,2003,20(6):719. [20]Yuan L,Liang G Z,Xie J Q,et al.Preparation and characterization of poly(urea-formaldehyde) microcapsules filled with epoxy resins[J].Polymer,2006,47(15):5338-5349. [21]Yuan L,Gu A J,Liang G Z.Preparation and properties of poly(urea-formaldehyde) microcapsules filled with epoxy resins[J].Mater Chem Phys,2008,110:417-425. [22]White S R,Sottos N R,Geubelle P H,et al.Autonomic healing of polymer composites[J].Nature,2001,409:794-797. [23]Risse W,Grubbs R H.Block and graft copolymers by living ring-opening olefin metathesis polymerization[J].Journal of Molecular Catalysis,2007,32(1):1-29. [24]Kessler M R,White S R.Cure kinetics of the ring-opening metathesis polymerization of dicyclopentadiene[J].Journal of Polymer Science Part A Polymer Chemistry,2002,40(14):2373-2383. [25]Rule J,Brown E,Sottos N,et al.Wax-protected catalyst microspheres for efficient self-healing materials[J].Advanced Materials,2005,17(2):205-208. [26]Lv L,Yang Z,Chen G,et al.Synthesis and characterization of a new polymeric microcapsule and feasibility investigation in self-healing cementitious materials[J].Construction and Building Materials,2016,105:487-495. [27]Keller M W,White S R,Sottos N R.A self-healing poly(dimethyl siloxane) elastomer[J].Advanced Functional Materials,2007,17(14):2399-2404. [28]Keller M W,White S R,Sottos N R.Torsion fatigue response of self-healing poly(dimethylsiloxane) elastomers[J].Polymer,2008,49(13-14):3136-3145. [29]Cho S,Andersson H,White S,et al.Polydimethylsiloxane-based self-healing materials[J].Advanced Materials,2010,18(8):997-1000. [30]Cho S H,White S R,Braun P V.Room-temperature polydimethylsiloxane-based self-healing polymers[J].Chemistry of Materials,2012,24(21):4209-4214. [31]Hondred P R,Salat L,Mangler J,et al.Tung oil-based thermosetting polymers for self-healing applications[J].Journal of Applied Polymer Science,2014,131(12):383-390. [32]Hondred P R,Kessler M R.Rare earth triflate initiators in the cationic polymerization of tung oil-based thermosetting polymers for self-healing applications[J].Macromolecular Materials and Engineering,2014,299(9):1062-1069. [33]Jin H,Mangun C L,Stradley D S,et al.Self-healing thermoset using encapsulated epoxy-amine healing chemistry[J].Polymer,2012,53(2):581-587. [34]Jin H,Mangun C L,Griffin A S,et al.Thermally stable autonomic healing in epoxy using a dual-microcapsule system[J].Advanced Materials,2014,26(2):282-287. [35]Yin T,Zhou L,Zhi Rong M,et al.Self-healing woven glass fabric/epoxy composites with the healant consisting of micro-encapsulated epoxy and latent curing agent[J].Smart Materials & Structures,2008,17(1):015019. [36]Yin T,Rong M Z,Wu J,et al.Healing of impact damage in woven glass fabric reinforced epoxy composites[J].Composites Part A:Applied Science & Manufacturing,2008,39(9):1479-1487. [37]Coope T S,Mayer U F J,Wass D F,et al.Self-healing of an epoxy resin using scandium(Ⅲ) triflate as a catalytic curing agent[J].Advanced Functional Materials,2015,21(24):4624-4631. [38]Liao L P,Wei Z,Yi X,et al.Preparation and characterization of microcapsule containing epoxy resin and its self-healing performance of anticorrosion covering material[J].Chinese Science Bulletin,2011,56(4-5):439-443. [39]廖乐平,张伟,赵阳.仿生自修复环氧树脂涂层制备及性能[J].中国表面工程,2013,26(4):88-93. [40]Caruso M M,Delafuente D A,Ho V,et al.Solvent-promoted self-healing epoxy materials[J].Macromolecules,2007,40(25):8830-8832. [41]Caruso M M,Blaiszik B J,White S R,et al.Full recovery of fracture toughness using a nontoxic solvent-based self-healing system[J].Advanced Functional Materials,2008,18(13):1898-1904. [42]Ma Wanpeng,Zhang Wei,Zhao Yang,et al.Predictions of healing performance for solvent-promoted self-healing material by using Hansen solubility parameters[J].Materials Letters,2016,163:244-246. [43]Ma Wanpeng,Zhang Wei,Zhao Yang.Preparation and assessment of self-healing material based on microcapsule filled with ethyl phenylacetate[J].Journal of Applied Polymer Science,2016,133(20):133-135. [44]Ma Wanpeng,Zhang Wei,Zhao Yang,et al.Estimation of the mechanical properties of urea-formaldehyde microcapsules by compression tests and finite element analysis[J].Journal of Applied Polymer Science,2016,133(19):254-257. [45]马万鹏,张伟,赵阳,等.溶剂微胶囊/环氧树脂复合材料的自修复性能[J].高分子材料科学与工程,2016,32(6):128-132. [46]Sandmann B,Happ B,Hager M D,et al.Efficient Cu(Ⅰ) acetate-catalyzed cycloaddition of multifunctional alkynes and azides:from solution to bulk polymerization[J].Journal of Polymer Science Part A Polymer Chemistry,2014,52(2):239-247. [47]Gragert M,Schunack M,Binder W H.Azide/alkyne-“click”-reactions of encapsulated reagents:toward self-healing materials[J].Macromolecular Rapid Communications,2011,32(5):419-425. [48]Pratama P A,Sharifi M,Peterson A M,et al.Room temperature self-healing thermoset based on the diels-alder reaction[J].Acs Applied Materials & Interfaces,2013,5(23):12425. [49]Boura S H,Peikari M,Ashrafi A,et al.Self-healing ability and adhesion strength of capsule embedded coatings-micro and nano sized capsules containing linseed oil[J].Progress in Organic Coatings,2012,75(4):292-300. [50]Samadzadeh M,Boura S H,Peikari M,et al.Tung oil:an autonomous repairing agent for self-healing epoxy coatings[J].Progress in Organic Coatings,2011,70(4):383-387. [51]Huang M,Yang J.Long-term performance of 1H,1H′,2H,2H′-perfluorooctyl triethoxysilane(POTS) microcapsule-based self-healing anticorrosive coatings[J].Journal of Intelligent Material Systems and Structures,2014,25(1):98-106. [52]Cho S H,Andersson H M,White S R,et al.Polydimethylsiloxane-based self-healing materials[J].Advanced Materials,2006,18(8):997-1000. [53]Brown E N,Sottos N R,White S R.Fracture testing of a self-healing polymer composite[J].Experimental Mechanics,2002,42(4):372-379. [54]Xiao D S,Yuan Y C,Rong M Z,et al.Self-healing materials:a facile strategy for preparing self-healing polymer composites by incorporation of cationic catalyst-loaded vegetable fibers[J].Advanced Functional Materials,2009,19(14):2289-2296. [55]Jin H,Mangun C L,Stradley D S,et al.Self-healing thermoset using encapsulated epoxy-amine healing chemistry[J].Polymer,2012,53(2):581-587. [56]Zhang H,Wang P,Yang J.Self-healing epoxy via epoxy-amine chemistry in dual hollow glass bubbles[J].Composites Science & Technology,2014,94(4):23-29. [57]Dubey R,Shami T C,Rao K U B.Microencapsulation technology and applications[J].Defence Science Journal,2009,59(1):82-95. [58]Nesterova T,Dam-Johansen K,Pedersen L T,et al.Microcapsule-based self-healing anticorrosive coatings:capsule size,coating formulation,and exposure testing[J].Progress in Organic Coatings,2012,75(4):309-318. [59]Brown E N,White S R,Sottos N R.Fatigue crack propagation in microcapsule-toughened epoxy[J].Journal of Materials Science,2006,41(19):6266-6273. [60]Yoshizawa H,Kamio E,Kobayashi E,et al.Investigation of alternative compounds to poly(E-MA) as a polymeric surfactant for preparation of microcapsules by phase separation method[J].Journal of Microencapsulation,2007,24(4):349-57. [61]Kanicky J R,Shah D O.Effect of degree,type,and position of unsaturation on the pKa of long-chain fatty acids[J].J Colloid Interface Sci,2002,256(1):201-207. [62]Hayes S A,Zhang W,Branthwaite M,et al.Self-healing of damage in fibre-reinforced polymer-matrix composites[J].Journal of the Royal Society Interface,2007,4(13):381. [63]Ding S X,Yan C Y,Min Z R,et al.Self-healing epoxy based on cationic chain polymerization[J].Polymer,2009,50(13):2967-2975. [64]Patel A J,Sottos N R,Wetzel E D,et al.Autonomic healing of low-velocity impact damage in fiber-reinforced composites[J].Composites Part A:Applied Science and Manufacturing,2010,41(3):360-368.